Hostname: page-component-8448b6f56d-qsmjn Total loading time: 0 Render date: 2024-04-24T23:06:01.754Z Has data issue: false hasContentIssue false

Device Physics of Heterojunction with Intrinsic Thin Layer (HIT) Solar Cells

Published online by Cambridge University Press:  31 January 2011

Ana Kanevce
Affiliation:
ana_kanevce@nrel.govkanevce@lamar.colostate.edu, National Renewable Energy Laboratory, Golden, Colorado, United States
Wyatt K. Metzger
Affiliation:
wyatt_metzger@nrel.gov, National Renewable Energy Laboratory, Golden, Colorado, United States
Get access

Abstract

Heterojunction with intrinsic thin layer (HIT) solar cells have achieved conversion efficiencies higher than 22%. Yet, many questions concerning the device physics governing these cells remain unanswered. We use numerical modeling to analyze the role of a-Si:H layers and tunneling on cell performance. For cells with n-type c-Si (n-HIT cells), incorporating the indium-tin-oxide (ITO) as an n-type semiconductor creates an n+/p/n structure. Most device simulations do not work with this structure. Our modeling indicates that the n+/p/n device often produces irregular S-shaped current density–voltage (J-V) curves, which have been observed experimentally but were not previously understood. However, if tunneling is included, there are specific conditions where the n+/p/n structure performs as a robust solar cell with efficiencies exceeding 20%. Additional analysis examines voltage-dependent carrier collection in n-HIT cells, as well as material and interface properties that limit fill factor. In p-HIT cells, modeling the ITO layer as a semiconductor, rather than as a metallic contact, significantly reduces the impact of a-Si:H layer parameters on device performance. In p-HIT cells, the a-Si:H layers adjacent to the ITO layer play the role of a buffer that reduces interface recombination at the a-Si:H/c-Si interface and prevents tunneling of electrons from the ITO layer to the c-Si absorber. Tunneling through the a-Si:H layers adjacent to the back contact is important to attain regular J-V curves.

Type
Research Article
Copyright
Copyright © Materials Research Society 2009

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1 Taira, S. Yoshimine, Y. Baba, T. Taguchi, M. Kinoshita, T. Sakata, H. Maruyama, E. and Tanaka, M. in 22nd EU PVSEC (Milan, 2007), p. 932936.Google Scholar
2 Green, M.A. Emery, K. Hisikawa, Y. and Warta, W. Prog. Photovoltaics 15, 425430 (2007).Google Scholar
3 Taguchi, M. Terakawa, A. Maruyama, E. and Tanaka, M. Prog. Photovoltaics 13, 481488 (2005).Google Scholar
4 Taguchi, M. Kawamoto, K. Tsuge, S. Baba, T. Sakata, H. Morizane, M. Uchihashi, K. Nakamura, N. Kiyama, S. and Oota, O. Prog. Photovoltaics 8, 503513 (2000).Google Scholar
5 Tanaka, M. Taguchi, M. Matsuyama, T. Sawada, T. Tsuda, S. Nakano, S. Hanafusa, H. and Kuwano, Y. Jpn. J. Appl. Phys., Part 1 31, 35183522 (1992).Google Scholar
6 Synopsys, Zurich, Switzerland, TCAD DEVICE Manual (2006), www.synopsys.comGoogle Scholar
7 Kanevce, A. and Metzger, W. K. J. Appl. Phys. 105 094507 (2009).Google Scholar