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Dechannealing Study of Nanocrystalline Si:H Layers Produced by High Dose Hydrogen Irradiation of Silicon Crystals

Published online by Cambridge University Press:  09 August 2011

V. P. Popov
Affiliation:
Institute of Semiconductor Physics, 630090 Novosibirsk, popov@isp.nsc.ru
A. K. Gutakovsky
Affiliation:
Institute of Semiconductor Physics, 630090 Novosibirsk, popov@isp.nsc.ru
I. V. Antonova
Affiliation:
Institute of Semiconductor Physics, 630090 Novosibirsk, popov@isp.nsc.ru
K. S. Zhuravlev
Affiliation:
Institute of Semiconductor Physics, 630090 Novosibirsk, popov@isp.nsc.ru
E. V. Spesivtsev
Affiliation:
Institute of Semiconductor Physics, 630090 Novosibirsk, popov@isp.nsc.ru
I. I. Morosov
Affiliation:
Institute of Nuclear Physics, 630090 Novosibirsk, Russia
G. P. Pokhil
Affiliation:
Research Institute of Nuclear Physics, MSU, Moscow, Russia.
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Abstract

A study of Si:H layers formed by high dose hydrogen implantation (up to 3x107cm-2) using pulsed beams with mean currents up 40 mA/cm2 was carried out in the present work. The Rutherford backscattering spectrometry (RBS), channeling of He ions, and transmission electron microscopy (TEM) were used to study the implanted silicon, and to identify the structural defects (a-Si islands and nanocrystallites). Implantation regimes used in this work lead to creation of the layers, which contain hydrogen concentrations higher than 15 at.% as well as the high defect concentrations. As a result, the nano- and microcavities that are created in the silicon fill with hydrogen. Annealing of this silicon removes the radiation defects and leads to a nanocrystalline structure of implanted layer. A strong energy dependence of dechanneling, connected with formation of quasi nanocrystallites, which have mutual small angle disorientation (<1.50), was found after moderate annealing in the range 200-500°C. The nanocrystalline regions are in the range of 2-4 nm were estimated on the basis of the suggested dechanneling model and transmission electron microscopy (TEM) measurements. Correlation between spectroscopic ellipsometry, visible photoluminescence, and sizes of nanocrystallites in hydrogenated nc-Si:H is observed.

Type
Research Article
Copyright
Copyright © Materials Research Society 1999

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