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Thin Film Properties of LPCVD TiN Barrier for Silicon Device Technology

Published online by Cambridge University Press:  15 February 2011

Rama I. Hegde
Affiliation:
Advanced Products Research and Development Laboratory, Motorola, Inc., 3501 Ed Bluestein Boulevard, Austin, Texas 78721
Robert W. Fiordalice
Affiliation:
Advanced Products Research and Development Laboratory, Motorola, Inc., 3501 Ed Bluestein Boulevard, Austin, Texas 78721
Edward O. Travis
Affiliation:
Advanced Products Research and Development Laboratory, Motorola, Inc., 3501 Ed Bluestein Boulevard, Austin, Texas 78721
Philip J. Tobin
Affiliation:
Advanced Products Research and Development Laboratory, Motorola, Inc., 3501 Ed Bluestein Boulevard, Austin, Texas 78721
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Abstract

Thin film properties of LPCVD TiN barriers deposited on Si(100), using TiCl4 and NH3 as reactants, were investigated as a function of deposition temperature between 400 °C and 700 °C. The TiN film chemistry and film composition were studied by AES and RBS techniques, while the microstructural properties (grain size, lattice parameter and texture) were evaluated by XRD. The TiN deposition rates and film resistivities were also determined. Finally the film properties of the TiN barriers as determined by surface analysis were related to the process parameters.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

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References

1. Travis, E. O., Paulson, W. M., Pintchovski, F., Boeck, B., Parrillo, L. C., Kottke, M. L., Fu, K. -Y., Rice, M. J., Price, J. B., Eichman, E. C., IEDM (1990) 47.Google Scholar
2. Pintchovski, F., White, T., Travis, E., Tobin, P. J., and Price, J. B., in Tungsten and Other Refractory Metals for VLSI Applications IV edited by Blewer, R. S. and McConica, C. M. (Mater. Res. Soc. Proc. Pennsylvania 1989) pp. 275282.Google Scholar
3. Srinivas, D., Hillman, J. T., Triggs, W. and Eichman, E. C., Advanced Metallization for ULSI Applications MRS (1992) (to be published).Google Scholar
4. Hegde, R. I., Jones, R. E. Jr., Kaushik, V. S., and Tobin, P. J., Appl. Surface Science 52 (1991) 59.CrossRefGoogle Scholar
5. Buiting, M. J., Otterloo, A. F. and Montree, A. H., J. Electrochem. Soc. 138 (1991) 265.Google Scholar
6. Sherman, A., J. Electrochem. Soc. 137 (1990) 1892.Google Scholar
7. Raaijmakers, I. J. and Sherman, A., IEEE 1990 219.Google Scholar
8. Yokoyama, N., Hinode, K. and Homma, Y., J. Electrochem. Soc. 13 (1991) 190.Google Scholar
9. Kurtz, S. R. and Gordon, R. G., Thin Solid Films, 140 (1986) 277.Google Scholar
10. Wu, H. Z., Chou, T. C., Mishra, A., Anderson, D. R., Lampert, J. K. and Gujrathi, S. C., Thin Solid Films, 191 (1990) 55.Google Scholar