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Synthesis, spectroscopic and electrochemical characterization of hybrid membranes for Polymer Electrolyte Membrane Fuel Cells.

Published online by Cambridge University Press:  01 February 2011

Maria Luisa Di Vona
Affiliation:
Department of Chemical Science and Technology, Università di Roma Tor Vergata, Via della Ricerca Scientifica 1, 00133 Rome, Italy.
Debora Marani
Affiliation:
Department of Chemical Science and Technology, Università di Roma Tor Vergata, Via della Ricerca Scientifica 1, 00133 Rome, Italy.
Alessandra D'Epifanio
Affiliation:
Department of Chemical Science and Technology, Università di Roma Tor Vergata, Via della Ricerca Scientifica 1, 00133 Rome, Italy.
Enrico Traversa
Affiliation:
Department of Chemical Science and Technology, Università di Roma Tor Vergata, Via della Ricerca Scientifica 1, 00133 Rome, Italy.
Marcella Trombetta
Affiliation:
Interdisciplinary Center for Biomedical Research (CIR), Laboratory of Biomaterials, Università “Campus Bio-Medico”, via E. Longoni 83, 00155 Rome, Italy
Silvia Licoccia
Affiliation:
Department of Chemical Science and Technology, Università di Roma Tor Vergata, Via della Ricerca Scientifica 1, 00133 Rome, Italy.
Stefano Caldarelli
Affiliation:
TRACES (JE 2421), Université de Provence, Centre St Jérôme, 13397 Marseille Cedex 20, France.
Philippe Knauth
Affiliation:
MADIREL (UMR 6121 CNRS), Université de Provence, Centre St Jérôme, 13397 Marseille Cedex 20, France.
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Abstract

Commercial polyether-etherketone was sulfonated and reacted with SiCl4 to obtain a hybrid polymer. Polymers having different inorganic content were characterized by 29Si NMR, ATR/FTIR spectroscopies and mass spectrometry (FAB-MS) demonstrating the formation of covalent bonds between the organic and inorganic components and the absence of dispersed inorganic silicon. The physicochemical properties of the hybrids were suitable for the preparation of membranes which showed sufficiently high conductivity values to make them promising candidates for application in PEMFCs.

Type
Research Article
Copyright
Copyright © Materials Research Society 2005

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Synthesis, spectroscopic and electrochemical characterization of hybrid membranes for Polymer Electrolyte Membrane Fuel Cells.
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