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Synthesis and characterization of periodic porous benzene-silica hybrid powders with cubic and hexagonal symmetries

Published online by Cambridge University Press:  01 February 2011

Valérie Goletto
Affiliation:
Chimie de la Matière Condensée, UPMC/CNRS, Paris, France. fb@ccr.jussieu.fr
Anne-Claire Bled
Affiliation:
Chimie de la Matière Condensée, UPMC/CNRS, Paris, France. fb@ccr.jussieu.fr
Gregor Trimmel
Affiliation:
Chimie de la Matière Condensée, UPMC/CNRS, Paris, France. fb@ccr.jussieu.fr
Michel Wong Chi Man
Affiliation:
Département de Chimie Organique Fine, Université de Montpellier II, France.
Hee-Gweon Woo
Affiliation:
Dept. of Chemistry, Chonnam National University, Kwangju, Korea
Dominique Durand
Affiliation:
LURE, Université Paris-Sud, Orsay, France
Florence Babonneau
Affiliation:
Chimie de la Matière Condensée, UPMC/CNRS, Paris, France. fb@ccr.jussieu.fr
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Abstract

Organosilica powders with uniformly distributed bridging benzene groups have been synthesized from the condensation of bis- or tris-(triethoxysilyl)benzene in the presence of cetyltrimethylammoniumbromide. The syntheses were performed under strong acidic conditions and the organic groups were always incorporated without cleavage of the Si-C bonds as indicated by solid state MAS NMR studies. Depending on the nature of the precursors, materials with different ordering were obtained: a 2D-hexagonal (p6m) phase was formed from the 1,3-bis(triethoxysilyl)benzene, whereas the 1,4-bis(triethoxysilyl)benzene lead to a cubic Pm3n phase. The surfactant was removed either by solvent extraction or by controlled calcination, which did not affect the mesostructure of the materials.

Type
Research Article
Copyright
Copyright © Materials Research Society 2002

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