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Structure and Optical Property of Polymers Obtained by Solid-State Polymerization of a Tetraacetylene Compound

Published online by Cambridge University Press:  21 February 2011

Shuji Okada
Affiliation:
Research Institute for Polymers and Textiles, 1-1-4 Higashi, Tsukuba, Ibaraki 305, Japan
Hiro Matsuda
Affiliation:
Research Institute for Polymers and Textiles, 1-1-4 Higashi, Tsukuba, Ibaraki 305, Japan
Atsushi Masaki
Affiliation:
Research Institute for Polymers and Textiles, 1-1-4 Higashi, Tsukuba, Ibaraki 305, Japan
Hachiro Nakanishi
Affiliation:
Research Institute for Polymers and Textiles, 1-1-4 Higashi, Tsukuba, Ibaraki 305, Japan
Kikuko Hayamizu
Affiliation:
National Chemical Laboratory for Industry, 1-1-5 Higashi, Tsukuba, Ibaraki 305, Japan.
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Abstract

The polydiacetylene having diacetylenic substituents has been prepared by γ-ray irradiated solid-state polymerization of 15, 17, 19, 21- hexatriacontatetrayne. It has been found that the polymer can be converted into the di(polydiacetylene), i.e., a new type of the fused-ring polymer of conjugated 10π-electron system, by the subsequent heat-treatment in the solid-state.

Type
Research Article
Copyright
Copyright © Materials Research Society 1991

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References

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