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Rationalization of Electrical Properties of The NiS2-xSex System

Published online by Cambridge University Press:  16 February 2011

J.M. Honig*
Affiliation:
Department of Chemistry, Purdue University, West Lafayette, IN 47907-1393, Email:jmh@chem.purdue.edu
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Abstract

The electrical and optical properties of the NiS2-xSex system are interpreted in terms of a band structure diagram that places a Mott-Hubbard, correlation-split Ni 3deg and the S 3pσ* band in the vicinity of the Fermi level. A variety of seemingly problematic experimental findings are resolved by adoption of this hypothesis.

Type
Research Article
Copyright
Copyright © Materials Research Society 1999

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