Skip to main content Accessibility help
×
Home
Hostname: page-component-99c86f546-vl2kb Total loading time: 0.24 Render date: 2021-12-03T14:01:27.382Z Has data issue: true Feature Flags: { "shouldUseShareProductTool": true, "shouldUseHypothesis": true, "isUnsiloEnabled": true, "metricsAbstractViews": false, "figures": true, "newCiteModal": false, "newCitedByModal": true, "newEcommerce": true, "newUsageEvents": true }

Problems In Realistic Modelling Of Interfacial Reactions

Published online by Cambridge University Press:  26 February 2011

Charles W. Allen
Affiliation:
Dept. of Materials Science and Engineering, University of Notre Dame, Notre Dame, IN 46556
Gordon A Sargent
Affiliation:
Dept. of Materials Science and Engineering, University of Notre Dame, Notre Dame, IN 46556
Get access

Abstract

For modelling the reaction of chemically distinct materials in which intermediate alloy phases are formed a simple thermodynamic description is not adequate. Despite thermodynamic prediction of multiple product phases, a single phase generally forms first which is not necessarily that of greatest thermodynamic stability or of simplest structure. Such initial reaction processes may be modelled as metastable perltectoid (solid-solid) or perltectlc (solid-liquid) reactions, characterized by large thermodynamic driving forces with superimposed kinetic and morphological constraints. The interfacial reaction problem is reviewed in light of heterogeneous nucleation theory with emphasis on non-classical aspects.

Type
Research Article
Copyright
Copyright © Materials Research Society 1986

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Gõsele, U. and Tu, K. N., J. Appl. Phys., 53, 3252 (1982).CrossRefGoogle Scholar
[2] Ottavianl, G., in Thin Films and Interfaces II, edited by Baglin, J. E. E., Campbell, D. R. and Chu, W. K. (North-Holland Publishers, New York, 1984), p. 21.Google Scholar
[3] Pretorlus, R., in Thin Films and Interfaces II, edited by Baglin, J. E. E., Campbell, D. R. and Chu, W. K. (North-Holland Publishers, New York, 1984), pp. 15–20.Google Scholar
[4] Cahn, J. W. and Hilliard, J. E., J. Chem. Phys., 28, 258 (1958).CrossRefGoogle Scholar
[5] Aaronson, H. I. and Russell, K. C., in Solid→Solid Phase Transformations, edited by Aaronson, H. I. et al, (The Metallurgical Society of AIME, 1982), pp. 371397.Google Scholar
[6] Cahn, J. W. and Hilliard, J. E., J. Chem. Phys., 31, 688 (1959).CrossRefGoogle Scholar
[7] Cahn, J. W., Acta Met., 9, 795 (1961); 10, 179 (1962).CrossRefGoogle Scholar
[8] Russell, K. C., Adv. in Colloid and Interface Sci., 13, 205 (1980).CrossRefGoogle Scholar
[9] Hilliard, J. E., in Phase Transformations, (ASM, Metals Park, 1970), pp.497560.Google Scholar
[10] Allen, C.W., Fulcher, M. R., Rai, A. S., Sargent, G. A. and Miller, A. E., inElectronic Packaging Materials Science, edited by Geiss, E. A., Tu, K.-N. and Uhlmann, D. R. (Materials Research Society, Pittsburgh, 1985), pp. 139144.Google Scholar

Send article to Kindle

To send this article to your Kindle, first ensure no-reply@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about sending to your Kindle. Find out more about sending to your Kindle.

Note you can select to send to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be sent to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Problems In Realistic Modelling Of Interfacial Reactions
Available formats
×

Send article to Dropbox

To send this article to your Dropbox account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Dropbox.

Problems In Realistic Modelling Of Interfacial Reactions
Available formats
×

Send article to Google Drive

To send this article to your Google Drive account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Google Drive.

Problems In Realistic Modelling Of Interfacial Reactions
Available formats
×
×

Reply to: Submit a response

Please enter your response.

Your details

Please enter a valid email address.

Conflicting interests

Do you have any conflicting interests? *