Skip to main content Accessibility help
×
Home
Hostname: page-component-55597f9d44-t4qhp Total loading time: 0.358 Render date: 2022-08-07T16:21:05.600Z Has data issue: true Feature Flags: { "shouldUseShareProductTool": true, "shouldUseHypothesis": true, "isUnsiloEnabled": true, "useRatesEcommerce": false, "useNewApi": true } hasContentIssue true

Platinum Clusters with Phosphide Ligands: Synthesis and Characterization

Published online by Cambridge University Press:  15 February 2011

Ilya I. Moiseev
Affiliation:
Institute of General & Inorganic Chemistry, Russian Academy of Sciences, Moscow
N. Yu. Kozitsyna
Affiliation:
Institute of General & Inorganic Chemistry, Russian Academy of Sciences, Moscow
D. I. Kochubey
Affiliation:
Institute of Catalysis, Russian Academy of Sciences, 630090 Novosibirsk
K. I. Zamaraev
Affiliation:
Institute of Catalysis, Russian Academy of Sciences, 630090 Novosibirsk
Get access

Extract

Reduction of triphenylphosphine-containing Pt(II) complexes with H2, HCOOH and Na-amalgam was studied to compare the results with those for similar reductions of analogous Pd(II) complexes. Clusters of compositions [Pt(PPh2)]n, n=6–10, have been found to be the products of the reduction reactions under consideration.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1. Vargaftik, M.N., Zagorodnikov, V.P., Stolarov, I.P., Moiseev, I.I., Kochubey, D.I., Likholobov, V.A., Chuvilin, A.L., Zamaraev, k.I., J.Molec.Cat.53, 315 (1989).CrossRefGoogle Scholar
2. Berenblyum, A.S., Kniznik, A.G., Mund, S.L., Moiseev, I.I., J.Organomet.Chem. 234, 219 (1982).CrossRefGoogle Scholar
3. Dobson, A., Robinson, S.P., Platinum Met. Rev., 1976, 20, 56; A. S. Berenblum, T.G. Goranskaya, S.L. Mund, I.I. Moiseev, Izv.Akad. Nauk SSSR, Ser.Khim. 1979, (6), 1387.Google Scholar
4. Hartley, F.R., Searle, G.W., Inorg.Chem.12, 1949 (1973).CrossRefGoogle Scholar
5. Powell, J., Jack, T., Inorg.Chem. 11, 1039 (1972).CrossRefGoogle Scholar
6. Bhaduri, S., Sharma, K., Jones, P.J., Erdbrugger, C.F.,.J.Organomet. Chem. 326, C4648 (1987).CrossRefGoogle Scholar
7. Burrows, A.D., Jeffrey, J.G., Machell, J.C., Mingos, D.M.P., J.Organomet. Chem. 406, 399 (1991).CrossRefGoogle Scholar
8. Kozitsyna, N.Yu., Dikareva, L.M., Andrianov, V.I., Zinchenko, S.V., Khutoryanskii, V.A., Schmidt, F.K., Porai-Koshits, M.A., Moiseev, I.I., Izv.Akad. Nauk SSSR, Ser.Khim. 1988, (8), 1894.Google Scholar
9. Kozitsyna, N. Yu., Surashskaya, M V., Larina, T. B., Kozmin, P. A., Kotelnikova, A. C., Moiseev, I. I., Izv.Akad. Nauk SSSR, Ser.Khim. 1989, (7), 1894.Google Scholar
10. Kozitsyna, N.Yu., Ellern, A.M., Antipin, M.Yu., Struchkov, Yu.T., Moiseev, I.I., Mendeleev Commun., 1991, (3), 92.CrossRefGoogle Scholar
11. Hursthouse, M.B., Sloan, O.D., Thornton, P., Walker, N.P.C., Polyhedron 5(9), 1475 (1986).CrossRefGoogle Scholar

Save article to Kindle

To save this article to your Kindle, first ensure coreplatform@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about saving to your Kindle.

Note you can select to save to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be saved to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Platinum Clusters with Phosphide Ligands: Synthesis and Characterization
Available formats
×

Save article to Dropbox

To save this article to your Dropbox account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you used this feature, you will be asked to authorise Cambridge Core to connect with your Dropbox account. Find out more about saving content to Dropbox.

Platinum Clusters with Phosphide Ligands: Synthesis and Characterization
Available formats
×

Save article to Google Drive

To save this article to your Google Drive account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you used this feature, you will be asked to authorise Cambridge Core to connect with your Google Drive account. Find out more about saving content to Google Drive.

Platinum Clusters with Phosphide Ligands: Synthesis and Characterization
Available formats
×
×

Reply to: Submit a response

Please enter your response.

Your details

Please enter a valid email address.

Conflicting interests

Do you have any conflicting interests? *