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Phosphazene Backbones for Siloxanes and Organic Polymers

Published online by Cambridge University Press:  10 February 2011

Guido Kickelbick
Affiliation:
Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15217
Peter J. Miller
Affiliation:
Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15217
Krzysztof Matyjaszewski
Affiliation:
Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15217
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Abstract

2,2,4,4,6,6-Hexachlorocyclotriphosphazene was modified by nucleophilic substitution to obtain building blocks for organic polymers and siloxane networks. 2,2,4,4,6,6-Hexachlorocyclotriphosphazene was substituted with functional groups to enable atom transfer radical polymerization (ATRP) as well as silicon alkoxide as precursors for the sol-gel process. ATRP was carried out with methyl acrylate followed by a chain extension with iso-bornyl acrylate to obtain new thermoplastic elastomers. The sol-gel process was carried out with acid, base and fluoride catalysts and the resulting materials were compared by TGA and DSC measurements.

Type
Research Article
Copyright
Copyright © Materials Research Society 1999

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References

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