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Investigations Of Solid Solutions Of CsBi4Te6

Published online by Cambridge University Press:  01 February 2011

Duck-Young Chung
Affiliation:
Department of Chemistry, Michigan State University, East Lansing, MI 48824.
Tim P. Hogan
Affiliation:
Department of Chemistry, Michigan State University, East Lansing, MI 48824.
Nishant Ghelani
Affiliation:
Dept of Electrical Engineering, Michigan State University, East Lansing, MI 48824.
Paul W. Brazis
Affiliation:
Dept of Electrical and Computer Engineering, Northwestern University, Evanston, IL 60208.
Melissa A. Lane
Affiliation:
Dept of Electrical and Computer Engineering, Northwestern University, Evanston, IL 60208.
Carl R. Kannewurf
Affiliation:
Dept of Electrical and Computer Engineering, Northwestern University, Evanston, IL 60208.
Mercouri G. Kanatzidis
Affiliation:
Department of Chemistry, Michigan State University, East Lansing, MI 48824.
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Abstract

Results on the synthesis and characterization of the solid solutions CsBi4-xSbxTe6, CsBi4Te6-ySey, as well as doping experiments on CsBi4Te6 are reported. We report X-ray structural investigations showing that the Sb or Se atoms in these compounds are not uniformly distributed in the lattice but show preferential occupation of specific crystallographic sites. Thermoelectric properties of selected systems are presented.

Type
Research Article
Copyright
Copyright © Materials Research Society 2000

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References

1. Chung, Duck-Young, Hogan, Tim, Brazis, Paul, Rocci-Lane, Melissa, Kannewurf, Carl, Bastea, Marina, Uher, Ctirad and Kanatzidis, Mercouri G., Science, 287, 1024 (2000).Google Scholar
2 Pauling, L., “The Nature of The Chemical Bond”, 3rd Ed. Cornell (1960).Google Scholar
3 Larson, P., Mahanti, B., Chung, D.-Y., Kanatzidis, M. G., See elsewhere in this volume.Google Scholar
4. Chung, Duck-Young, Hogan, Tim, Brazis, Paul, Rocci-Lane, Melissa, Kannewurf, Carl, Bastea, Marina, Uher, Ctirad and Kanatzidis, Mercouri G., manuscript in preparation.Google Scholar
5. Goldsmid, H. J. and Sharp, J. W., J. Electron. Mater. 28, 869 (1999).Google Scholar

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