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Enhancement of Third Order Nonlinearity on Phthalocyanine Compounds

Published online by Cambridge University Press:  21 February 2011

Masahiro Hosoda ,
Tatsuo Wada ,
Akira Yamada ,
Anthony F. Garitoa  and
Hiroyuki Sasabe
Masahiro Hosoda
Affiliation:
Frontier Research Program (RIKEN), Wako, Saitama 351-01, Japan
Tatsuo Wada
Affiliation:
Frontier Research Program (RIKEN), Wako, Saitama 351-01, Japan
Akira Yamada
Affiliation:
Frontier Research Program (RIKEN), Wako, Saitama 351-01, Japan
Anthony F. Garitoa
Affiliation:
Frontier Research Program (RIKEN), Wako, Saitama 351-01, Japan
Hiroyuki Sasabe
Affiliation:
Frontier Research Program (RIKEN), Wako, Saitama 351-01, Japan
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Abstract

The third order optical susceptibilities (−3ω; ω, ω ω,) for soluble metallophthalocyanine derivatives were determined by optical third harmonic generation measurements of molecularly doped polymer films at a wavelength of 1907nm. The X(3) value of tetra-tert-butylvanadylphthalocyanine is larger than that of metal-free derivative. We demonstrate experiment on modes of propagating light wave in molecularly doped films which exhibit excellent optical quality. The enhancement of third order optical nonlinear susceptibilities in phthalocyanine compounds are discussed in terms of molecular structure and molecular packing.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 175: Symposium S – Multifunctional Materials , 1989 , 89
Copyright
Copyright © Materials Research Society 1990

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