Hostname: page-component-7bb8b95d7b-495rp Total loading time: 0 Render date: 2024-10-06T22:12:14.089Z Has data issue: false hasContentIssue false

Electronic Structure of One-Dimensional Biradical Molecular Chain

Published online by Cambridge University Press:  22 January 2014

H. Koike
Affiliation:
Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510, Japan
K. Ogawa
Affiliation:
Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510, Japan
T. Kubo
Affiliation:
Osaka University, 1-1 Machikaneyama, Toyonaka, Osaka, 560-0043, Japan
K. Uchida
Affiliation:
Osaka University, 1-1 Machikaneyama, Toyonaka, Osaka, 560-0043, Japan
M. Chikamatsu
Affiliation:
National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki, 305-8565, Japan
R. Azumi
Affiliation:
National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki, 305-8565, Japan
K. Mase
Affiliation:
KEK, 1-1 Oho, Tsukuba, Ibaraki 305-0801, Japan
K. Kanai
Affiliation:
Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510, Japan
Get access

Abstract

We investigated electronic structure of one-dimensional biradical molecular chain which is constructed by exploiting the covalency between organic molecules of a diphenyl derivative of s-indacenodiphenalene (Ph2-IDPL). To control the crystallinity, we used gas deposition method. Ultraviolet photoelectron spectroscopy (UPS) revealed developed band structure with wide dispersion of the one-dimensional biradical molecular chain.

Type
Articles
Copyright
Copyright © Materials Research Society 2014 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Hasegawa, S., Mori, T., Imaeda, K., Tanaka, S., Yamashita, Y., Inokuchi, H., Fujimoto, H., Seki, K., and Ueno, N., J. Chem. Phys. 100, 6969 (1994).CrossRefGoogle Scholar
Kakuta, H., Hirahara, T., Matsuda, I., Nagao, T., Hasegawa, S., Ueno, N., and Sakamoto, K., Phys. Rev. Lett. 98, 247601 (2007).CrossRefGoogle Scholar
Kubo, T., Shimizu, A., Sakamoto, M., Uruichi, M., Yakushi, K., Nakano, M., Shiomi, D., Sato, K., Takui, T., Morita, Y., and Nakasuji, K., Angew. Chem. Int. Ed. 44, 6564 (2005).CrossRefGoogle Scholar
Kanai, K., Noda, Y., Kato, K., Kubo, T., Iketaki, K., Shimizu, A., Ouchi, Y., Nakasuji, K., and Seki, K., Phys. Chem. Chem. Phys. 12, 12570 (2010).CrossRefGoogle Scholar
Toyoshima, A., Kikuchi, T., Tanaka, H., Mase, K., Amemiya, K., and Ozawa, K., J. Phys.: Conf. Ser. 425, 152019 (2013).Google Scholar
Chikamatsu, M., Mikami, T., Chisaka, J., Yoshida, Y., Azumi, R., Yase, K., Shimizu, A., Kubo, T., Morita, Y., and Nakasuji, K., Appl. Phys. Lett. 91, 043506 (2007).CrossRefGoogle Scholar
Koike, H., Kubo, T., Uchida, K., Chikamatsu, M., Azumi, R., Mase, K., and Kanai, K., Appl. Phys. Lett. 102, 134103 (2013).CrossRefGoogle Scholar
Huang, J., Kertesz, M., J. Am. Chem. Soc., 129, 1634 (2007)CrossRefGoogle Scholar