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The diamond-solution interface: the surface energy of hydrogen terminated nanocrystalline CVD diamond derived from contact angle measurements

Published online by Cambridge University Press:  07 July 2011

Stoffe D. Janssens
Affiliation:
Institute for Materials Research (IMO), Hasselt University, BE-3590 Diepenbeek, Belgium
Sien Drijkoningen
Affiliation:
Institute for Materials Research (IMO), Hasselt University, BE-3590 Diepenbeek, Belgium
Marc Saitner
Affiliation:
Institute for Materials Research (IMO), Hasselt University, BE-3590 Diepenbeek, Belgium
Hans-Gerd Boyen
Affiliation:
Institute for Materials Research (IMO), Hasselt University, BE-3590 Diepenbeek, Belgium
Ken Haenen
Affiliation:
Institute for Materials Research (IMO), Hasselt University, BE-3590 Diepenbeek, Belgium IMOMEC, IMEC vzw, BE-3590 Diepenbeek, Belgium
Patrick Wagner
Affiliation:
Institute for Materials Research (IMO), Hasselt University, BE-3590 Diepenbeek, Belgium IMOMEC, IMEC vzw, BE-3590 Diepenbeek, Belgium
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Abstract

In this work, a determination of the surface energy for hydrogen terminated nanocrystalline diamond grown with microwave plasma enhanced chemical vapor deposition is presented. Five identical hydrogen terminated nanocrystalline diamond layers of ~150 nm thick are deposited on silicon substrates and examined with X-ray photoelectron spectroscopy to determine the surface groups and possible surface contaminations. In order to evaluate the surface energy, contact angle measurements are performed using the sessile drop method in combination with data analysis based on the ‘Owens, Wendt, Rabel and Kaelble’ method. Four different experimental approaches to evaluate the surface energy of hydrogen terminated nanocrystalline diamond are discussed.

Type
Research Article
Copyright
Copyright © Materials Research Society 2011

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References

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