Hostname: page-component-78c5997874-8bhkd Total loading time: 0 Render date: 2024-11-01T20:10:45.879Z Has data issue: false hasContentIssue false

Corrosion Protection of Metallic Waste Packages Using Thermal Sprayed Ceramic Coatings

Published online by Cambridge University Press:  10 February 2011

K. R. Wilfinger
Affiliation:
Lawrence Livermore National Lab, P.O. Box 808, L-355, Livermore, CA 94550
J. C. Farmer
Affiliation:
Lawrence Livermore National Lab, P.O. Box 808, L-355, Livermore, CA 94550
R. W. Hopper
Affiliation:
Lawrence Livermore National Lab, P.O. Box 808, L-355, Livermore, CA 94550
T. E. Shell
Affiliation:
Lawrence Livermore National Lab, P.O. Box 808, L-355, Livermore, CA 94550
Get access

Abstract

Ceramic coated carbon steel coupons were corrosion tested in water with dissolved salts to simulate exposure to evaporation concentrated groundwater in an underground nuclear repository. Metallography revealed no corrosion at the ceramic metal interface of dense coatings, even though electrical measurements demonstrated that the coatings were slightly porous. Experimental results and a model to predict corrosion rates influenced by a porous ceramic coating and coating lifetimes are presented.

Type
Research Article
Copyright
Copyright © Materials Research Society 1999

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. “Aluminum Oxide as an Encapsulation Material for Unreprocessed Nuclear Fuel Waste - Evaluation from the Viewpoint of Corrosion,” Final Report 1980-03-19, Swedish Corrosion Institute, Stockholm, Sweden, (1980).Google Scholar
2. Hopper, R., Ceramic Barrier Performance Model (V.1.0), Description and Initial PA Input Memorandum, Lawrence Livermore National Laboratory, Livermore, CA, March 30, 1998.Google Scholar
3. Henshall, G.A., “Numerical Predictions of Dry Oxidation of Iron and Low-Carbon Steel at Moderately Elevated Temperatures.” (UCRL-JC-124639) Lawrence Livermore National Laboratory, Livermore, CA, (1996).Google Scholar
4. Leygraf, C., Atmospheric Corrosion, Chapter 12 in Corrosion Mechanisms in Theory and Practice, edited by Marcus, P., and Oudar, J., Marcel Dekker, Inc., New York, 1995.Google Scholar
5. Sherwood, T.K., Pigford, P.L., and Wilke, C.R., Mass Transfer, McGraw-Hill, San Francisco, CA, (1975) pp. 178182.Google Scholar
6. Farmer, J.C., “Development of corrosion models for high-level waste containers.” In proceedings of the Sixth International Conference on Nuclear Engineering (ICONE-6). San Francisco, May 10-14, 1998. ASME. 13p.Google Scholar
7. Thornton, P.A., and Colangelo, V.J., Fundamentals of Engineering Materials. Prentice Hall, Englewood Cliffs, NJ, (1985).Google Scholar