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Carboxylate-Substituted Oxotitanium and Oxozirconium Clusters as Structural Models for Titania- and Zirconia-Based Inorganic-Organic Hybrid Materials

Published online by Cambridge University Press:  10 February 2011

Guido Kickelbick
Affiliation:
Institut für Anorganische Chemie der Technischen Universitä;t Wien, Getreidemarkt 9, A-1060 Wien, Austria, uschuber@fbch.tuwien.ac.at
Ulrich Schubert
Affiliation:
Institut für Anorganische Chemie der Technischen Universitä;t Wien, Getreidemarkt 9, A-1060 Wien, Austria, uschuber@fbch.tuwien.ac.at
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Abstract

Reaction of Ti(OR)4 or Zr(OR)4 with carboxylic acids resulted in the formation of crystalline carboxylate-substituted oxotitanium and oxozirconium clusters with different Ti/Zr : carboxylate ratios. Structural investigations showed that the cluster cores are rutile- or zirconia-like if the carboxylate : metal ratio does not exceed 1.33 (for Ti) or 2 (for Zr), respectively. When the carboxylate : metal ratio is increased beyond these values, more open clusters and eventually polymeric structures are obtained.

Type
Research Article
Copyright
Copyright © Materials Research Society 1998

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References

1 Sanchez, C. and In, M., J.Non-Cryst. Solids 147&148, 1 (1992)10.1016/S0022-3093(05)80584-8CrossRefGoogle Scholar
2 Schubert, U., , N. and Lorenz, N., Chem.Mater. 7, 2010 (1995).10.1021/cm00059a007CrossRefGoogle Scholar
3 Doeuff, S., Dromzee, Y., Taulelle, F. and Sanchez, C., Inorg.Chem. 28, 4439 (1989). I. Gautier-Luneau, A. Mosset and J. Galy, Z. Kristallogr. 180, 83 (1987). I.Laaziz, A.Larbot, C.Guizard, J.Durand and L.Cot, Acta Cryst. C46, 2332 (1990)10.1021/ic00324a006CrossRefGoogle Scholar
4 Schubert, U., Arpac, E., Helmerich, A. and Chau, C., Chem.Mater. 4, 291 (1992).10.1021/cm00020a014CrossRefGoogle Scholar
5 Kickelbick, G. and Schubert, U., Europ.J.Inorg.Chem. 159 (1998)Google Scholar
6 Kickelbick, G. and Schubert, U., Chem.Ber. 130, 473 (1997)10.1002/cber.19971300406CrossRefGoogle Scholar
7 Toledano, P., Ribot, F. and Sanchez, C., Compt.Rend.Acad.Sci. Paris, Ser. II 311 (1990) 1315.Google Scholar
8 Lorenz, A., Kickelbick, G. and Schubert, U., Chem. Mater. 9, 2551 (1997)10.1021/cm9702575CrossRefGoogle Scholar

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Carboxylate-Substituted Oxotitanium and Oxozirconium Clusters as Structural Models for Titania- and Zirconia-Based Inorganic-Organic Hybrid Materials
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Carboxylate-Substituted Oxotitanium and Oxozirconium Clusters as Structural Models for Titania- and Zirconia-Based Inorganic-Organic Hybrid Materials
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Carboxylate-Substituted Oxotitanium and Oxozirconium Clusters as Structural Models for Titania- and Zirconia-Based Inorganic-Organic Hybrid Materials
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