Skip to main content Accessibility help
×
Home
Hostname: page-component-544b6db54f-kbvt8 Total loading time: 0.214 Render date: 2021-10-24T13:12:56.715Z Has data issue: true Feature Flags: { "shouldUseShareProductTool": true, "shouldUseHypothesis": true, "isUnsiloEnabled": true, "metricsAbstractViews": false, "figures": true, "newCiteModal": false, "newCitedByModal": true, "newEcommerce": true, "newUsageEvents": true }

Anchoring of Organic Molecules on Cu(001) Surface Through S-Headgroup.

Published online by Cambridge University Press:  01 February 2011

P. Monachesi
Affiliation:
Dipartimento di Fisica, Università dell'Aquila and INFM, L'Aquila (Italy)
L. Chiodo
Affiliation:
Dipartimento di Fisica, Università di Roma, ‘Tor Vergata’ and INFM, Roma (Italy)
F. Bussolotti
Affiliation:
Dipartimento di Fisica, Università di Modena and INFM CRS-S3, Modena (Italy)
M. G. Betti
Affiliation:
Dipartimento di Fisica, Università di Roma, ‘La Sapienza’ and INFM CRS-SOFT, Roma (Italy)
C. Mariani
Affiliation:
Dipartimento di Fisica, Università di Roma, ‘La Sapienza’ and INFM CRS-S3, Roma (Italy)
Get access

Abstract

We characterize, experimentally and theoretically, the electronic properties of the S/Cu(001) interface in two molecule-metal systems, Mercaptobenzoxazole(MBO) and Methanethiol on Cu(001), containing the S-headgroup. The S atom realizes the anchoring of the whole molecule to the substrate through the formation of an S-Cu hybrid, irrespective of the p(2×2) and c(2×2) reconstruction, but with different relative orbital contributions. This behaviour may be highlighted only by the comparison of the high resolution angular resolved photoemission spectra with the ab inito calculated electronic density of states of the interface.

Type
Research Article
Copyright
Copyright © Materials Research Society 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1] Norskov, J.K. and Hammer, B. in Chemisorption and Reactivity of supported clusters in thin films, ed. By Lambert, R.M. and Pacchioni, G. (Kluwer Academic, the Netherlands, 1997)Google Scholar
[2] Mariani, C., Allegretti, F., Corradini, V., Contini, G., Castro, V. D., Baldacchini, C., and Betti, M. G., Phys. Rev. B 66, 115407 (2002)CrossRefGoogle Scholar
[3] Monachesi, P., Chiodo, L. and Sole, R. Del, Phys. Rev. B 69, 165404 (2004)CrossRefGoogle Scholar
[4] Kondoh, H., Saito, N., Matsui, F., Yokoyama, T., Ohta, T. and Kuroda, H., J. Phys. Chem B 105, 1287 (2001)Google Scholar
[5] Vollmer, S., Witte, G. and Woell, C., Langmuir 17, 7560 (2001)CrossRefGoogle Scholar
[6] Driver, S.M. and Woodruff, D.P., Surface Science 488, 207 (2001)CrossRefGoogle Scholar
[7] Bussolotti, F., Corradini, V., Castro, V. Di, Betti, M.G., Mariani, C., Surface Science, 566-568, 591 (2004)CrossRefGoogle Scholar
[8] Zeng, H.C., McFarlane, R. A., Mitchell, K.A.R., Phys. Rev. B 39, 8000 (1989)CrossRefGoogle Scholar
[9] Wittenau, A.E. Schach von, Hussain, Z., Wand, L.Q., Huang, Z., Ji, Z.G. and Shirley, D.A., Phys. Rev. B 45, 9291 (1992)Google Scholar
[10] McGrath, R., MacDowell, A. A., Hashizume, T., Sette, F. and Citrin, P. H., Phys. Rev. Lett. 64, 575 (1990)CrossRefGoogle Scholar
[11] Wills, J. and Cooper, B. R., Phys. Rev. B 36, 3809 (1987).CrossRefGoogle Scholar
[12] Andersen, O. K., Phys. Rev. B 12, 3060 (1975)CrossRefGoogle Scholar
[13] Kohn, W. and Sham, L. J., Phys. Rev. 140, A1133 (1965)CrossRefGoogle Scholar
[14] Barth, U. von and Hedin, L., J. Phys. C 5, 1629 (1972)Google Scholar
[15] Jepsen, O. and Andersen, O. K., Solid State Comm. 9, 1763 (1971)CrossRefGoogle Scholar

Send article to Kindle

To send this article to your Kindle, first ensure no-reply@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about sending to your Kindle. Find out more about sending to your Kindle.

Note you can select to send to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be sent to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Anchoring of Organic Molecules on Cu(001) Surface Through S-Headgroup.
Available formats
×

Send article to Dropbox

To send this article to your Dropbox account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Dropbox.

Anchoring of Organic Molecules on Cu(001) Surface Through S-Headgroup.
Available formats
×

Send article to Google Drive

To send this article to your Google Drive account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Google Drive.

Anchoring of Organic Molecules on Cu(001) Surface Through S-Headgroup.
Available formats
×
×

Reply to: Submit a response

Please enter your response.

Your details

Please enter a valid email address.

Conflicting interests

Do you have any conflicting interests? *