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Nanodiode-based hot electrons: Influence on surface chemistry and catalytic reactions

Published online by Cambridge University Press:  10 January 2020

Jeong Young Park  and
Gabor A. Somorjai
Jeong Young Park
Affiliation:
Center for Nanomaterials and Chemical Reactions, Institute for Basic Science; and Department of Chemistry, Korea Advanced Institute of Science and Technology, Republic of Korea; jeongypark@kaist.ac.kr
Gabor A. Somorjai
Affiliation:
University of California, Berkeley, USA; somorjai@berkeley.edu
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Abstract

Understanding fundamental mechanisms for surface electronic excitation is of great importance in surface chemistry. Charge transport through metal–oxide interfaces plays a significant role in heterogeneous catalysis. Over the last several decades, a number of experimental and theoretical results suggest that this charge flow through metal–support interfaces leads to catalytic enhancement often observed in mixed catalysts. Direct measurement of charge flow on actual catalysts is a rather challenging task because it requires the use of an electronic circuit. This approach has been enabled by a catalytic nanodiode that is mainly composed of a catalytic metal and semiconducting oxides that form a Schottky contact. In this article, we describe the advances in this approach. We show that there is close connection between the phenomena of hot-electron creation and chemical reaction that occur at both gas–solid and liquid–solid interfaces. The intensity of hot-electron flow is well correlated with the turnover rates of corresponding reactions, which opens the possibility for developing new operando methodologies to monitor catalytic reactions as well as a novel scheme for the electronic control of chemical reactions.

Type
Materials for Hot-Carrier Chemistry
Information
MRS Bulletin , Volume 45 , Issue 1: Materials for Hot-Carrier Chemistry , January 2020 , pp. 26 - 31
Copyright
Copyright © Materials Research Society 2020

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