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Vitreous Materials for Nuclear Waste Immobilisation and IAEA Support Activities

Published online by Cambridge University Press:  20 February 2017

Rebecca A. Robbins*
Affiliation:
Department of Nuclear Energy, International Atomic Energy Agency, Vienna International Centre, PO Box 100, 1400 Vienna, Austria
Michael I. Ojovan
Affiliation:
Department of Nuclear Energy, International Atomic Energy Agency, Vienna International Centre, PO Box 100, 1400 Vienna, Austria
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Abstract

Vitreous materials are the overwhelming world-wide choice for the immobilisation of HLW resulting from nuclear fuel reprocessing due to glass tolerance for the chemical elements found in the waste as well as its inherent stability and durability. Vitrification is a mature technology and has been used for high-level nuclear waste immobilization for more than 50 years. Borosilicate glass is the formulation of choice in most applications although other formulations are also used e.g. phosphate glasses are used to immobilize high level wastes in Russia. The excellent durability of vitrified radioactive waste ensures a high degree of environment protection. Waste vitrification gives high waste volume reduction along with simple and cheap disposal facilities. Although vitrification requires a high initial investment and then operational costs, the overall cost of vitrified radioactive waste is usually lower than alternative options when account is taken of transportation and disposal expenses. Glass has proven to be also a suitable matrix for intermediate and low-level radioactive wastes and is currently used to treat legacy waste in USA, and NPP operational waste in Russia and South Korea. This report is also outlining IAEA activities aiming to support utilisation of vitreous materials for nuclear waste immobilisation.

Type
Articles
Copyright
Copyright © Materials Research Society 2017 

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References

REFERENCES

Jantzen, C.M.. Historical development of glass and ceramic waste forms for high level radioactive waste. In: Ojovan, M. Handbook of advanced radioactive waste conditioning technologies. Woodhead, Cambridge. 159-172 (2011).Google Scholar
Donald, I.W.. Waste Immobilisation in Glass and Ceramic Based Hosts. Wiley, Chichester (2010).Google Scholar
Caurant, D., Loiseau, P., Majérus, O., Aubin Chevaldonnet, V., Bardez, I., Quintas, A.. Glasses, Glass-Ceramics and Ceramics for Immobilization of Highly Radioactive Nuclear Wastes. Nova, New York (2009).Google Scholar
Ojovan, M.I., Lee, W.E.. New Developments in Glassy Nuclear Wasteforms, Nova, New York, 131p (2007).Google Scholar
Pegg, I.L., Joseph, I.. Vitrification. In: Hazardous and radioactive waste treatment technologies handbook. Ed. Ho Oh, C., CRC Press, Boca Raton, 4.2.1-27 (2001).Google Scholar
Ozhovan, M.I.. Topological characteristics of bonds in SiO2 and GeO2 oxide systems at glass-liquid transition. J. Exp. Theor. Phys., 103 (5) 819829 (2006).CrossRefGoogle Scholar
Marra, J.C., Ojovan, M.I.. Vitrification of Radioactive Wastes. Glass International, 37 (4), 19-21 (2014).Google Scholar
Ojovan, M.I., Lee, W.E.. Glassy wasteforms for nuclear waste immobilisation. Metallurgical and Materials Transactions A, 42(4), 837851 (2011).Google Scholar
Ojovan, M.I., Juoi, J.M., Boccaccini, A.R., Lee, W.E.. Glass Composite Materials for Nuclear and Hazardous Waste Immobilisation. Mater. Res. Soc. Symp. Proc., 1107, 245252 (2008).Google Scholar
Gin, S., Abdelouas, A., Criscenti, L.J., Ebert, W.L., Ferrand, K., Geisler, T., Harrison, M.T., Inagaki, Y., Mitsui, S., Mueller, K.T., Marra, J.C., Pantano, C.G., Pierce, E.M., Ryan, J.V., Shoefield, J.M., Steefel, C.I., Vienna, J.D.. An international initiative on long-term behaviour of high-level nuclear waste glass. Materials Today, 16 (6) 243248 (2013).CrossRefGoogle Scholar
Samanta, S.K., Drace, Z., Ojovan, M.. An Overview of IAEA Activities to Support Predisposal Management of Radioactive Wastes in Member States. Proc. WM2012 Conference, February 26-March 1, 2012, Phoenix, Arizona, WM – 12334, 10 p. (2012).Google Scholar