Skip to main content Accessibility help
×
Home
Hostname: page-component-5d6d958fb5-8cb25 Total loading time: 0.187 Render date: 2022-11-27T03:44:21.224Z Has data issue: true Feature Flags: { "shouldUseShareProductTool": true, "shouldUseHypothesis": true, "isUnsiloEnabled": true, "useRatesEcommerce": false, "displayNetworkTab": true, "displayNetworkMapGraph": false, "useSa": true } hasContentIssue true

Article contents

Synthesis and Characterization of Hydrotalcite like Compound via a Facile Solid State Method

Published online by Cambridge University Press:  30 June 2016

Abbas Fahami*
Affiliation:
Materials Science, Engineering and Commercialization Program, Texas State University, San Marcos TX, 78666, U.S.A.
Gary W. Beall
Affiliation:
Department of Chemistry and Biochemistry, Texas State University, 601 University Drive, San Marcos, TX, 78666, U.S.A. Physics Department, Faculty of Science, King Abdulaziz University, Jeddah, 21589, Saudi Arabia.
*
*Corresponding author. Tel.: +15129600009; fax: +15122453675 E-mail address: fahami@txstate.edu.
Get access

Abstract

Carbonate intercalated Mg-Al layered double hydroxides (Mg-Al-CO3-LDH) were successfully produced by mechanical alloying process using different starting raw chemicals. Two distinct chemical reactions were activated at different milling times. The samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), energy dispersive spectroscopy (EDS), and transmission electron microscopy (TEM). Results revealed that the structural characteristics of Mg-Al-CO3-LDH such as lattice parameters, unit cell volume, and the interlayer spacing were affected strongly by milling time. Based on the XRD data, the formation rate of pure Hydrotalcite (HT) was strongly influenced by the chemical composition of raw materials. Electron microscopic observation displayed that the final product had a platelet-like structure with an average particle size of 20-100 nm. Therefore, the synthesis of Mg-Al-CO3-LDH via a cost-effective solid-state method owing to simplicity and reproducibility can be a promising candidate especially for use in biomaterials and catalyst industries.

Type
Articles
Copyright
Copyright © Materials Research Society 2016 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Hibino, T., Tsunashima, A., Chem. Mater.9, 2082 (1997).CrossRef
Cantú, M., López-Salinas, E., Valente, J.S., Montiel, R., Environ. Sci. Technol.39, 9715 (2005).CrossRef
Wang, S., Yan, S., Ma, X., Gong, J., Energy Environ. Sci.4, 3805 (2011).CrossRef
Wang, X., Deng, R., Kulkarni, S.A., Wang, X., Pramana, S.S., Wong, C.C., Grätzel, M., Uchida, S., Mhaisalkar, S.G., J. Mater. Chem. A.1, 4345 (2013).CrossRef
Sampieri, A., Fetter, G., Villafuerte-Castrejon, M. E., Tejeda-Cruz, A., Bosch, P., Beilstein J. Nanotechnol.2, 99 (2011).CrossRef
Wang, Q., Tay, H. H., Guo, Z., Chen, L., Liu, Y., Chang, J., Zhong, Z., Luo, J., Borgna, A., Appl. Clay Sci. 55, 18 (2012).CrossRef
Fahami, A., Beall, G. W., J. Solid State Chem.233, 422 (2016).CrossRef
Brei, V.V., Melezhyk, O.V., Starukh, G.M., Oranskaya, E.I., Mutovkin, P.A., Microporous Mesoporous Mater. 113, 411 (2008).CrossRef
Zhao, H., Nagy, K. L., J. Colloid & Interfacial Sci.274, 613 (2004).CrossRef
Choy, J. H., Choi, S. J., Oh, J. M., Park, T., Appl. Clay Sci.36, 122 (2007).CrossRef
Fahami, A., Ebrahimi-Kahrizsangi, R., Nasiri-Tabrizi, B. Solid State Sci.13, 135 (2011).CrossRef
Nasiri-Tabrizi, B., Fahami, A., Ebrahimi-Kahrizsangi, R., Ceram. Int. 39, 5751 (2013).CrossRef
Ay, A. N., Zümreoglu-Karan, B., Mafra, L., Z. Anorg. Allg. Chem.635, 1470 (2009).CrossRef
Fahami, A., Nasiri-Tabrizi, B., Ceram. Int.40, 14939 (2014).CrossRef
Nasiri-Tabrizi, B., Fahami, A., Ebrahimi-Kahrizsangi, R., J. Ind. Eng. Chem. 20, 245 (2014).CrossRef

Save article to Kindle

To save this article to your Kindle, first ensure coreplatform@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about saving to your Kindle.

Note you can select to save to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be saved to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Synthesis and Characterization of Hydrotalcite like Compound via a Facile Solid State Method
Available formats
×

Save article to Dropbox

To save this article to your Dropbox account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you used this feature, you will be asked to authorise Cambridge Core to connect with your Dropbox account. Find out more about saving content to Dropbox.

Synthesis and Characterization of Hydrotalcite like Compound via a Facile Solid State Method
Available formats
×

Save article to Google Drive

To save this article to your Google Drive account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you used this feature, you will be asked to authorise Cambridge Core to connect with your Google Drive account. Find out more about saving content to Google Drive.

Synthesis and Characterization of Hydrotalcite like Compound via a Facile Solid State Method
Available formats
×
×

Reply to: Submit a response

Please enter your response.

Your details

Please enter a valid email address.

Conflicting interests

Do you have any conflicting interests? *