Hostname: page-component-8448b6f56d-t5pn6 Total loading time: 0 Render date: 2024-04-23T14:41:42.564Z Has data issue: false hasContentIssue false
  • English
  • Français

The story of one diamond: the heterogeneous distribution of the optical centres within a diamond crystal from the Ichetju placer, northern Urals

Published online by Cambridge University Press:  08 May 2019

Evgeny Vasilev Open the ORCID record for Evgeny Vasilev [Opens in a new window] ,
Vitaly Petrovsky ,
Alexander Kozlov ,
Anton Antonov ,
Andrey Kudryavtsev  and
Ksenia Orekhova
Evgeny Vasilev*
Affiliation:
Saint-Petersburg Mining University, Saint-Petersburg, Russia
Vitaly Petrovsky
Affiliation:
Institute of Geology of the Komi Science Centre of the Ural Branch of the Russian Academy of Sciences, Syktyvkar, Russia
Alexander Kozlov
Affiliation:
Saint-Petersburg Mining University, Saint-Petersburg, Russia
Anton Antonov
Affiliation:
A.P. Karpinsky Russian Geological Research Institute, Saint-Petersburg, Russia
Andrey Kudryavtsev
Affiliation:
TESCAN Ltd, Saint-Petersburg, Russia
Ksenia Orekhova
Affiliation:
Ioffe Institute, Saint- Petersburg, Russia
*
*Author for correspondence: Evgeny Vasilev, Email: simphy12@mail.ru
Get access Rights & Permissions [Opens in a new window]

Abstract

We have investigated a diamond crystal that consists of several misorientated subgrains. The main feature of the crystal is the dark areas in the cathodoluminescent core that has ‘estuary-like’ boundaries extending along the subgrain interfaces. The core has >3100 ppm of nitrogen, and the share of the B form is >95%; the absorbance of the centre N3VH at 3107 cm–1 reaches 75 cm–1. The N3 centre absorbance, as well as N3 luminescence, is absent in the core. In the outer part of the crystal, bright blue luminescence of the N3 centre is apparent, and the N3 absorbance reaches 5.3 cm–1. These observations could be explained by the conversion of N3 centres to N3VH after attaching a hydrogen atom. After the full conversion of the N3 centres, the diamond becomes darker under CL. We hypothesise the dark core has a specific shape due to the post-growth diffusion of the hydrogen.

Keywords

diamondFTIRluminescencehydrogennitrogen
Type
Article
Information
Mineralogical Magazine , Volume 83 , Issue 4 , August 2019 , pp. 515 - 522
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2019 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

Footnotes

Associate Editor: Sergey V. Krivovichev

References

Boyd, S.R., Kiflawi, I. and Woods, G.S. (1994) The relationship between infrared absorption and the A defect concentration in diamond. Philosophical Magazine B, 69, 1149–1153.Google Scholar
Boyd, S.R., Kiflawi, I. and Woods, G.S. (1995) Infrared absorption by the B nitrogen aggregate in diamond. Philosophical Magazine B, 72, 351–361.Google Scholar
Clackson, S.G., Moore, M., Walmsley, J.С and Woods, G.S. (1990) The relationship between platelet size and the frequency of the B’ infrared absorption peak in type Ia diamond. Philosophical Magazine B, 62, 115–128.Google Scholar
Collins, A.T. (1992) The characterization of point defects in diamond by luminescence spectroscopy. Diamond and Related Materials, 1, 457–469.Google Scholar
De Weerdt, F. and Collins, A.T. (2006) Optical study of the annealing behavior of the 3107 cm− 1 defect in natural diamonds. Diamond and Related Materials, 15, 593–596.Google Scholar
Dishler, B. (2012). Handbook of Spectral Lines in Diamond. Springer-Verlag, Berlin-Heidelberg, 467 pp.Google Scholar
Dudar, V.A. (1996) North Timan placers. Ores and Metals, 4, 80–90.Google Scholar
Evans, T., Kiflawi, I., Luyten, W., Van Tendeloo, G. and Woods, G.S. (1995) Conversion of platelets into dislocation loops and voidite formation in type IaB diamonds. Proceedings of the Royal Society of London Series A – Mathematical and Physical Sciences, 1936, 295–313.Google Scholar
Gaft, M., Reisfeld, R., Panczer, G. (2015) Modern Luminescence Spectroscopy of Minerals and Materials. Springer-Verlag, Berlin-Heidelberg, 606 pp.Google Scholar
Goss, J.P., Goomer, B.J., Jones, R., Fall, C.J., Briddon, P.R. and Öberg, S. (2003) Extended defects in diamond: the interstitial platelet. Physical Review B, 16, 165–208.Google Scholar
Goss, J.P., Briddon, P.R., Hill, V., Jones, R. and Rayson, M.J. (2014) Identification of the structure of the 3107 cm−1 H–related defect in diamond. Journal of Physics – Condensed Matter, 26, 1–6.Google Scholar
Götze, J. and Kempe, U. (2009) Physical principles of cathodoluminescence (CL) and its applications in geosciences. Pp. 1–22 in: Cathodoluminescence and its application in the planetary sciences (Gucsik, A., editor). Springer, Berlin Heildelberg.Google Scholar
Howell, D., O'Neill, C.J., Grant, K.J., Griffin, W.L., O'Reilly, S.Y., Pearson, N.J., Stern, R.A. and Stachel, T. (2012) Platelet development in cuboid diamonds: insights from micro-FTIR mapping. Contributions Mineralogy Petrology, 164, 1011–1025.Google Scholar
Howell, D., Griffin, W., Piazolo, S., Say, J.M., Stern, R.A., Stachel, T., Nasdala, L., Rabeau, J.R., Pearson, N.J. and O'Reilly, S.I. (2013) A spectroscopic and carbon-isotope study of mixed-habit diamonds: Impurity characteristics and growth environment. American Mineralogist, 98, 66–77.Google Scholar
Kiflawi, I. and Bruley, J. (2000) The nitrogen aggregation sequence and the formation of voidites in diamond. Diamond and Related Materials, 1, 87–93.Google Scholar
Kiflawi, I., Fisher, D., Kanda, H. and Sittas, G. (1996) The creation of the 3107 cm−1 hydrogen absorption peak in synthetic diamond single crystals. Diamond and Related Materials, 12, 1516–1518.Google Scholar
Kohn, S.C., Speich, L., Smith, C.B. and Bulanova, G.P. (2016) FTIR thermochronometry of natural diamonds: a closer look. Lithos, 265, 148–158.Google Scholar
Lang, A.R. (1993) Topographic methods for studying defects in diamonds. Diamond and Related Materials, 2, 106–114.Google Scholar
Lang, A.R., Bulanova, G.P., Fisher, D., Furkert, S. and Sarua, A. (2007) Defects in a mixed–habit Yakutian diamond: Studies by optical and cathodoluminescence microscopy, infrared absorption, Raman scattering and photoluminescence spectroscopy. Journal of Crystal Growth, 309, 170–180.Google Scholar
Luyten, W., Vantendeloo, G., Fallon, P.J. and Woods, G.S. (1994) Electron microscopy and energy-loss spectroscopy of voidites in pure type-IaB diamonds. Philosophical Magazine A, 4, 767–778.Google Scholar
Nasdala, L., Grambole, D., Wildner, M., Gigler, A.M., Hainschwang, T., Zaitsev, A.M., Harris, J.W., Milledge, J., Schulze, D.J., Hofmeister, W. and Balmer, W.A. (2013) Radio–coloration of diamond: a spectroscopic study. Contributions to Mineralogy and Petrology, 5, 843–861.Google Scholar
Ragozin, A.L., Zedgenizov, D.A., Kuper, K.E. and Shatsky, V.S. (2016). Radial mosaic internal structure of rounded diamond crystals from alluvial placers of Siberian platform. Contributions to Mineralogy and Petrology, 6, 861–875.Google Scholar
Ragozin, A.L., Zedgenizov, D.A., Kuper, K.E. and Palyanov, Y.N. (2017) Specific Internal Structure of Diamonds from Zarnitsa Kimberlite Pipe. Crystals, 7, 133.Google Scholar
Ragozin, A.L., Zedgenizov, D.A., Shatsky, V.S. and Kuper, K.E. (2018) Formation of mosaic diamonds from the Zarnitsa kimberlite Russian Geology and Geophysics, 59, 486–498.Google Scholar
Rondeau, B., Fritsch, E., Guiraud, M., Chalain, J.-P. and Notari, F. (2004) Three historical ‘asteriated’ hydrogen-rich diamonds: Growth history and sector-dependent impurity incorporation. Diamond and Related Materials, 9, 1658–1673.Google Scholar
Orlov, Y.L. (1977) The Mineralogy of Diamond. John Wiley, New York, 248 pp.Google Scholar
Saguy, C., Cytermann, C., Fizgeer, B., Richter, V., Avigal, Y., Moriya, N., Kalish, R., Mathieu, B. and Deneuville, A. (2003) Diffusion of hydrogen in undoped, p-type and n-type doped diamonds. Diamond and Related Materials, 12, 623–631.Google Scholar
Shatsky, V., Ragozin, A., Zedgenizov, D. and Mityukhin, S. (2008) Evidence for multistage evolution in a xenolith of diamond-bearing eclogite from the Udachnaya kimberlite pipe. Lithos, 105, 289–300.Google Scholar
Skuzovatov, S., Zedgenizov, D., Howell, D. and Griffin, W.L. (2016) Various growth environments of cloudy diamonds from the Malobotuobia kimberlite field (Siberian craton). Lithos, 265, 96–107.Google Scholar
Speich, L., Kohn, S.C., Wirth, R, Bulanova, G.P. and Smith, C.B. (2017) The relationship between platelet size and the B′ infrared peak of natural diamonds. Lithos, 278, 419–426.Google Scholar
Speich, L., Kohn, S.C., Bulanova, G.P. and Smith, C.B. (2018) The behaviour of platelets in natural diamonds and the development of a new mantle thermometer. Contributions to Mineralogy and Petrology, 173:39. doi:10.1007/s00410-018-1463-4Google Scholar
Stacey, A., Karle, T.J., McGuinness, L.P., Gibson, B.C., Ganesan, K., Tomljenovic-Hanic, S., Greentree, A.D., Hoffman, A., Beausoleil, R.G. and Prawer, S. (2012) Depletion of nitrogen-vacancy color centres in diamond via hydrogen passivation. Applied Physics Letters, 100, 071902. doi: 10.1063/1.3684612Google Scholar
Sumida, N. and Lang, A.R. (1988) On the measurement of population density and size of platelets in type Ia diamond and its implications for platelet structure models. Proceedings of the Royal Society of London Series A, 1857, 235–257.Google Scholar
Taylor, W.R., Jaques, A.L. and Ridd, M. (1990) Nitrogen-defect aggregation characteristics of some Australian diamonds: time–temperature constraints on the source regions of pipe and alluvial diamonds. American Mineralogist, 11, 1290–1310.Google Scholar
Thomson, A.R., Kohn, S.C., Bulanova, G.P., Smith, C.B., Araujo, D., EIMF and Walter, M.J. (2014) Origin of sub-lithospheric diamonds from the Juina-5 kimberlite (Brazil): constraints from carbon isotopes and inclusion compositions. Contributions to Mineralogy and Petrology, 168, 1081–1088.Google Scholar
Van der Bogert, C.H., Smith, C.P., Hainschwang, T. and McClure, S.F. (2009) Gray-to-blue-to-violet hydrogen-rich diamonds from the Argyle mine, Australia. Gems and Gemology, 1, 20–37.Google Scholar
Van Tendeloo, G., Luyten, W. and Woods, G.S. (1990) Voidites in pure type IaB diamonds. Philosophical Magazine Letters, 61, 343–348.Google Scholar
Vasilev, E.A. and Sofroneev, S.V. (2007) Zoning of diamonds from the Mir kimberlite pipe: results of Fourier-transformed infrared spectroscopy. Geology of Ore Deposits, 49, 784–791.Google Scholar
Vasilev, E.A., Ivanov-Omskii, V.I., Pomazanskii, B.S. and Bogush, I.N. (2004) The N3 centre luminescence quenched by nitrogen impurity in natural diamond. Technical Physic Letters, 10, 802–803.Google Scholar
Vasilev, E.A., Kozlov, A.V. and Petrovsky, V.A. (2018 a) Volume and surface distribution of radiation defect in natural diamonds. Journal of Mining Institute, 230, 107–115.Google Scholar
Vasilev, E.A., Petrovsky, V.A., Kozlov, A.V. and Antonov, A.V. (2018 b) Infrared spectroscopy and internal structure of diamonds from the Ichetju Placer, Central Timan, Russia. Geology of Ore Deposits, 7, 1–9.Google Scholar
Vins, V.G. and Eliseev, A.P. (2010) Effect of annealing at high pressures and temperatures on the defect-admixture structure of natural diamonds. Inorganic Materials. Applied Research, 4, 303–310.Google Scholar
Wiggers de Vries, D.F., Bulanova, G.P., De Corte, K., Pearson, D.G., Craven, J.A. and Davies, G.R. (2013) Micron–scale coupled carbon isotope and nitrogen abundance variations in diamonds: Evidence for episodic diamond formation beneath the Siberian Craton. Geochimica et Cosmochimica Acta, 100, 176–199.Google Scholar
Woods, G.S. (1986) Platelets and the infrared absorption of type Ia diamonds. Proceedings of the Royal Society of London Series A–Mathematical and Physical Sciences, 407, 219–238.Google Scholar
Zaitsev, A.M. (2001) Optical Properties of Diamond: A Data Handbook. Springer, New York. 502 pp.Google Scholar
Zamoryanskaya, M.V., Konnikov, S.G. and Zamoryanskii, A.N. (2004) A high–sensitivity system for cathodoluminescent studies with the Camebax electron probe microanalyzer. Instruments and Experimental Techniques, 4, 787–483.Google Scholar
Supplementary material: File

Vasilev et al. supplementary material

Vasilev et al. supplementary material 1

Download Vasilev et al. supplementary material(File)
File 222.9 KB