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Cannonite, Bi2O(OH)2SO4, a new mineral from Marysvale, Utah, USA*

Published online by Cambridge University Press:  05 July 2018

C. J. Stanley ,
A. C. Roberts ,
D. C. Harris ,
A. J. Criddle  and
J. T. Szymañski
C. J. Stanley
Affiliation:
Department of Mineralogy, Natural History Museum, Cromwell Road, London SW7 5BD, UK
A. C. Roberts
Affiliation:
Geological Survey of Canada, 601 Booth Street, Ottawa, Ontario, KIA 0E8, Canada
D. C. Harris
Affiliation:
Geological Survey of Canada, 601 Booth Street, Ottawa, Ontario, KIA 0E8, Canada
A. J. Criddle
Affiliation:
Department of Mineralogy, Natural History Museum, Cromwell Road, London SW7 5BD, UK
J. T. Szymañski
Affiliation:
CANMET, 555 Booth Street, Ottawa, Ontario, K1A 0G1, Canada
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Abstract

Cannonite, ideally Bi2O(OH)2SO4, is a new mineral from the Tunnel Extension mine, Ohio Mining District, Marysvale, Utah, USA. It occurs mostly as intergrown crystalline aggregates (<1 mm) of subhedral to euhedral equant to prismatic crystals (<200 μm) in cavities in quartz gangue. Other associated minerals are cuprobismutite, bismuthinite, and covelline. Cannonite is colourless and transparent with an adamantine lustre and white streak. It is brittle with an uneven to conchoidal fracture. In reflected light it is low reflecting, weakly to moderately bireflectant and weakly anisotropic. Internal reflections (colourless to white) are abundant. Measured reflectance values in air and oil are tabulated. Colour values relative to the CIE illuminant C for R1 and R2 in air respectively are: Y% 10.4, 11.7; Lambdad 475,475; Pe% 2.6, 3.0. Calculated refractive indices at 589 nm: R1 1.91 and R2 1.99. VHN100 229 (range 183-280); calculated Mohs hardness is 4.

X-ray studies show that cannonite is monoclinic with space group P21/c and a 7.700(3), b 13.839(6), c 5.686(2) Å, β 109.11(3) ° It has a cell volume of 572.5(4) Å3 with Z = 4. Dcalc. is 6.515 g/cm3. The strongest six lines of the X-ray powder pattern are [d in Å (I) (hkl)] 3.206 (100) (221); 1.984 (90) (340, 152); 2.924 (70) (131); 3.644 (60) (111); 3.466 (60) (040); 2.782 (50) (112). Averaged probe analyses gave the empirical formula Bi1.99O(OH1.04)2S0.99O4 on the basis of 7 oxygen atoms. The name is for Benjamin Bartlett Cannon of Seattle, Washington, United States of America.

Keywords

cannonitenew mineralbismuthMarysvaleUtah
Type
Research Article
Information
Mineralogical Magazine , Volume 56 , Issue 385 , December 1992 , pp. 605 - 609
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1992

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References

Aurivillius, B. (1964) The crystal structures of Bi202 804.H20 and BiOHSeO4.H20. Acta Chem. Scand., 18, 2375–8.CrossRefGoogle Scholar
Criddle, A. L., Stanley, C. J., Chisholm, J. E., and Fejer, E. E. (1983) Henryite, a new copper-silver telluride from Bisbee, Arizona., Bull. Mineral., 106, 511–7.Google Scholar
Goliě, L., Graunar, M., and Lazarni, F. (1982) Catena-Di-μt-hydroxo-μ3-oxo-dibismuth(III) sulphate. Acta Cryst., B38, 2881-3.Google Scholar
Margulis, E. V., Grishankina, N. S., Novoselova, V. N., and Maletina, E. D. (1967) Hydrolysis of bismuth sulphates. Russ. J. Inorg. Chem., 12, 1072-5.Google Scholar
Pouchou, J. L. and Picboir, F. (1984) A new model for quantitative X-ray microanalysis. La Recherche Aerospatial, 3, 167–92.Google Scholar
Radtke, A. S., Taylor, C. M., and Frost, J. E. (1967) Bismuth and tin minerals in gold- and silver-bearing sulphide ores, Ohio Mining District, Marysvale, Utah. U.S. Geol. Survey Prof Paper, 575-D, D127-30.Google Scholar
Stanley, C. J., Jones, G. C., Hart, A. D., Keller, P., and Lloyd, D. (1991) Barstowite, 3PbCl/.PbCO3.H2O, a new mineral from Bounds Cliff, St Endellion, Cornwall., Mineral. Mag., 55, 121–5.CrossRefGoogle Scholar