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Tourmaline from the Solnechnoe tin deposit, Khabarovsk Krai, Russia

Published online by Cambridge University Press:  11 November 2019

Ivan A. Baksheev
Affiliation:
Geology Department, Lomonosov Moscow State University, Leninskie Gory, Moscow 119991 Russia
Marina F. Vigasina
Affiliation:
Geology Department, Lomonosov Moscow State University, Leninskie Gory, Moscow 119991 Russia
Vasily O. Yapaskurt
Affiliation:
Geology Department, Lomonosov Moscow State University, Leninskie Gory, Moscow 119991 Russia
Igor A. Bryzgalov
Affiliation:
Geology Department, Lomonosov Moscow State University, Leninskie Gory, Moscow 119991 Russia
Nina V. Gorelikova
Affiliation:
Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry, Russian Academy of Sciences, Moscow, Staromonetny per., Moscow, 119017, Russia
Corresponding
E-mail address:

Abstract

Tourmaline from the Solnechnoe hydrothermal granitoid-related tin deposit in the Khabarovsk Krai, Russian Far East has been studied with electron microprobe, infrared and Mössbauer spectroscopy. Tourmaline formed in three distinct stages with different types of chemical substitution. Tourmaline from the first unmineralised stage is classified as dravite or schorl, which could be enriched locally in Ca, the X-site vacancy and F. This tourmaline is characterised by the Fe ↔ Mg and X vacancy + Al ↔ Na + Fe substitutions. The second, molybdenum-stage tourmaline, is schorl–dravite and fluor-schorl–fluor-dravite enriched in Ca, and a few compositions belong to the calcic group. The predominant substitution is Ca + Mg ↔ Na + Al. The third, tin-stage tourmaline, is classified as schorl–dravite with some tourmalines being fluor-schorl, oxy-schorl, foitite and magnesio-foitite. The tin-stage tourmaline is characterised by the substitutions Fe2+ ↔ Mg, Altot + O2– ↔ Fe2+ + OH, and Fe3+ ↔ Altot. An increase of the Fe3+/Fetot value from 3–9% in the molybdenum stage to 12–16% in the tin-stage tourmalines indicates an increase in oxidation potential, which possibly contributed to cassiterite deposition. Comparison of tourmalines from greisen, porphyry and intrusion-related tin deposits worldwide shows they differ in primary chemical substitutions so can be characterised by this mechanism. The Fe3+/Fetot value in tourmaline also appears to be one of the indications for the tin deposit type. The Fe3+/Fetot value increases from <10% in greisen tourmaline through 15% in tourmaline from intrusion-related deposits to 20% in tourmaline from porphyry deposits.

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Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2019

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Footnotes

Associate Editor: Ferdinando Bosi

References

Alekseev, V.I. and Marin, Yu.B. (2019) Tourmaline as an indicator of tin occurrences of cassiterite–quartz and cassiterite–silicate formations (a case study of the Verkhneurmiysky ore cluster). Journal of Mining Institute, 235, 39.CrossRefGoogle Scholar
Andreozzi, G.B., Bosi, F. and Longo, M. (2008) Linking Mössbauer and structural parameters in elbaite–schorl–dravite tourmalines. American Mineralogist, 93, 658666.CrossRefGoogle Scholar
Baksheev, I.A. and Kudryavtseva, O.E. (2004) Nickeloan tourmaline from the Berezovskoe gold deposit, Middle Urals, Russia. The Canadian Mineralogist, 42, 10651078.CrossRefGoogle Scholar
Baksheev, I.A., Tikhomirov, P.L., Yapaskurt, V.O., Vigasina, M.F., Prokofiev, V.Yu. and Ustinov, V.I. (2009) Tourmaline of the Mramorny tin cluster, Chukotka Peninsula, Russia. The Canadian Mineralogist, 47, 11771194.CrossRefGoogle Scholar
Baksheev, I.A., Prokofiev, V.Yu., Zaraisky, G.P., Chitalin, A.F., Yapaskurt, V.O., Nikolaev, Y.N., Tikhomirov, P.L., Nagornaya, E.V., Rogacheva, L.I., Gorelikova, N.V. and Kononov, O.V. (2012) Tourmaline as a prospecting guide for the porphyry-style deposits. European Journal of Mineralogy, 24, 957979.CrossRefGoogle Scholar
Bloodaxe, E.S., Hughes, J.M., Dyar, M.D., Grew, E.S. and Guidotti, C.V. (1999) Linking structure and chemistry in the schorl–dravite series. American Mineralogist, 84, 922928.CrossRefGoogle Scholar
Bortnikov, N.S., Khanchuk, A.I., Krylova, T.L., Anikina, E.Yu., Gorelikova, N.V., Gonevchuk, V.G., Ignat'ev, A.V., Kokorin, A.M., Korostelev, P.G. and Lomm, T. (2005). Geochemistry of the mineral-forming fluids in some tin-bearing hydrothermal systems of Sikhote Alin, the Russian Far East. Geology of Ore Deposits, 47, 488516.Google Scholar
Bortnikov, N.S., Gorelikova, N.V., Korostelev, P.G. and Gonevchuk, V.G. (2008) Rare earth elements in tourmaline and chlorite from tin-bearing assemblages: factors controlling fractionation of REE in hydrothermal systems. Geology of Ore Deposits, 50, 445461.10.1134/S1075701508060032CrossRefGoogle Scholar
Bosi, F. (2008) Disordering of Fe2+ over octahedrally coordinated sites of tourmaline. American Mineralogist, 93, 16471653.CrossRefGoogle Scholar
Bosi, F. (2018) Tourmaline crystal chemistry. American Mineralogist, 103, 298306.CrossRefGoogle Scholar
Bosi, F., Andreozzi, G.B., Hålenius, U. and Skogby, H. (2015) Experimental evidence for partial Fe2+ disorder at the Y and Z sites of tourmaline: a combined EMP, SREF, MS, IR and OAS study of schorl. Mineralogical Magazine, 79, 515528.CrossRefGoogle Scholar
Choo, C.O. (2003) Mineralogical studies of complex zoned tourmaline in diaspore nodules from the Milyang clay deposit, Korea. Geoscience Journal, 7, 151162.CrossRefGoogle Scholar
Chugaev, A.V., Bortnikov, N.S., Gonevchuk, V.G., Gorelikova, N. V., Korostelev, P.G. and Baranova, A.N. (2012) Age of tin ore from the Solnechnoe quartz–tourmaline–cassiterite deposit, the Khabarovsk krai, Russia from the results of Rb–Sr dating of quartz and adularia. Geology of Ore Deposits, 54, 233240.CrossRefGoogle Scholar
Codeço, M.S., Weis, P., Trumbull, R.B., Pinto, F., Lecumberri-Sanchez, P., and Wilke, F.D.H. (2017) Chemical and boron isotopic composition of hydrothermal tourmaline from the Panasqueira W–Sn–Cu deposit, Portugal. Chemical Geology, 468, 116.CrossRefGoogle Scholar
Collins, A.C. (2010) Mineralogy and Geochemistry of Tourmaline in Contrasting Hydrothermal Systems: Copiapó Area, Northern Chile. MS dissertation, University of Arizona.Google Scholar
Dutrow, B.L. and Henry, D.J. (2000) Complexly zoned fibrous tourmaline, Cruzeiro mine, Minas Gerais, Brazil: a record of evolving magmatic and hydrothermal fluids. The Canadian Mineralogist, 38, 131143.CrossRefGoogle Scholar
Dutrow, B.L. and Henry, D.J. (2016) Fibrous tourmaline: A sensitive probe of fluid compositions and petrologic environments. The Canadian Mineralogist, 54, 311335.CrossRefGoogle Scholar
Dutrow, B.L. and Henry, D.J. (2018) Tourmaline compositions and textures: reflections of the fluid phase. Journal of Geosciences, 63, 99110.Google Scholar
Dutrow, B.L., Henry, D.J. and Sun, Z. (2019) Origin of corundum–tourmaline–phlogopite rocks from Badakhshan, northeastern Afghanistan: a new type of metasomatism associated with sapphire formation. European Journal of Mineralogy, 31, 739753.CrossRefGoogle Scholar
Dyar, M.D., Taylor, M.E., Lutz, T.M., Francis, C.A., Guidotti, C.V. and Wise, M. (1998) Inclusive chemical characterization of tourmaline: Mössbauer study of Fe valence and site occupancy. American Mineralogist, 83, 848864.CrossRefGoogle Scholar
El Mahjoubi, E.M., Chauvet, A., Badra, L., Sizaret, S., Barbanson, L., El Maz, A., Chen, Y. and Amann, M. (2016) Structural, mineralogical, and paleoflow velocity constraints on Hercynian tin mineralization: the Achmmach prospect of the Moroccan Central Massif. Mineralium Deposita, 51, 431451.CrossRefGoogle Scholar
Gonevchuk, V.G. (2002) Tin-Bearing Systems of the Far East: Magmatism and Ore Formation. Dalnauka, Vladivostok, 207 pp. [in Russian].Google Scholar
Gonevchuk, V.G., Gonevchuk, G.A. and Gorelikova, N.V. (2010) Ore-forming system of the Komsomolsk district: Some features of evolution. Pp 1112 in: Conference on Geology and Complex Utilization of Natural Resources of Eastern Asia. Institute of Geology and Natural Management, Far East Branch Russian Academy of Sciences, Blagoveshchensk, June 2010 [in Russian].Google Scholar
Gorelikova, N.V. (1988) Paragenetic Assemblages of Trace Elements in Tourmaline from Tin Deposits. Nauka, Vladivostok, 126 pp. [in Russian].Google Scholar
Henry, D.J. and Dutrow, B.L. (1990). Ca substitution in Li-poor aluminous tourmaline. The Canadian Mineralogist, 28, 111124.Google Scholar
Henry, D.J., Sun, H., Slack, J.F. and Dutrow, B.L. (2008) Tourmaline in meta-evaporites and highly magnesian rocks: perspectives from Namibian tourmalinites. European Journal of Mineralogy, 20, 889904.CrossRefGoogle Scholar
Henry, D.J., Novák, M., Hawthorne, F., Ertl, A., Dutrow, B., Uher, P. and Pezzotta, F. (2011) Nomenclature of the tourmaline-supergroup minerals. American Mineralogist, 96, 895913.10.2138/am.2011.3636CrossRefGoogle Scholar
Henry, D.J., Novák, M., Hawthorne, F.C., Ertl, A., Dutrow, B.L., Uher, P. and Pezzotta, F. (2013) Erratum. American Mineralogist, 98, 524.Google Scholar
Hinsberg van, V.J., Henry, D.J. and Marschall, H.R. (2011) Tourmaline: an ideal indicator of its host environment. The Canadian Mineralogist, 49, 116.CrossRefGoogle Scholar
Huang, S., Song, Y., Hou, Z. and Xue, C. (2016) Chemical and stable isotopic (B, H, and O) compositions of tourmaline in the Maocaoping vein-type Cu deposit, western Yunnan, China: Constraints on fluid source and evolution. Chemical Geology, 439, 173188.CrossRefGoogle Scholar
Jarozewich, E. (2002) Smithsonian microbeam standards. Journal of Research of the National Institute of Standards and Technology, 107, 681685.CrossRefGoogle Scholar
Jia, R., Fang, W. and Hu, R. (2010) Mineral geochemical compositions of tourmalines and their significance in the Geju tin polymetallic deposits, Yunnan, China. Acta Geologica Sinica (English edition), 84, 155166.CrossRefGoogle Scholar
Jiang, S-Y., Yu, Ji-M. and Lu, J-J. (2004) Trace and rare-earth element geochemistry in tourmaline and cassiterite from the Yunlong tin deposit, Yunnan, China: implication for migmatitic-hydrothermal fluid evolution and ore genesis. Chemical Geology, 209, 193213.CrossRefGoogle Scholar
Korostelev, P.G., Gonevchuk, V.G., Semenyak, B.I., Suchkov, V.I., Kokorin, A.M., Gonevchuk, G.A., Gorelikova, N.V. and Kokorina, D.K. (2001) The Solnechnoe deposit, Komsomolsk ore district, Khabarovsk krai, as typical object of cassiterite–silicate association. Pp 131156 in: Ore Deposits of Continental Margins (Khanchuk, A.I., editor). Nauka, Vladivostok [in Russian].Google Scholar
Korostelev, P.G., Gonevchuk, V.G., Gorelikova, N.V., Ekimova, N.I., Kononov, V.V., Krylova, T.L., Orekhov, A.A., Semenyak, B.I. and Suchkov, V.I. (2016) Tin–rare-earth element greisens of the Solnechnoe cassiterite–silicate deposit, Russian Far East. Russian Journal of Pacific Geology, 10, 6377.CrossRefGoogle Scholar
Korovushkin, V.V., Kuzmin, V.I. and Belov, V.F. (1979) Mössbauer studies of structural features in tourmaline of various genesis. Physics and Chemistry of Minerals, 4, 209220.CrossRefGoogle Scholar
Kuzmin, V.I., Dobrovolskaya, N.V. and Solntseva, L.S. (1979) Tourmaline and its Use in Prospecting. Nedra, Moscow, 270 pp. [in Russian].Google Scholar
Lussier, A.J., Abdu, Y., Hawthorne, F.C., Michaelis, V.K., Aguiar, P.M. and Kroeker, S. (2011) Oscillatory zoned liddicoatite from Anjanabonoina, central Madagascar. I. Crystal chemistry and structure by SREF and 11B and 27Al MAS NMR spectroscopy. The Canadian Mineralogist, 49, 6388.CrossRefGoogle Scholar
Mlynarczyk, M.S.J. and Williams-Jones, A. (2006) Zoned tourmaline associated with cassiterite: implications for fluid evolution and tin mineralization in the San Rafael Sn–Cu deposit, Southeastern Peru. The Canadian Mineralogist, 44, 347365.CrossRefGoogle Scholar
Norton, D. and Dutrow, B.L. (2001) Complex behavior of magma-hydrothermal processes: role of supercritical fluid. Geochimica et Cosmochimica Acta, 65, 40094017.CrossRefGoogle Scholar
Ognyanov, N.V. (1989) Geological formation conditions of cassiterite–silicate–sulfide mineralization in the Komsomolsk and Kavalerovo districts. Pp 113148 in: Geological Conditions of Localization of Endogenous Mineralization (Khomich, V.G., editor). Vladivostok, Far East Branch, Academy of Sciences of the USSR [in Russian].Google Scholar
Panova, E.G. (2000) Chemical Evolution of Rock-Forming Minerals During Formation of Tin and Tungsten Hydrothermal Deposits. Doctoral Dissertation, Saint Petersburg State University [in Russian].Google Scholar
Pirajno, F. and Smithies, R.H. (1992) The FeO / (FeO + MgO) ratio of tourmaline: a useful indicator of spatial variations in granite-related hydrothermal mineral deposits. Journal of Geochemical Exploration, 42, 371381.CrossRefGoogle Scholar
Pouchou, I.L. and Pichoir, F. (1985) “PAP” (phi-rho-z) procedure for improved quantitative microanalysis. Pp. 104106. in: Microbeam Analysis (Armstrong, I.T., editor). San Francisco Press; San Francisco, USA.Google Scholar
Radkevich, E.A. (editor) (1971) Geology, Mineralogy, and Geochemistry of the Komsomolsk District. Nauka Moscow 335pp [in Russian].Google Scholar
Radkevich, E.A., Korostelev, P.G., Kokorin, A.M., Ryabov, V.K., Stepanov, M.V., Kokorina, D.K., Golovkov, G.S., Bakulin, Yu.I., Kushev, V.B., Seleznev, P.N., Klemin, V.P. and Radkevich, R.O. (1967) Mineralized Zones of the Komsomolsk Ore District. Nauka, Moscow, 114 pp. [in Russian]Google Scholar
Rodionov, S.M., Semenyak, B.I. and Zabrodin, V.Yu. (2004) The Komsomolsk ore district. Pp. 4371 in: Metallogeny of the Pacific Northwest (Russian Far East): Tectonics, Magmatism and Metallogeny of Active Continental Margins (Khanchuk, A.I., Gonevchuk, G.A. and Seltmann, R., Editors). Guidebook for the Field Excursions in the Far East of Russia: September 1–20, 2004 Dalnauka Publishing House, IAGOD Guidebook series 11, Vladivostok.Google Scholar
Slack, J.F. (1996) Tourmaline associations with hydrothermal ore deposits. Pp 559644 in: Boron: Mineralogy, Petrology and Geochemistry (Grew, E.S. and Anovitz, L.M., editors). Reviews in Mineralogy, 33. Mineralogical Society of America, Washington DC.CrossRefGoogle Scholar
Slack, J.F., Ramsden, A.R., Griffin, W.L., Win, T.T., French, D.H. and Ryan, C.G. (1999) Trace elements in tourmaline from the Kidd Creek massive sulfide deposit and vicinity, Timmins, Ontario: a proton microprobe study. Pp. 415430 in: The Giant Kidd Creek Volcanogenic Massive Sulfide Deposit, Western Abitibi Subprovince, Canada (Hannington, M.D. and Barrie, C.T., editors). Economic Geology Monograph, 10.Google Scholar
Sushchevskaya, T.M., Ignatiev, A.V. and Velivetskaya, T.A. (2009) Determination of hydrogen isotopic composition of tin-bearing fluid using tourmaline. Vestnik Otdelenia nauk o Zemle RAN, no. 1, https://onznews.wdcb.ru/publications/asempg/hydroterm-28.pdf [in Russian].Google Scholar
Veličkov, B. (2002) Kristallchemie von Fe, Mg-turmalinen: synthese und spektroskopische untersuchungen vorgelegt. PhD dissertation, Technischen Universität, Berlin, Germany.Google Scholar
Watenphul, A., Burgdorf, M., Schlüter, J., Horn, I., Malcherek, T. and Mihailova, B. (2016) Exploring the potential of Raman spectroscopy for crystallochemical analyses of complex hydrous silicates: II. American Mineralogist, 101, 970985.CrossRefGoogle Scholar
Williamson, B.J., Spratt, J., Adams, J.T., Tindle, A.G. and Stanley, C.J. (2000) Geochemical constraints from zoned hydrothermal tourmalines on fluid evolution and tin mineralization: an example from fault breccias at Roche, SW England. Journal of Petrology, 41, 14391453.CrossRefGoogle Scholar
Wright, J.H. and Kwak, T.A.P. (1989) Tin-bearing greisens of Mount Bischof, Northwestern Tasmania, Australia. Economic Geology, 84, 551574.CrossRefGoogle Scholar
Yavuz, F., Fuchs, Y., Karakaya, N. and Karakaya, M.Ç. (2008) Chemical composition of tourmaline from the Asarcık Pb–Zn–Cu ± U deposit, Şebinkarahisar, Turkey. Mineralogy and Petrology, 94, 195208.CrossRefGoogle Scholar

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