Hostname: page-component-78c5997874-v9fdk Total loading time: 0 Render date: 2024-11-01T21:13:34.241Z Has data issue: false hasContentIssue false

Sideritic concretions from the Westphalian of Yorkshire: a chemical investigation of the carbonate phase

Published online by Cambridge University Press:  05 July 2018

M. J. Pearson*
Affiliation:
Department of Geology and Mineralogy, The University, Marischal College, Aberdeen, AB9 IAS

Summary

The carbonate phase of impure sideritic concretions from a sequence of argillaceous sediments from the Westphalian of Yorkshire has been analysed using an acid-dissolution technique and corrections allowing for the decomposition of non-carbonate minerals applied to obtain accurate compositional formulae.

The siderites show considerable compositional variation, some containing Ca in excess of anticipated substitutional limits. Whilst these may be metastable it is suggested that coupled Mg-Ca substitution could provide an explanation.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1974

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Deer, (W. A.), Howie, (R. A.), and Zussman, (J.), 1962. Rock forming minerals, 5, 273, London (Longmans).Google Scholar
Goldsmith, (J. R.), Graf, (D. L.), Witters, (J.), and Northrop, (D. A.), 1962. Journ. Geology, 70, 659.CrossRefGoogle Scholar
Groves, (A. W.), 1951. Silicate analysis. London (George Allen & Unwin).CrossRefGoogle Scholar
Rosenberg, (P. E.), 1960. Subsolidus studies in the system CaCO3-MgCO2-FeCO3-MnCOs.Ann Arbor, Michigan (University Microfilms Inc.)Google Scholar
Smythe, (J. A.) and DUNHAM (K. C), 1947. Min. Mag., 28, 53.Google Scholar
Taylor, (J.H.), 1950. Ibid. 29, 21.CrossRefGoogle Scholar
Zaritskii, (P. V.) , 1964. Dokl. Akad. nauk. SSSR. (Earth Sci. Sect.), 155, 151 (transl. of CCCP, 155, 1341).Google Scholar