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Hitachiite, Pb5Bi2Te2S6, a new mineral from the Hitachi mine, Ibaraki Prefecture, Japan

Published online by Cambridge University Press:  15 July 2019

Takahiro Kuribayashi*
Affiliation:
Department of Earth Science, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan
Toshiro Nagase
Affiliation:
The Tohoku University Museum, Tohoku University, Sendai 980-8578, Japan
Tatsuo Nozaki
Affiliation:
Research and Development Centre for Submarine Resources, Japan Agency for Marine-Earth Science and Technology, Yokosuka, 237-0061, Japan Frontier Research Centre for Energy and Resources, School of Engineering, The University of Tokyo, Tokyo 113-8656, Japan Department of Planetology, Kobe University, Kobe 657-8501, Japan Ocean Resources Research Centre for Next Generation, Chiba Institute of Technology, Narashino 275-0016, Japan
Junichiro Ishibashi
Affiliation:
Department of Earth and Planetary Sciences, Faculty of Science, Kyushu University, Fukuoka 819-0395, Japan
Kazuhiko Shimada
Affiliation:
Department of Earth and Planetary Sciences, Faculty of Science, Kyushu University, Fukuoka 819-0395, Japan
Masaaki Shimizu
Affiliation:
Department of Earth System Science, Graduate School of Science and Engineering for Education, University of Toyama, Toyama 930-8555, Japan
Koichi Momma
Affiliation:
Department of Geology and Paleontology, National Museum of Nature and Science, Tsukuba 305-0005, Japan.
*
*Author for correspondence: T. Kuribayashi, Email: takahiro.kuribayashi.a7@tohoku.ac.jp

Abstract

Hitachiite, Pb5Bi2Te2S6, is a new mineral discovered in the Hitachi mine, located in the Ibaraki Prefecture of Japan. The mean of 21 electron microprobe analyses gave: Pb 52.01, Bi 23.06, Fe 0.69, Sb 0.17, Te 13.74, S 9.71, Se 0.54, total 100.04 wt.%. The empirical chemical formula based on 15 apfu is (Pb4.75Fe0.23)Σ4.98(Bi2.09Sb0.03)Σ2.12Te2.04(S5.73Se0.13)Σ5.86, ideally Pb5Bi2Te2S6. Synchrotron single-crystal X-ray diffraction experiments indicated that hitachiite has trigonal symmetry, space group P${\bar 3}$m1, with a = 4.2200(13) Å, c = 27.02(4) Å and Z = 1. The four strongest diffraction peaks shown in the powder X-ray pattern [d, Å (I)(hkl)] are: 3.541(35)(012), 3.391(59)(013), 3.039(100)(015) and 2.114(56)(110). The calculated density (Dcalc) for the empirical chemical formula is 7.54 g/cm3.

The crystal structure of hitachiite has been refined using synchrotron single-crystal X-ray diffraction data, to R = 7.38% and is based on ABC-type stacking of 15 layers (five Pb, two Bi, two Te, and six S layers) along the [001] direction, and with each layer ideally containing only one kind of atom. The stacking sequence is described as Te–Bi–S–Pb–S–Pb–S–Pb–S–Pb–S–Pb–S–Bi–Te. The discovery of hitachiite implies that the minerals of the Bi2Te2S–PbS join might form a homologous series of Bi2Te2nPbS.

Type
Article
Copyright
Copyright © Mineralogical Society of Great Britain and Ireland 2019 

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Footnotes

Associate Editor: František Laufek

References

Bayliss, P. (1991) Crystal chemistry and crystallography of some minerals in the tetradymite group. American Mineralogist, 76, 257265.Google Scholar
Bindi, L. and Cipriani, C. (2003) Plumbian baksanite from Tyrnyauz W–Mo deposit, Baksan river valley, northern Caucasus, Russian Federation. The Canadian Mineralogist, 41, 14751479.Google Scholar
Cook, N.J., Ciobanu, C.L., Stanley, C.J., Paar, W.H. and Sundblad, K. (2007 a) Compositional data for Bi–Pb tellurosulfides. The Canadian Mineralogist, 45, 417435.Google Scholar
Cook, N.J., Ciobanu, C.L., Wagner, T. and Stanley, C.J. (2007 b) Minerals of the system Bi–Te–Se–S related to the tetradymite archetype. The Canadian Mineralogist, 45, 665708.Google Scholar
Farrugia, L.J. (1999) WinGX suite for small-molecule single-crystal crystallography. Journal of Applied Crystallography, 32, 837838.Google Scholar
Harker, D. (1934) The crystal structure of the mineral tetradymite, Bi2Te2S. Zeit für Kristallographie, 89, 175181.Google Scholar
Imamov, P.M. and Semiletov, S.A. (1971) The crystal structure of the phases in the system Bi–Se, Bi–Te, and Sb–Te. Soviet Physics Crystallography, 15, 845850.Google Scholar
Kase, K. (1978) Sulfide Minerals of the Hitachi deposits and their comparison with those of the Bessi deposit – studies on sulfide minerals in metamorphosed ores of the Bessi and Hitachi copper deposits (2). Mining Geology, 28, 1324.Google Scholar
Kase, K. and Yamomoto, M. (1985) Geochemical study of conformable massive sulfide deposits of the Hitachi mine, Ibaraki Prefecture, Japan. Mining Geology, 35, 1729.Google Scholar
Kuribayashi, T., Nagase, T., Nozaki, T., Ishibashi, J., Shimada, K., Shimizu, M. and Momma, K. (2018) Hitachiite, IMA 2018-027. CNMNC Newsletter No. 44, August 2018, page 1018; Mineralogical Magazine, 82, 1015–1021.Google Scholar
Kuznetsov, V.G. and Kanishcheva, A.S. (1970) X–ray investigation of alloys of the system Bi2Te3–Bi2S3. Inorganic Materials, 6, 11131116.Google Scholar
Liu, H. and Chang, L.Y. (1994) Lead and bismuth chalcogenide systems. American Mineralogist, 79, 11591166.Google Scholar
Makovicky, E. (2006) Crystal structures of sulphides and other chalcogenides. Pp. 7125 in: Sulfide Mineralogy and Geochemistry (Vaughan, D.J., editor). Reviews in Mineralogy and Geochemistry, 61. Mineralogical Society of America and the Geochemical Society, Chantilly, Virginia, USA.Google Scholar
Moëlo, Y., Makovicky, E., Mozgova, N.N., Jambor, J.L., Cook, N., Pring, A., Paar, W., Nickel, E.H., Graeser, S., Karup–Moøller, S., Balic–Žunic, T., Mumme, W.G., Vurro, F., Topa, D., Bindi, L., Bente, K. and Shimizu, M. (2008) Sulfosalt systematics: a review. Report of sulfosalt sub-committee of the IMA commission on ore mineralogy. European Journal of Mineralogy, 20, 746.Google Scholar
Momma, K. and Izumi, F. (2011) VESTA 3 for three-dimensional visualization of crystals, volumetric and morphology data. Journal of Applied Crystallography, 44, 12721276.Google Scholar
Nakajima, S. (1963) The crystal structure of Bi2Te3–xSex. Journal of Physics and Chemistry of Solids, 24, 479485.Google Scholar
Nakamuta, Y. (1999) Precise analysis of a very small mineral by an X–ray diffraction method. Journal of the Mineralogical Society of Japan, 28, 117121 [in Japanese with English abstract].Google Scholar
Noda, Y., Masumoto, K., Ohba, S., Saito, Y., Toriumi, K., Iwata, Y. and Shibuya, I. (1987) Temperature dependence of atomic thermal parameters of lead chalcogenides, PbS, PbSe and PbTe. Acta Crystallographica, C43, 14431445.Google Scholar
Nozaki, T., Kato, Y. and Suzuki, K. (2014) Re–Os geochronology of the Hitachi volcanic massive sulfide deposit: The oldest ore deposit in Japan. Economic Geology, 109, 20232034.Google Scholar
Oszlanyi, G. and Suto, A. (2004) Ab initio structure solution by charge flipping, Acta Crystallographica, A60, 134141.Google Scholar
Palatinus, L. and Chapuis, G. (2007) SUPERFLIP – a computer program for the solution of crystal structures by charge flipping in arbitrary dimensions. Journal of Applied Crystallography, 40, 456462.Google Scholar
Parkin, S.Moezzi, B. and Hope, H. (1995) XABS2: an empirical absorption correction program. Journal of Applied Crystallography, 28, 5356.Google Scholar
Pauling, L. (1975) The formula, structure and chemical bonding of tetradymite Bi14Te13S8–Bi14Te15S6. American Mineralogist, 60, 994997.Google Scholar
Prince, E. (editor) (2004) International Tables for X–ray Crystallography. Volume C: Mathematical, Physical and Chemical Tables. 3rd edition. International Union of Crystallography. Kluwer Academic Publisher, Dordrecht, Netherlands.Google Scholar
Sheldrick, G.M. and Schneider, T.R. (1997) SHELXL: high–resolution refinement. Methods in Enzymology, 277, 319343.Google Scholar
Shelimova, L.E., Karpinski, O.G, Svechnikova, T.E., Avilov, E.S., Kretova, M.A. and Zemskov, V.S. (2004) Synthesis and structure of layered compounds in the PbTe–Bi2Te3 and PbTe–Sb2Te3 systems. Inorganic Materials, 40, 12641270.Google Scholar
Shimazaki, H. and Ozawa, T. (1978) Tsumoite, BiTe, a new mineral from the Tsumo mine, Japan. American Mineralogist, 63, 11621165.Google Scholar
Strunz, H. and Nickel, E.H. (2001) Class 2. SULFIDES and SULFOSALTS. pp. 56147 in: Strunz Mineralogical Tables 9th Edition. E. Schweizerbart'sche Verlagsbuchhandlung (Nägele u. Obermiller), Stuttgart, Germany.Google Scholar
Tagiri, M., Dunkley, D.J., Adachi, T., Hiroi, Y. and Fanning, C.M. (2011) SHRIMP dating of magmatism in the Hitachi metamorphic terrane, Abukuma Belt, Japan: Evidence for a Cambrian volcanic arc. Island Arc, 20, 259279.Google Scholar
Talybov, A.G. and Vainshtein, B.K. (1962) An electron diffraction study of the second superlattice in PbBi4Te7. Kristallografiya, 7, 4350.Google Scholar
Zhukova, T.B. and Zaslavskii, A.I. (1972) Crystal structures of the compounds PbBi4Te7 PbBi2Te4 SnBi4Te7 SnBi2Te4 SnSb2Te4 and GeBi4Te7. Kristallografiya, 16, 918922.Google Scholar
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