Hostname: page-component-848d4c4894-jbqgn Total loading time: 0 Render date: 2024-07-03T05:47:42.937Z Has data issue: false hasContentIssue false

Gas Evolution in Rotating Electrochemical Cells Under Reduced and Normal Gravity Conditions

Published online by Cambridge University Press:  05 May 2011

Fang-Bor Weng*
Affiliation:
Department of Mechanical Engineering, Yuan Ze University, Chung-Li, Taiwan 320, R.O.C.
Ay Su*
Affiliation:
Department of Mechanical Engineering, Yuan Ze University, Chung-Li, Taiwan 320, R.O.C.
Yasuhiro Kamotani*
Affiliation:
Department of Mechanical and Aerospace Engineering, Case Western Reserve University, Cleveland, OH 44106, U.S.A.
Simon Ostrach*
Affiliation:
Department of Mechanical and Aerospace Engineering, Case Western Reserve University, Cleveland, OH 44106, U.S.A.
*
* Assistant Professor
** Associate Professor
*** Professor
*** Professor
Get access

Abstract

Electrochemical experiments in microgravity are essential for the optimum design of advanced life support systems and power storage systems in space. In the absence of gravity, the evolved gas bubbles will clog the electrode and slow the reaction. Here, a rotating cell concept is introduced as a plan for improving mass transfer and bubble removal in a microgravity environment. A primary experimental study of bubble behavior in rotating water electrolysis cells has been done in reduced gravity through KC-135 parabolic flight. The results show that the cell resistance decreases with increasing rotation rate. Without rotation, the bubbles stick on the electrode surface during reduced gravity period, thus, the cell efficiency degrades. Mass transfer enhanced by bubble generation is investigated in ground-based work at high rotation rate of test cells, so that gravitational effects are minimized.

Type
Articles
Copyright
Copyright © The Society of Theoretical and Applied Mechanics, R.O.C. 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1]Eckart, P., Spaceflight Life Support and Biospherics, Space Technology Library, Kluwer Academic Publishers (1996).CrossRefGoogle Scholar
[2]Elikan, L., Editor, Aerospace Life Support, Chemical Engineering Process Symposium Series, 62(63), American Institute of Chemical Engineers (1966).Google Scholar
[3]Tennakoon, C. L. K., Bhardwaj, R. C. and Bockris, J.O'm, “Electrochemical Treatment of Human Wastes in a Packed Bed Reactor,” Journal of Applied Electrochemistry, 26, pp. 1829 (1996).CrossRefGoogle Scholar
[4]Kaneko, H., Tanaka, K., Iwasaki, A., Abe, Y., Negishi, A. and Kamimoto, M., “Water Electrolysis Under Microgravity Condition by Parabolic Flight,” Electrochimica Acta, 38(5), pp. 729733 (1993).CrossRefGoogle Scholar
[5]Janssen, L. J. J., “Boiling Phenomena,” 1, Edited by Van Stralen, S.J.D. and Cole, R., Mcgraw-Hill, New York, Ch. 13 (1979).Google Scholar
[6]Sides, P. J. and Tobias, C. W., “Primary Potential and Current Distribution around a Bubble on an Electrode,” J. of the Electrochemical Society, 127(2), pp. 288291 (1980).CrossRefGoogle Scholar
[7]Shah, A. and Jörne, J., “Mass Transfer Under Bubble-Induced Convection in a Vertical Electrochemical Cells,” J. of the Electrochemical Society, 136(1), pp. 144153 (1989).CrossRefGoogle Scholar
[8]Shah, A. and Jörne, J., “Mass Transfer Under Combined Gas Evolution and Force Convection,” J. of the Electrochemical Society, 136(1), pp. 154158 (1989).CrossRefGoogle Scholar
[9]Alkire, R. and Lu, P.-Y., “Effect of Hydrogen Evolution on Current Distribution During Electrodepostition at Vertical Electrodes,” J. of Electrochemical Society, 126(12), pp. 21182124 (1979).CrossRefGoogle Scholar
[10]Fukunaka, Y., Suzuki, K., Ueda, A. and Kondo, Y., “Mass Transfer Rate on a Plane Vertical Cathode with Hydrogen Gas Evolution,” J. of the Electrochemical Society, 136(4), pp. 10021009 (1989).CrossRefGoogle Scholar
[11]Weng, F.-B., Kamotani, Y. and Ostrach, S., “Mass Transport Rate Study in Rotating Shallow Electrochemical Cells,” International Journal of Heat and Mass Transfer, 41, pp. 27252733 (1998).CrossRefGoogle Scholar