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Microwave-assisted Al-substituted Tobermorite Synthesis

Published online by Cambridge University Press:  31 January 2011

Michihiro Miyake ,
Shigeto Niiya  and
Motohide Matsuda
Michihiro Miyake
Affiliation:
Department of Environmental Chemistry and Materials, Faculty of Environmental Science and Technology, Okayama University, Tsushima-Naka, Okayama 700–8530, Japan
Shigeto Niiya
Affiliation:
Department of Environmental Chemistry and Materials, Faculty of Environmental Science and Technology, Okayama University, Tsushima-Naka, Okayama 700–8530, Japan
Motohide Matsuda
Affiliation:
Department of Environmental Chemistry and Materials, Faculty of Environmental Science and Technology, Okayama University, Tsushima-Naka, Okayama 700–8530, Japan
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Abstract

The effect of microwave heating on the hydrothermal synthesis of Al-substituted tobermorite and the removal characteristics of resulting materials were examined and compared with the effect of conventional heating. The microwave heating reduced the crystallization time of Al-substituted tobermorite—i.e., Al-substituted tobermorite was synthesized within 80 min at around 140 °C—and produced smaller crystallites than the conventional heating. The minute crystallites were found to promote the removal characteristics for Cs+ ions in short reaction time.

Type
Rapid Communications
Information
Journal of Materials Research , Volume 15 , Issue 4 , April 2000 , pp. 850 - 853
Copyright
Copyright © Materials Research Society 2000

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References

REFERENCES

1.Jansen, J.C., Arafat, A., Barakat, A.K., and van Bekkum, H., in Synthesis of Microporous Materials, edited by Occelli, M.L. and Robson, H.E. (Van Nostrand Reinhold, New York, 1992), Vol. I, p. 507.Google Scholar
2.Araft, A., Jansen, J.C., Ebaid, A.R., and van Bekkum, H., Zeolites 13, 162 (1993).CrossRefGoogle Scholar
3.Girnus, I., Jancke, K., Vetter, R., Richter-Mendau, J., and Caro, J., Zeolites 15, 33 (1995).CrossRefGoogle Scholar
4.Carmona, J.G., Clemente, R.R., and Morales, J.G., Zeolites 18, 340 (1997).Google Scholar
5.Park, M. and Komarneni, S., Microporous Mesoporous Mater. 20, 39 (1998).CrossRefGoogle Scholar
6.Mintova, S., Mo, S., and Bein, T., Chem. Mater. 10, 4030 (1998).CrossRefGoogle Scholar
7.Komarneni, S., Roy, R., and Li, Q.H., Mater. Res. Bull. 27, 1393 (1992).Google Scholar
8.Komarneni, S., Li, Q., Stefansson, K.M., and Roy, R., J. Mater. Res. 8, 3176 (1993).CrossRefGoogle Scholar
9.Komarneni, S., Li, Q.H., and Roy, R., J. Mater. Chem. 4, 1903 (1994).Google Scholar
10.Komarneni, S., Pidugu, R., Li, Q.H., and Roy, R., J. Mater. Res. 10, 1687 (1995).CrossRefGoogle Scholar
11.Komarneni, S., Hussein, M.Z., Liu, C., Breval, E., and Malla, P.B., Eur. J. Solid State Inorg. Chem. 32, 837 (1995).Google Scholar
12.Komarneni, S., D'Arrigo, M.C., Leionelli, C., Pellacani, G.C., and Katsuki, H., J. Am. Ceram. Soc. 81, 3041 (1998).CrossRefGoogle Scholar
13.Hamid, S.A., Z. Kristallogr. 154, 189 (1981).Google Scholar
14.Sakiyama, M. and Mitsuda, T., Cem. Concr. Res. 7, 681 (1977).Google Scholar
15.Chan, C.F. and Mitsuda, T., Cem. Concr. Res. 8, 135 (1978).CrossRefGoogle Scholar
16.Komarneni, S. and Roy, D.M., Science 221, 647 (1983).Google Scholar
17.Komarneni, S., Breval, E., Miyake, M., and Roy, R., Clays Clay Miner. 35, 385 (1987).CrossRefGoogle Scholar
18.Miyake, M., Komarneni, S., and Roy, R., Mater. Res. Bull. 24, 311 (1989).CrossRefGoogle Scholar