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Kinetic study of (Bi,Pb)2Sr2Ca2Cu3O10+x phase formation in KCl flux

Published online by Cambridge University Press:  31 January 2011

Sergey Lee
Affiliation:
Superconductivity Research Laboratory, ISTEC, Koto-ku, Tokyo 135–0062, Japan
Ayako Yamamoto
Affiliation:
Superconductivity Research Laboratory, ISTEC, Koto-ku, Tokyo 135–0062, Japan
Setsuko Tajima
Affiliation:
Superconductivity Research Laboratory, ISTEC, Koto-ku, Tokyo 135–0062, Japan
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Abstract

The kinetics of (Bi,Pb)2Sr2Ca2Cu3O10+x phase formation in KCl flux was studied, and kinetic analysis using the Avrami relation for isothermal phase transformation gave the Avrami exponent n = 2.5 at 855 °C for the whole process of (Bi,Pb)-2223 phase formation. The estimated value of the activation energy Ea = 150 kJ/mol for the formation of (Bi,Pb)-2223 phase at 845–855 °C is the lowest among the previously reported values. The low value of activation energy explains the fast formation of single-phase (Bi,Pb)-2223 powder in the KCl flux.

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Articles
Copyright
Copyright © Materials Research Society 2002

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