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Intercalation of mixed chloride–fluorides of antimony in graphite

Published online by Cambridge University Press:  31 January 2011

W. R. Datars ,
H. Zaleski  and
P. K. Ummat
W. R. Datars
Affiliation:
Department of Physics, McMaster University, Hamilton, Ontario, L8S4M1 Canada
H. Zaleski
Affiliation:
Department of Physics, McMaster University, Hamilton, Ontario, L8S4M1 Canada
P. K. Ummat
Affiliation:
Department of Physics, McMaster University, Hamilton, Ontario, L8S4M1 Canada
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Abstract

The intercalation of SbCl4F and SbCl3F2 into graphite is described. The c-axis identity period, measured by (00/) x-ray diffraction, is 9.30, 12.69, and 16.04 Å for stages 1, 2, and 3, respectively, of SbCl4 F-intercalated graphite. The c-axis identity period for stage 1 SbCl4F-intercalated graphite is 8.85 Å. Mass spectroscopy shows that the molecule in SbCl4F-intercalated graphite is a (SbCl4F)4 tetramer. The molecule in SbCl3F2-intercalated graphite is a (SbCl3F2)4 tetramer. Mossbauer measurements show that Sb is in a 5 + state in SbCl4F-intercalated graphite.

Type
Articles
Information
Journal of Materials Research , Volume 3 , Issue 4 , August 1988 , pp. 705 - 709
Copyright
Copyright © Materials Research Society 1988

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References

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