Hostname: page-component-76fb5796d-zzh7m Total loading time: 0 Render date: 2024-04-25T12:55:33.410Z Has data issue: false hasContentIssue false
  • English
  • Français

Electrosynthesis and Microstructural Characterization of Anodic VOx Films

Published online by Cambridge University Press:  31 January 2011

J. P. Schreckenbach ,
D. Butte ,
G. Marx ,
B. R. Johnson  and
W. M. Kriven
J. P. Schreckenbach
Affiliation:
Institut für Chemie, Technische Universität Chemnitz, D-09111 Chemnitz, Germany
D. Butte
Affiliation:
Institut für Chemie, Technische Universität Chemnitz, D-09111 Chemnitz, Germany
G. Marx
Affiliation:
Institut für Chemie, Technische Universität Chemnitz, D-09111 Chemnitz, Germany
B. R. Johnson
Affiliation:
Department of Materials Science and Engineering, University of Illinois at Urbana- Champaign, Urbana, Illinois 61801
W. M. Kriven
Affiliation:
Department of Materials Science and Engineering, University of Illinois at Urbana- Champaign, Urbana, Illinois 61801
Get access

Abstract

Anodic conversion films of vanadium oxides on vanadium were potentiodynamically generated at high voltages in an acetate electrolyte system. The microstructure of the anodic VOx coatings was characterized by surface and solid-state techniques such as scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and x-ray photoelectron spectroscopy. An amorphous structure is proposed in which network-forming [VO4] tetrahedra in various degrees of condensation are connected by distorted [VO5] and [VO6] units. Such polyhedra lead to the formation of nanocrystalline phases of stoichiometric and substoichiometric vanadium oxides, which were observed in the amorphous phase.

Type
Articles
Information
Journal of Materials Research , Volume 15 , Issue 7 , July 2000 , pp. 1483 - 1489
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Thompson, G.E., Thin Solid Films 297, 192 (1997).CrossRefGoogle Scholar
2.Schreckenbach, J.P., Marx, G., Schlottig, F., Textor, M., and Spencer, N.D., J. Mater. Sci.: Mater. Med. 10, 1 (1999).Google Scholar
3.Schreckenbach, J.P., Schlottig, F., Marx, G., Kriven, W.M., Popoola, O.O., Jilavi, M.H., and Brown, S.D., J. Mater. Res. 14, 1437 (1999).CrossRefGoogle Scholar
4.Zhang, L., Cho, H.S., Li, F., Metzger, R.M., and Doyle, W.D., J. Mater. Sci. Lett. 17, 291 (1998).CrossRefGoogle Scholar
5.Julien, C., Nazri, G.A., and Bergström, O., Phys. Status Solidi B 201, 319 (1997).3.0.CO;2-T>CrossRefGoogle Scholar
6.Gorenstein, A., Khelfa, J.P., and Julien, C., in Solid-State Ionics IV, edited by Nazri, G-A., Tarascon, J-M., and Schreiber, M. (Mater. Res. Soc. Symp. Proc. 369, Pittsburgh, PA, 1995), p. 649.Google Scholar
7.Ramana, V., Hussain, O.M., Srinivasulu Naidu, B., Julien, C., and Balkanski, M., Mater. Sci. Eng. B 52, 32 (1998).CrossRefGoogle Scholar
8.Chen, Y., Xie, K., and Liu, Z.X., Appl. Surf. Sci. 133, 221 (1998).CrossRefGoogle Scholar
9.Keil, R.G. and Salomon, R.E., J. Electrochem. Soc. 115, 628 (1968).CrossRefGoogle Scholar
10.Arora, M.R. and Kelly, R., J. Mater. Sci. 12, 1673 (1977).CrossRefGoogle Scholar
11.Hornkjoel, S. and Hornkjoel, I.M., Electrochim. Acta 36, 577 (1991).CrossRefGoogle Scholar
12.Privman, M. and Hepel, T., J. Electroanal. Chem. 382, 137 (1995).CrossRefGoogle Scholar
13.Nabavi, M., Sanchez, C., and Livage, J., Philos. Mag. B 63, 941 (1991).CrossRefGoogle Scholar
14.Haber, J., Witko, M., and Tokarz, R., Appl. Catal. A 157, 3 (1997).CrossRefGoogle Scholar
15.Cui, J., Da, D., and Jiang, W., Appl. Surf. Sci. 133, 225 (1998).CrossRefGoogle Scholar
16.Schreckenbach, J.P. and Strauch, P., Appl. Surf. Sci. 143, 6 (1999).CrossRefGoogle Scholar
17.Schreckenbach, J.P., Witke, K., Butte, D., and Marx, G., Fres. J. Anal. Chem. 363, 211 (1999).CrossRefGoogle Scholar
18.Attos, O., Massot, M., Balkanski, M., Haro-Poniatowski, E., and Asomoza, M., J. Non-Cryst. Solids 210, 163 (1997).CrossRefGoogle Scholar
19.Sanchez, C., Livage, J., and Lucazeau, G., J. Raman Spectrosc. 12, 68 (1982).CrossRefGoogle Scholar
20.Witke, K., Klaffke, D., Skopp, A., and Schreckenbach, J.P., J. Raman Spectrosc. 29, 411 (1998).3.0.CO;2-D>CrossRefGoogle Scholar
21.Oppermann, H. and Brückner, W., Vanadiumoxide (AkademieVerlag, Berlin, Germany, 1983).Google Scholar
22.Mosset, A., Lecante, P., Galej, J., and Livage, J., Philos. Mag. B 46, 137 (1982).CrossRefGoogle Scholar
23.Grymonprez, G., Fiermans, L., and Vennik, J., Acta Crystallogr. A 33, 834 (1977).CrossRefGoogle Scholar
24.Rao, C.N.R and Raveau, B., Transition Metal Oxides (VCH Publishers, New York, 1995).Google Scholar