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Study on preparation of polyacrylonitrile/polyimide composite lithium-ion battery separator by electrospinning

Published online by Cambridge University Press:  20 February 2019

Lin Li Open the ORCID record for Lin Li [Opens in a new window] ,
Ping Liu ,
Qin Shan Fu ,
Yong Gong ,
Shi Rong Zhang ,
Heng Ji He  and
Jian Chen
Lin Li*
Affiliation:
Material Corrosion and Protection Key Laboratory of Sichuan Province, Sichuan University of Science and Engineering, Zigong 643000, China
Ping Liu
Affiliation:
Material Corrosion and Protection Key Laboratory of Sichuan Province, Sichuan University of Science and Engineering, Zigong 643000, China
Qin Shan Fu
Affiliation:
Material Corrosion and Protection Key Laboratory of Sichuan Province, Sichuan University of Science and Engineering, Zigong 643000, China
Yong Gong
Affiliation:
Material Corrosion and Protection Key Laboratory of Sichuan Province, Sichuan University of Science and Engineering, Zigong 643000, China
Shi Rong Zhang
Affiliation:
Material Corrosion and Protection Key Laboratory of Sichuan Province, Sichuan University of Science and Engineering, Zigong 643000, China
Heng Ji He*
Affiliation:
Material Corrosion and Protection Key Laboratory of Sichuan Province, Sichuan University of Science and Engineering, Zigong 643000, China
Jian Chen*
Affiliation:
Material Corrosion and Protection Key Laboratory of Sichuan Province, Sichuan University of Science and Engineering, Zigong 643000, China
*
a)Address all correspondence to this author. e-mail: jchenzg@aliyun.com
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Abstract

Compared with commercial polyolefin membranes, polyacrylonitrile (PAN) membrane prepared by electrostatic spinning has higher porosity, electrolyte uptake, thermal stability, and lithium-ion conductivity, etc. However, poor mechanical performance has largely limited the application of electrospun PAN separators. In this study, PAN/polyimide (PI) composite membrane is prepared by electrostatic spinning to improve the mechanical and electrochemical performances. Scanning electron microscopy, thermal analysis method, and electrochemical methods were used for evaluation of the electrospun composite membrane. The results show that the composite membrane possesses good thermal stability and exhibits better mechanical performance than pristine PAN membrane (increasing by 1.1 times in tension strength). The addition of PI can increase porosity and fluid absorption rate obviously. In addition, the composite membrane has high ionic conductivity (18.77 × 10−4 S/cm), wide electrochemical window (about 4.0 V), and excellent cycling performance. It can retain a discharge specific capacity of 153 mA h/g even after 50 cycles at 0.5 C. The electrospun PAN/PI membrane may be a promising candidate for lithium-ion battery separators.

Keywords

electrospinningPANPIcomposite separatorlithium-ion battery
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 4 , 28 February 2019 , pp. 642 - 651
Copyright
Copyright © Materials Research Society 2019 

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References

Arora, P. and Zhang, Z.: Battery separators. Chem. Rev. 104, 4419 (2016).CrossRefGoogle Scholar
Li, H., Zhang, B., Lin, B., Yang, Y.Z., Zhao, Y., and Wang, L.: Electrospun poly(ether ether ketone) nanofibrous separator with superior performance for lithium-ion batteries. J. Electrochem. Soc. 165, A939 (2018).CrossRefGoogle Scholar
Peng, K., Wang, B., and Ji, C.: A poly(ethylene terephthalate) nonwoven sandwiched electrospun polysulfonamide fibrous separator for rechargeable lithium ion batteries. J. Appl. Polym. Sci. 134, 44907 (2017).CrossRefGoogle Scholar
Zhang, Y., Wang, Z., Xiang, H., Shi, P., and Wang, H.: A thin inorganic composite separator for lithium-ion batteries. J. Membr. Sci. 509, 19 (2016).CrossRefGoogle Scholar
Sato, N.: Thermal behavior analysis of lithium-ion batteries for electric and hybrid vehicles. J. Power Sources 99, 70 (2001).CrossRefGoogle Scholar
Wang, Q.S., Ping, P., Zhao, X.J., Chu, G.Q., and Sun, J.H.: ChemInform abstract: Thermal runaway caused fire and explosion of lithium ion battery. J. Power Sources 208, 210 (2012).CrossRefGoogle Scholar
Ji, W.X., Wang, F., Qian, J.F., Cao, Y.L., Ai, X.P., and Yang, H.X.: 3, 4-ethylenedioxythiophene monomer as safety-enhancing additive for lithium ion batteries. J. Electrochem. 22, 271 (2016).Google Scholar
Li, H., Ji, W.X., Cao, Y.L., Zhan, H., Yang, H.X., and Ai, X.P.: Thermal runaway-preventing technologies for lithium-ion batteries. J. Energy Storage Sci. Technol. 3, 2095 (2018).Google Scholar
Liu, J., Liu, Y.B., Yang, W.X., Ren, Q., Li, F.G., and Huang, Z.H.: Lithium ion battery separator with high performance and high safety enabled by tri-layered SiO2@PI/m-PE/SiO2@PI nanofiber composite membrane. J. Power Sources 396, 265 (2018).CrossRefGoogle Scholar
Wu, D.Z., Shi, C., Huang, S.H., Qiu, X.C., Wang, H., Zhan, Z., Zhang, P., Zhao, J.B., Sun, D.H., and Lin, L.W.: Electrospun nanofibers for sandwiched polyimide/poly(vinylidene fluoride)/polyimide separators with the thermal shutdown function. Electrochim. Acta 176, 727 (2015).CrossRefGoogle Scholar
Wu, Y.S. and Hu, K.L.: Influence of Carbon Nanotubes on the Electrochemical Properties of Lithium-Ion Battery Anode Materials[C]//Proceedings of the 2nd International Conference on Intelligent Technologies and Engineering Systems (ICITES2013). Springer, Cham, 2014: 391–398.Google Scholar
Waterloo, U.O.: Ultra-thin nanomaterial is at the heart of a major battery breakthrough. Nat. Commun. (2015).Google Scholar
Cao, L., An, P., Xu, Z., and Huang, J.: Performance evaluation of electrospun polyimide non-woven separators for high power lithium-ion batteries. J. Electroanal. Chem. 767, 34 (2016).CrossRefGoogle Scholar
Chen, J., Zhang, D.J., and Zhang, T.J.: Preparation of thermoplastic polyimide ultrafine fiber nonwovens by electrospinning. J. Mater. Eng. 2, 1001 (2018).Google Scholar
Boriboon, D., Vongsetskul, T., Limthongkul, P., Kobsiriphat, W., and Tammawat, P.: Cellulose ultrafine fibers embedded with titania particles as a high performance and eco-friendly separator for lithium-ion batteries. Carbohydr. Polym. 189, 145 (2018).CrossRefGoogle ScholarPubMed
Cho, T.H., Sakai, T., Tanase, S., Kimura, K., Kondo, Y., and Tanaka, M.: Electrochemical performances of polyacrylonitrile nanofiber-based nonwoven separator for lithium-ion battery. Electrochem. Solid-State Lett. 10, 982 (2007).CrossRefGoogle Scholar
Raghavan, P., Manuel, J., Zhao, X.H., Kim, D.S., and Ahn, J.H.: Preparation and electrochemical characterization of gel polymer electrolyte based on electrospun polyacrylonitrile nonwoven membranes for lithium batteries. J. Power Sources 196, 6742 (2011).CrossRefGoogle Scholar
Ding, J., Kong, Y., Li, P., and Yang, J.R.: Polyimide/poly(ethylene terephthalate) composite membrane by electrospinning for nonwoven separator for lithium-ion battery. J. Electrochem. Soc. 159, A1474 (2012).CrossRefGoogle Scholar
Wu, Z.P., Wu, D.Z., Qi, S.L., Zhang, T., Cai, Q., Zhang, P., Zhang, Y.F., and Jin, R.G.: Effect of polyimide structure on the reflectivity and conductivity of silvered polyimide films. Polym. Mater. Sci. Eng. 22, 95 (2006).Google Scholar
Bo, Z.: DuPont develops barrier film for batteries. World Plast. 22, 6 (2010).Google Scholar
Hou, J., Jang, W., Kim, S.Y., Kim, J.H., and Byun, H.S.: Rapid formation of polyimide nanofiber membranes via hot-press treatment and their performance as Li-ion battery separators. RSC Adv. 8, 14958 (2018).CrossRefGoogle Scholar
Miao, Y.E., Zhu, G.N., Hou, H.Q., Xia, Y.Y., and Liu, T.X.: Electrospun polyimide nanofiber-based nonwoven separators for lithium-ion batteries. J. Power Sources 226, 82 (2013).CrossRefGoogle Scholar
Wang, Y., Wang, S.Q., Fang, J.Q., Ding, L.X., and Wang, H.H.: A nano-silica modified polyimide nanofiber separator with enhanced thermal and wetting properties for high safety lithium-ion batteries. J. Membr. Sci. 537, 248 (2017).CrossRefGoogle Scholar
Ma, X., Kolla, P., Yang, R., Zhao, W., Zhao, Y., Smirnova, A.L, and Fong, H.: Electrospun polyacrylonitrile nanofibrous membranes with varied fiber diameters and different membrane porosities as lithium-ion battery separators. Electrochim. Acta 236, 417 (2017).CrossRefGoogle Scholar
Li, J.D., Zhong, Q., Yao, Y.Y., Bi, S.H., Zhou, T., Guo, X.M., Wu, M.Q., Feng, T.T., and Xiang, R.L.: Electrochemical performance and thermal stability of the electrospun PTFE nanofiber separator for lithium-ion batteries. J. Appl. Polym. Sci. 135, 46508. (2018).CrossRefGoogle Scholar
Abada, S., Marlair, G., Lecocq, A., Petit, M., Sauvant-Moynot, V., and Huet, F.: Safety focused modeling of lithium-ion batteries: A review. J. Power Sources 306, 178 (2016).CrossRefGoogle Scholar
Yu, W., Lau, K.C., Lei, Y., Liu, R.L., Qin, L., Yang, W., Li, B.H., Curtiss, L.A., Zhai, D.Y., and Kang, F.Y.: A dendrite-free potassium-oxygen battery based on a liquid alloy anode. ACS Appl. Mater. Interfaces 9, 31871 (2017).CrossRefGoogle ScholarPubMed
Zhu, J., Wei, S., Dan, R., Neel, H., and David, P.Y.: Magnetic polyacrylonitrile-Fe@FeO nanocomposite fibers—Electrospinning, stabilization and carbonization. Polymer 52, 2947 (2011).CrossRefGoogle Scholar
Chen, H.L. and Jiao, X.N.: Preparation and characterization of Polyvinylidene fluoride/Octaphenyl-Polyhedral oligomeric silsesquioxane hybrid Lithium-ion battery separators by electrospinning. Solid State Ionics 134, 310 (2017).Google Scholar
Lin, X., Salari, M., Arava, L.M., Ajayanc, P.M., and Grinstaff, M.W.: High temperature electrical energy storage: Advances, challenges, and frontiers. Chem. Soc. Rev. 45, 5848 (2016).CrossRefGoogle ScholarPubMed