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Spreading dynamics and contact angle of completely wetting volatile drops

Published online by Cambridge University Press:  12 April 2018

Etienne Jambon-Puillet*
Affiliation:
Institute of Physics, Van der Waals-Zeeman Institute, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands
Odile Carrier
Affiliation:
Institute of Physics, Van der Waals-Zeeman Institute, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands
Noushine Shahidzadeh
Affiliation:
Institute of Physics, Van der Waals-Zeeman Institute, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands
David Brutin
Affiliation:
Aix-Marseille University, IUSTI UMR 7343, 13453 Marseille, France
Jens Eggers
Affiliation:
School of Mathematics – University of Bristol, University Walk, Bristol BS8 1TW, UK
Daniel Bonn
Affiliation:
Institute of Physics, Van der Waals-Zeeman Institute, University of Amsterdam, Science Park 904, 1098 XH Amsterdam, The Netherlands
*
Email address for correspondence: e.a.m.jambonpuillet@uva.nl

Abstract

The spreading of evaporating drops without a pinned contact line is studied experimentally and theoretically, measuring the radius $R(t)$ of completely wetting alkane drops of different volatility on glass. Initially the drop spreads ($R$ increases), then owing to evaporation reverses direction and recedes with an almost constant non-zero contact angle $\unicode[STIX]{x1D703}\propto \unicode[STIX]{x1D6FD}^{1/3}$, where $\unicode[STIX]{x1D6FD}$ measures the rate of evaporation; eventually the drop vanishes at a finite-time singularity. Our theory, based on a first-principles hydrodynamic description, well reproduces the dynamics of $R$ and the value of $\unicode[STIX]{x1D703}$ during retraction.

Type
JFM Papers
Copyright
© 2018 Cambridge University Press 

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