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Influence of Water on the Retention of Organic Probes on Clays Studied by IGC

Published online by Cambridge University Press:  28 February 2024

Henri Balard ,
Alain Saada ,
Bernard Siffert  and
Eugène Papirer
Henri Balard
Affiliation:
Institut de Chimie des Surfaces et Interfaces, 15, rue Starcky - B.P. 2488, F-68057 Mulhouse Cedex, France
Alain Saada
Affiliation:
Institut de Chimie des Surfaces et Interfaces, 15, rue Starcky - B.P. 2488, F-68057 Mulhouse Cedex, France
Bernard Siffert
Affiliation:
Institut de Chimie des Surfaces et Interfaces, 15, rue Starcky - B.P. 2488, F-68057 Mulhouse Cedex, France
Eugène Papirer
Affiliation:
Institut de Chimie des Surfaces et Interfaces, 15, rue Starcky - B.P. 2488, F-68057 Mulhouse Cedex, France
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Abstract

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Oil recovery is strongly related to the wettability of reservoir rocks that are formed of quartz grains attached by mineral hydroxides and clay minerals. Illites and kaolinites are the most active due to their high specific surface areas and electrical charge densities. Therefore, these minerals’ relative affinities for oil or water when in contact with a water-oil mix are of great importance. In order to model such a complex system, we used a mix of organic model molecules of the oil constituents and water vapor. Their interactions were estimated by inverse gas chromatography (IGC). IGC experiments were performed using a carrier gas with controlled humidity. By means of IGC at infinite dilution conditions, the dispersive component of the surface energy, γsd, was determined. A strong decrease of γsd, due to water molecules shielding the highest-energy sites, was observed. The energetic surface heterogeneity of the clays was examined using IGC at finite concentration conditions, allowing the determination of organic probe adsorption isotherms in the presence of water. From these isotherms, adsorption energy distribution functions were computed for propanol-2 and pyridine probes. Water mainly modifies the illite distribution functions, whereas practically no change was observed in the case of kaolinite. This observation is related to the higher hydrophilicity of illite as compared with kaolinite, and explains the different behaviors of the 2 clay families in oil reservoirs.

Keywords

IlliteInverse Gas ChromatographyKaoliniteSurface Energetic HeterogeneityWater Adsorption
Type
Research Article
Information
Clays and Clay Minerals , Volume 45 , Issue 4 , August 1997 , pp. 489 - 495
Copyright
Copyright © 1997, The Clay Minerals Society

References

Anderson, W.G., 1986 Wettability literature survey—Part 1: Rock/oil/brine interactions and the effect of core handling on wettability J Petrol Technol Oct 1125–1144.CrossRefGoogle Scholar
Balard, H., 1997 Estimation of the surface energetic heterogeneity of a solid by IGC method Langmuir 13 1260–1269 10.1021/la951526d.CrossRefGoogle Scholar
Balard, H. and Papirer, E., 1994 Surface heterogeneity of carbon black by IGC at finite concentration Polym Mater Sci Eng 70 456–459.Google Scholar
Balard, H. and Papirer, E., 1994 Grinding of mica monitored by IGC Polym Mater Sci Eng 70 512–515.Google Scholar
Balard, H. Yeates, D. Papirer, E. Gastiger, M. Bouard, P. Clauss, F. and Baeza, R., 1993 The modification of the surface of talc by the chemical vapor deposition of silica Proc MOF-FIS-93 Conf 217–220.Google Scholar
Bandosz, T.J. Jagie⌈⌈o, J. Andersen, B. and Schwartz, J.A., 1992 Inverse gas chromatography study of modified smectite surfaces Clays Clay Miner 40 306–310 10.1346/CCMN.1992.0400309.CrossRefGoogle Scholar
Chassin, P. Jouanay, C. and Quiquampoix, H., 1986 Measurement of the surface free energy of a calcium-montmorillonite Clay Miner 21 899–907 10.1180/claymin.1986.021.5.04.CrossRefGoogle Scholar
Conder, R.J. and Young, C.L., 1979 Physicochemical measurements by gas chromatography New York: J Wiley 385–390.Google Scholar
Cuiec, L., 1986 Mouillabilité et réservoirs pétroliers Revue de l’Institut Français du Pétrole 41 487–509 10.2516/ogst:1986029.CrossRefGoogle Scholar
Dannenberg, E.M. and Opie, W.H. Jr., 1958 A study of the moisture adsorption properties of carbon black Rubber World 136 6 849–855.Google Scholar
Dorris, G.M. and Gray, D.G., 1979 Adsorption spreading pressure and London force interactions of hydrocarbons on cellulose and wood fiber surfaces J Colloid Interface Sci 71 93–110 10.1016/0021-9797(79)90224-8.CrossRefGoogle Scholar
Dorris, G.M. and Gray, D.G., 1980 Adsorption of n-alkanes at zero surface coverage on cellulose paper and wood fibers J Colloid Interface Sci 77 353–362 10.1016/0021-9797(80)90304-5.CrossRefGoogle Scholar
Fassi-Fihri, O. Robin, M. and Rosenberg, E., 1992 Etude de la mouillabilité des roches réservoir à l’echelle du pore par cryomicroscopie à balayage Revue de l’Institut Français du Pétrole 47 685–701 10.2516/ogst:1992045.CrossRefGoogle Scholar
Flandrin, J. and Chapelle, J., 1961 Le pétrole Paris Editions Technip.Google Scholar
Giese, R.F. Costanzo, P.M. and van Oss, C.J., 1991 The surface free energies of talc and pyrophyllite Phys Chem Minerai 17 611–616 10.1007/BF00203840.CrossRefGoogle Scholar
Glaeser, R., 1954 Complexes organo-argileux et rôle des cations échangeables [Ph.D. thesis] Paris, France Faculté des Sciences 3473.Google Scholar
Grim, R.E., 1962 Applied clay mineralogy 2nd ed New York McGraw-Hill.CrossRefGoogle Scholar
Hadjar, H. Balard, H. and Papirer, E., 1995 An inverse gas chromatography study of crystalline and amorphous silicas Colloids Surf 99 1 45–51 10.1016/0927-7757(95)03131-V.CrossRefGoogle Scholar
Hobson, J.P., 1965 Analysis of physical adsorption isotherms on heterogeneous surfaces at very low pressures Can J Phys 43 1941–1950 10.1139/p65-188.CrossRefGoogle Scholar
Jagie⌈⌈o, J. and Schwarz, J., 1991 Local exact and approximate solutions of the adsorption integral equation with a kernel of Langmuir-like isotherm: Determination of adsorption energy distribution J Colloid Interface Sci 146 415–424 10.1016/0021-9797(91)90206-N.CrossRefGoogle Scholar
Jaroniec, M. and Madey, R., 1989 Physical adsorption on heterogeneous solids Amsterdam Elsevier 35.Google Scholar
Papirer, E. Balard, H., Dabrowski, A. and Tertykh, V.A., 1995 Chemical and morphological characteristics of inorganic sorbents in relation with gas adsorption Adsorption on new and modified inorganic sorbents Amsterdam Elsevier 479–502.Google Scholar
Papirer, E. Balard, H. Rahmani, Y. Legrand, A.P. Facchini, L. and Hommel, H., 1987 Characterization by inverse gas chromatography of the surface properties of silicas modified by poly(ethyleneglycols) and their models (oligomers, diols) Chromatographia 23 9 639–647 10.1007/BF02311491.CrossRefGoogle Scholar
Papirer, E. Li, S. Balard, H. and Jagiello, J., 1991 The surface energy and adsorption energy distribution measurements on some carbon blacks Carbon 29 8 1135–1143 10.1016/0008-6223(91)90031-D.CrossRefGoogle Scholar
Papirer, E. Perrin, J.M. Siffert, B. and Philipponneau, G., 1991 Surface characteristics of alumina in relation with polymer adsorption J Colloid Interface Sci 144 1 263–270 10.1016/0021-9797(91)90257-9.CrossRefGoogle Scholar
Robert, M. and Tessier, D., 1974 Méthode de préparation des argiles des sols pour des études minéralogiques Ann Agron 25 859–882.Google Scholar
Rudzinski, W. and Everett, D.H., 1992 Adsorption of gases on heterogeneous surfaces London Academic Pr.Google Scholar
Saada, A. Siffert, B. Balard, H. and Papirer, E., 1995 Determination of surface properties of illites and kaolinites by inverse gas chromatography J Colloid Interface Sci 175 212–218 10.1006/jcis.1995.1448.CrossRefGoogle Scholar
Saada, A. Siffert, B. and Papirer, E., 1995 Comparison between hydrophilicity/hydrophobicity of illites and kaolinites J Colloid Interface Sci 174 185–190 10.1006/jcis.1995.1381.CrossRefGoogle Scholar
van Oss, C.J., 1993 Acid-base interfacial interactions in aqueous media Colloids Surf 78 1–49 10.1016/0927-7757(93)80308-2.CrossRefGoogle Scholar