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The origin of spheroidal halloysites: a review of the literature

Published online by Cambridge University Press:  02 January 2018

F. Cravero  and
G. Jock Churchman
F. Cravero*
Affiliation:
Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Centro de Tecnología de Recursos Minerales y Cerámica (CETMIC–CIC–CONICET), C. C. 49, Manuel B. Gonnet B1897ZCA, Argentina
G. Jock Churchman
Affiliation:
School of Agriculture, Food and Wine, University of Adelaide, Adelaide 5005, Australia
*
*E-mail: fcravero@cetmic.unlp.edu.ar
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Abstract

Tubular halloysite has many applications as a nanomaterial. Spheroidal halloysite (SPH) is the other most common form of halloysite. Its mode of formation has had different explanations, including association with allophane, or more generally, following weathering of volcanic glass. Some SPHs have formed from minerals in crystalline rocks, sometimes as an early stage of evolution into plates and/or tubes of halloysite and ultimately to kaolinite. Spheroidal halloysites can show a range of Fe contents and can occur with other forms of halloysite; they have often formed in confined environments whereas tubular halloysites apparently form in more open spaces. They have also formed on microbes or where there is a significant amount of organic matter. Generally, SPHs have often formed by rapid dissolution of volcanic glass and primary minerals. The SPHs can persist over time. They have fewactive edges, so interparticle interaction is poor, causing low viscosities in clay-water suspensions, poor soil stability and low adsorption capacities.

Keywords

spheroidal halloysiteallophaneiron contentmicrobesorganic mattervolcanic glass
Type
Research Article
Information
Clay Minerals , Volume 51 , Issue 3 , June 2016 , pp. 417 - 427
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2016

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References

Adamo, P., Violante, P. & Wilson, M.J. (2001) Tubular and spheroidal halloysite in pyroclastic deposits in the area of the Roccamonfina volcano — southern Italy. Geoderma, 99, 295–316.10.1016/S0016-7061(00)00076-8Google Scholar
Askenasy, P.E., Dixon, J.B. & McKee, T.R. (1973) Spheroidal halloysite in Guatemalan soil. Soil Science Society of America Proceedings, 37, 799–803.10.2136/sssaj1973.03615995003700050045xGoogle Scholar
Bailey, S.W. (1990) Halloysite - A critical assessment. Pp. 89–98 in: Surface Chemistry Structure and Mixed Layering of Clays - Proceedings of the 9th International Clay Conference 1989, Strasbourg, France (V.C. Farmer & Y Tardy, editors). Sciences Géologiques, Mémoire 86, Strasbourg, France.Google Scholar
Birrell, K.S., Fieldes, M. & Williamson, K.I. (1955) Unusual forms of halloysite. American Mineralogist, 40, 122–124.Google Scholar
Certini, G., Wilson, M.J., Hillier, S.J., Fraser, A.R. & Delbos, E. (2006) Mineral weathering in trachydacitic-derived soils and saprolites involving formation of embryonic halloysite and gibbsite at Mt. Amiata, central Italy. Geoderma, 133, 173–190.10.1016/j.geoderma.2005.07.005Google Scholar
Churchman, G.J. (2000) The alteration and formation of soil minerals by weathering. Pp. F3-F76 in: Handbook of Soil Science (M.E. Sumner, editor). CRC Press, Boca Raton, Florida, USA.Google Scholar
Churchman, G.J. (2015) The identification and nomen-clature of halloysite (a historical perspective). Pp. 51–67 in: NaturalMineralNanotubes (P. Pasbakhsh & G.J. Churchman, editors). Apple Academic Press, Oakville, Canada.Google Scholar
Churchman, G.J. & Lowe, D.J. (2012) Alteration, formation, and occurrence of minerals in soils. Pp. 20.1-20.72 in: Handbook of Soil Sciences. 2nd Edition. Vol. 1, Properties and Processes (P.M. Huang, Y Li & M.E. Sumner, editors). CRC Press (Taylor & Francis), Boca Raton, Florida, USA.Google Scholar
Churchman, G.J. & Theng, B.K.G. (1984) Interactions of halloysites with amides: Mineralogical factors affecting complex formation. Clay Minerals, 19, 161–175.10.1180/claymin.1984.019.2.04Google Scholar
Churchman, G.J., Davy, T.J., Aylmore, L.A.G., Gilkes, R.J. & Self, P.G. (1995) Characteristics of fine pores in some halloysites. Clay Minerals, 30, 89–98.10.1180/claymin.1995.030.2.01Google Scholar
Churchman, G.J., Pasbakhsh, P., Lowe, D.J. & Theng, B.K.G. (2016) Unique but diverse: some observations on the formation, structure and morphology of halloysite. Clay Minerals, 51, 395–16.10.1180/claymin.2016.051.3.14Google Scholar
Cravero, F., Martínez, G.A. & Pestalardo, F. (2009) Yacimientos de halloysita en Mamil Choique, Provincia de Río Negro, Patagonia. Revista de la Asociación Geológica Argentina, 65, 586–592.Google Scholar
Cravero, F., Maiza, P. & Marfil, S. (2012) Halloysite in Argentinian deposits. Origin and textural constraints. Clay Minerals, 47, 329–340.10.1180/claymin.2012.047.3.04CrossRefGoogle Scholar
Cravero, F., Marfil, S., Ramos, C. & Maiza, P. (2014) Coexistence of halloysite and iron-bearing clays in an altered ignimbrite, Patagonia, Argentina. Clay Minerals, 49, 377–389.10.1180/claymin.2014.049.3.06CrossRefGoogle Scholar
Cravero, F., Fernandez, L.G., Marfil, S.A., Sanchez, M., Maiza, P. & Martinez, A. (2016) Spheroidal halloysites from Patagonia, Argentina: Some aspects of their formation and applications. Applied Clay Science, 131, 48–58.10.1016/j.clay.2016.01.011CrossRefGoogle Scholar
Daltry, V.D.C. & Deliens, M. (1993) The type mineralogy of Belgium. Annales de la Société géologique de Belgique, 116, 15–28.Google Scholar
de Oliveira, M.T.G., Petit, S., Grauby, O., Formoso, M.L.L. & Trescases, J.J. (1997) Characterization and distribution of halloysitic clay minerals in weathered basalts (southern Parana basin, Brasil). Anais da Academia Brasileira de Ciencias, 69, 179–192.Google Scholar
Dixon, J.B. & McKee, T.R. (1974) Spherical halloysite formation in a volcanic soil of Mexico. Pp. 115–124 in: Transactions of the 10th International Congress of the Soil Sciences, Moscow, USSR.Google Scholar
Fieldes, M. (1955) Clay mineralogy of New Zealand soils. Allophane and related mineral colloids. New Zealand Journal of Science and Technology, B36, 140–154.Google Scholar
Henmi, T. & Wada, K. (1976) Morphology and composition of allophane. American Mineralogist, 61, 379–390.Google Scholar
Imbert, T. & Desprairies, A. (1987) Neoformation of halloysite on volcanic glass in a marine environment. Clay Minerals, 22, 179–185.10.1180/claymin.1987.022.2.06Google Scholar
Jeong, G.Y. & Kim, S.J. (1993) Boxwork fabric of halloysite-rich kaolin formed by weathering of anorthosite in the Sancheong area, Korea. Clays and Clay Minerals, 41, 56–65.Google Scholar
Johnson, S.L., Guggenheim, S. & Koster Van Groos, A.F. (1990) Thermal stability of halloysite by high-pressure differential thermal analysis. Clays and Clay Minerals, 38, 477–484.10.1346/CCMN.1990.0380503Google Scholar
Joussein, E., Petit, S., Churchman, J., Theng, B., Righi, D. & Delvaux, B. (2005) Halloysite clay minerals — a review. Clay Minerals, 40, 383–426.10.1180/0009855054040180Google Scholar
Kawano, M. & Tomita, K. (1995) Experimental study on the formation of clay minerals from obsidian by interaction with acid solution at 150° and 200°C. Clays and Clay Minerals, 43, 212–222.10.1346/CCMN.1995.0430208Google Scholar
Kirkman, J.H. (1975) Clay Mineralogy of some tephra beds of Rotorua Area, North Island, New Zealand. Clay Minerals, 10, 437–447.Google Scholar
Kirkman, J.H. (1977) Possible structure of halloysite disks and cylinders observed in some New Zealand rhyolitic tephras. Clay Minerals, 12, 199–215.10.1180/claymin.1977.012.3.03Google Scholar
Kirkman, J.H. (1981) Morphology and structure of halloysite in New Zealand tephras. Clays and Clay Minerals, 29, 1–9.Google Scholar
Loughnan, F.C. & Roberts, F.I. (1981) The natural conversion of ordered kaolinite to halloysite (10 Å) at Burning Mountain near Wingen, New South Wales. American Mineralogist, 66, 997–1005.Google Scholar
McIntosh, P.D. (1979) Halloysite in a New Zealand tephra and paleosol less than 2500 years old. New Zealand Journal of Science, 22, 49–54.Google Scholar
Mellor, J.W. (1908) A note on the nomenclature of clays. Transactions of the English Ceramic Society, 8, 23–30.Google Scholar
Moon, V.G., Lowe, D.J., Cunningham, M.J., Wyatt, J., Churchman, G.J., de Lange, W.P., Mörz, T., Kreiter, S., Kluger, M.O. & Jorat, M.E. (2015) Sensitive pyroclas-tic-derived halloysitic soils in northern New Zealand: interplay of micro structure, minerals, and geomecha-nics. Pp. 3–21 in: Volcanic Rocks and Soils. Proceedings of the International Workshop on Volcanic Rocks and Soils, Lacco Ameno, Ischia Island, Italy, 24-25 September, 2015 (T Rotonda, M. Cecconi, F Silvestri & P. Tommasi, editors). Taylor and Francis Group, London.Google Scholar
Nagasawa, K. (1969) Kaolin minerals in cenozoic sediments in central Japan. Pp. 15–30 in: Proceedings of the International Clay Conference 1969, Tokyo, Japan (L. Heller, editor). Israel University Press, Jerusalem.Google Scholar
Nagasawa, K. & Miyazaki, S. (1976) Mineralogical properties of halloysite as related to its genesis. Pp. 257–265 in: Proceedings of the International Clay Conference 1975, Mexico City, Mexico (S.W. Bailey, editor). Applied Publishing Ltd, Wilmette, USA.Google Scholar
Nagasawa, K. & Noro, H. (1987) Mineralogical properties of halloysites of weathering origin. Chemical Geology, 60, 145–149.10.1016/0009-2541(87)90120-3CrossRefGoogle Scholar
Nakamura, M.T. & Sherman, G.D. (1965) The genesis of halloysite and gibbsite from mugearite on the island of Maui. Hawaii Agricultural Experimental Statio, Technical Bulletin, 62, 36 p. cited by: Askenasy P.E., Dixon J.B. & McKee T.R. (1973) Spheroidal halloysite in Guatemalan soil. Soil Science Society of America Proceedings, 37, 799–803.Google Scholar
Papoulis, D., Tsolis-Katagas, P. & Katagas, C. (2004) Progressive stages in the formation of kaolinite from halloysite in the weathering of plagioclase. Clays and Clay Minerals, 52, 271–285.CrossRefGoogle Scholar
Parfitt, R.L., Russell, M. & Orbell, G.E. (1983) Weathering sequence of soils from volcanic ash involving allophane and halloysite, New Zealand. Geoderma, 29, 41–57.10.1016/0016-7061(83)90029-0Google Scholar
Parham, W.E. (1970) Clay Mineralogy and Geology of Minnesota's Kaolin Clays. Minnesota Geological Survey Special Publication Series SP-10. Minneapolis, Minnesota, USA. 142 pp.Google Scholar
Pasbakhsh, P., Churchman, G.J. & Keeling, J.L. (2013) Characterisation of properties of various halloysites relevant to their use as nanotubes and microfibre fillers. Applied Clay Science, 74, 47–57.10.1016/j.clay.2012.06.014Google Scholar
Quantin, P. & Rambaud, D. (1987) Genesis of spherical halloysite from basaltic ash, at Ambryn (Vanuatu). Pp. 505–522 in: Geochemistry and Mineral Formation at the Earth Surface (R. Rodríguez Clemente & Y. Tardy, editors). CSIC, Madrid.Google Scholar
Quantin, P., Gautheyrou, J. & Lorenzoni, P. (1988) Halloysite formation through in situ weathering of volcanic glass from trachytic pumices, Vico's Volcano, Italy. Clay Minerals, 23, 423–437.10.1180/claymin.1988.023.4.09Google Scholar
Romero, R., Robert, M., Elsass, F. & Garcia, C. (1992) Abundance of halloysite neoformation in soils developed from crystalline rocks. Contribution of transmission electron microscopy. Clay Minerals, 27, 35–46.10.1180/claymin.1992.027.1.04Google Scholar
Saigusa, M., Shoji, S. & Kato, T. (1978) Origin and nature of halloysite in ando soils from Towada tephra, Japan. Geoderma, 20, 115–129.10.1016/0016-7061(78)90039-3Google Scholar
Sieffermann, G. & Millot, G. (1969) Equatorial and tropical weathering of recent basalts from Cameroon: allo-phanes, halloysite, metahalloysite, kaolinite and gibbsite. Pp. 417–430 in: Proceedings of the International Clay Conference 1969, Tokyo, Japan (L. Heller, editor). Israel University Press, Jerusalem.Google Scholar
Singer, A., Zarei, M., Lange, F.M. & Stahr, K. (2004) Halloysite characteristics and formation in the northern Golan Heights. Geoderma, 123, 279–295.10.1016/j.geoderma.2004.02.012Google Scholar
Smalley, I.J., Ross, C.W. & Whitton, J.S. (1980) Clays from New Zealand support the inactive particle theory of soil sensitivity. Nature, 288, 576–577.Google Scholar
Sudo, T. (1953) Particle shape of a certain clay of hydrated halloysite, as revealed by the electron microscope. Mineralogical Journal, 1, 66–68.10.2465/minerj1953.1.66Google Scholar
Sudo, T. & Takahashi, H. (1955) Shapes of halloysite particles in Japanese clays. Clays and Clay Minerals, 4, 67–79.CrossRefGoogle Scholar
Tazaki, K. (1982) Analytical electron microscopic studies of halloysite formation processes: morphology and composition of halloysite. Pp. 573–584 in: Proceedings of the 7th International Clay Conference 1981, Bologna and Pavia, Italy (H. Van Olphen & F. Veniale, editors). Developments in Sedimentology, 35, Elsevier, Amsterdam.Google Scholar
Tazaki, K. (2005) Microbial formation of a halloysite-like mineral. Clays and Clay Minerals, 53, 224–233.10.1346/CCMN.2005.0530303Google Scholar
Theng, B.K.G. & Wells, N. (1995) The flow characteristics of halloysite suspensions. Clay Minerals, 30, 99–106.10.1180/claymin.1995.030.2.02Google Scholar
Theng, B.K.G., Russell, M., Churchman, G.J. & Parfitt, R.L. (1982) Surface properties of allophane, halloysite, and imogolite. Clays and Clay Minerals, 30, 143–149.10.1346/CCMN.1982.0300209Google Scholar
Tomura, S., Shibasaki, Y., Mizuta, H. & Kitamura, M. (1985) Growth conditions and genesis of spherical and platy kaolinite. Clays and Clay Minerals, 33, 200–206.10.1346/CCMN.1985.0330305Google Scholar
Wada, K. & Kakuto, Y. (1985) Embryonic halloysite in Ecuadorian soils derived from volcanic ash. Soil Science Society of America Journal, 49, 1309–1318.Google Scholar
Wada, K., Yamauchi, H., Kakuto, Y. & Wada, S.I. (1985) Embryonic halloysite in a paddy soil derived from volcanic ash. Clay Science, 6, 177–186.Google Scholar
Ward, C. & Roberts, F.I. (1990) Occurrence of spherical halloysite in bituminous coals of the Sydney Basin, Australia. Clays and Clay Minerals, 38, 501–506.10.1346/CCMN.1990.0380506Google Scholar
Wilke, B.M., Schwertmann, U. & Murad, E. (1978) An occurrence of polymorphic halloysite in granite saprolite of the Bayerisher Wald, Germany. Clay Minerals, 13, 66–67.Google Scholar
Wilson, M.J. & Tait, J.M. (1977) Halloysite in some soils from North-East Scotland. Clay Minerals, 12, 59–66.10.1180/claymin.1977.012.1.05Google Scholar
Wilson, M.J., Certini, G., Campbell, C.D., Anderson, I.C. & Hillier, S. (2008) Does the preferential microbial colonisation of ferromagnesian minerals affect mineral weathering in soil. Naturwissenschaften, 95, 851–858.Google Scholar
Yuan, P., Tan, D. & Annabi-Bergaya, F. (2015) Properties and applications of halloysite nanotubes: recent research advances and future prospects. Applied Clay Science, 112-113, 75–93.10.1016/j.clay.2015.05.001Google Scholar