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Origin and distribution of clay minerals in calcareous arid and semi-arid soils of Fars Province, southern Iran

Published online by Cambridge University Press:  09 July 2018

F. Khormali  and
A. Abtahi
F. Khormali*
Affiliation:
Department of Soil Science, College of Agriculture, Shiraz University, ShirazIran
A. Abtahi
Affiliation:
Department of Soil Science, College of Agriculture, Shiraz University, ShirazIran
*
*E-mail: fkhormali@hotmail.com
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Abstract

The clay mineralogy of soils and of the main calcareous sedimentary parent rocks of southern Iran were investigated to determine their origin and factors controlling their distribution pattern in soils. The results revealed that the soil-available moisture plays the major role in the distribution pattern of palygorskite and smectite clay minerals in the arid and semi-arid areas studied. There is an inverse correlation between palygorskite and smectite with regard to the soil-available moisture as expressed by P/ETº (ratio of mean annual precipitation to mean annual reference crop evapotranspiration). At P/ETº values >0.4 palygorskite transforms to smectite. Smectite is thought to be mainly of ‘transformed’ origin. It is detected in trace amounts in soils of more arid areas and increases in soils having greater available moisture. The general decrease in illite content with depth is related mainly to its transformation to smectite under favourable moisture conditions of the deeper horizons. Palygorskite is considered to be inherited in plateau soils of the arid regions whereas in saline and alkaline soils and soils with high gypsum, it is mainly of authigenic origin. The P/ETº and gypsum content show a significant correlation with the palygorskite content. The occurrence of kaolinite in some soils is due to its inheritance from the surrounding kaolinite-bearing Cretaceous rocks. Illite and chlorite abundance in soils is also largely related to their presence in parent rocks. The rare occurrence of vermiculite in the studied calcareous soils is mainly related to its lower stability under high pH, low Al activity and the presence of large amounts of Si and Mg in soils.

Keywords

clay mineralogypalygorskite, smectiteP/ETºgypsum arid and semi-arid climateclay pedogenesis
Type
Research Article
Information
Clay Minerals , Volume 38 , Issue 4 , December 2003 , pp. 511 - 527
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2003

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References

Aba-Huseyn, M.M., Dixon, J.B. & Lee, S.Y. (1980) Mineralogy of Saudi Arabian soils: south western region. Soil Science Society of America Journal, 44, 643–649.Google Scholar
Abtahi, A. (1977) Effect of a saline and alkaline ground water on soil genesis in semiarid southern Iran. Soil Science Society of America Journal, 41, 583–588.CrossRefGoogle Scholar
Abtahi, A. (1985) Synthesis of sepiolite at room temperature from SiO2 and MgCl2 solution. Clay Minerals, 20, 521– 523.CrossRefGoogle Scholar
Abtahi, A. & Khormali, F. (2001) Genesis and morphological characteristics of Mollisols formed in a catena under water Table influence in southern Iran. Communications in Soil Science and Plant Analysis, 32, 1643–1658.CrossRefGoogle Scholar
Al Ravi, A.H., Jackson, M.L. & Hole, F.D. (1969) Mineralogy of some arid and semiarid land soils of Iraq. Soil Science, 107, 480–486.CrossRefGoogle Scholar
Aoudjit, M., Robert, M., Elsass, F. & Curmi, P. (1995) Detailed study of smectite genesis in granitic saprolites by analytical electron microscopy. Clay Minerals, 30, 135– 147.Google Scholar
Banaei, M.H. (1998) Soil Moisture and Temperature Regime Map of Iran. Soil and Water Research Institute, Ministry of Agriculture, Tehran, Iran.Google Scholar
Boettinger, J.L. & Southard, R.J. (1995) Phyllosilicate distribution and origin in Aridisols on a granitic pediment, Western Mojave Desert. Soil Science Society of America Journal, 59, 1189–1198.Google Scholar
Borchardt, G. (1989) Smectites. Pp. 675–727 in. Minerals in Soil Environment (Dixon, J.B. & Weed, S.B, editors.) Soil Science Society of America, Madison, Wisconsin, USA.Google Scholar
Bronger, A., Winter, R. & Sedov, S. (1998) Weathering and clay mineral formation in two Holocene soils and in buried paleosols in Tadjikestan: Towards a Quaternary paleoclimatic record in Central Asia. Catena, 34, 19–34.Google Scholar
Burnett, A.D., Fookes, P.G. & Robertson, R.H.S. (1972) An engineer ing soil at Kermanshah, Zagros Mountains, Iran. Clay Minerals, 9, 329–343.Google Scholar
Callen, R.A. (1984) Clays of palygorskite-sepiolite group: depositional environment, age and distribution. Pp. 1–38 in. Palygor skite- sepiol ite: Occurrences, Genesis and Uses (A. Singer & E. Galán, editors). Developments in Sedimentology, 37. Elsevier, Amsterdam.Google Scholar
Chapman, H.D. (1965) Cation exchange capacity. Pp. 891–900 in. Methods of Soil Analysis Part 2 (Black., C.A. editor). American Society of Agronomy, Madison, Wisconsin, USA.Google Scholar
Curtis, C.D. (1983) Link between aluminium mobility and destruction of secondary porosity. American Association of Petroleum Geology Bulletin, 67, 380–384.Google Scholar
Day, P.R. (1965) Particle fractionation and particle-size analysis. Pp. 545– 566.in. Methods of Soil Analysis Part 1 (Black., C.A. editor). American Society of Agronomy, Madison, Wisconsin, USA.Google Scholar
Dixon, J.B. (1989) Kaolin and serpentine group minerals. Pp. 467–525 in. Minerals in Soil Environment (Dixon, J.B. & Weed, S.B, editors). Soil Science Society of America, Madison, Wisconsin, USA.Google Scholar
Douglas, L.A. (1989) Vermiculites. Pp. 635–674 in. Minerals in Soil Environment (Dixon, J.B. & Weed, S.B, editors). Soil Science Society of America, Madison, Wisconsin, USA.Google Scholar
Dregne, H.E. (1976) Soils of Arid Regions. Elsevier, New York. Google Scholar
Ducloux, J., Guero, Y. & Fallavier, P. (1998) Clay particle differentiation in Alluvial soils of Southwestern Niger (West Africa). Soil Science Society of America Journal, 62, 212–222.Google Scholar
Eswaran, H. & Barzanji, A.F. (1974) Evidence for the neoformation of attapulgite in some soils of Iraq. Transactions of the 10th International Congress of Soil Science, Moscow, Russia, 7, 154– 161.Google Scholar
Fanning, D.S., Keramidas, V.Z. & El-Desoky, M.A. (1989) Micas. Pp. 551–634 in. Minerals in Soil Environment (Dixon, J.B. & Weed., S.B. editors). Soil Science Society of America, Madison, Wisconsin, USA.Google Scholar
Gharaee, H.A. & Mahjoory, R.A. (1984) Characteristics and geomorphic relationships of some representative Aridisols in southern Iran. Soil Science Society of America Journal, 48, 115–119.CrossRefGoogle Scholar
Givi, J. & Abtahi, A. (1985) Soil genesis as affected by topography and depth of saline and alkaline groundwater under semiarid conditions in southern Iran. Iran Agricultural Research, 4, 11– 27.Google Scholar
Hassouba, H. & Shaw, H.F. (1980) The occurrence of palygorskite in Quaternary sediments of the coastal plain of northwest Egypt. Clay Minerals, 15, 77– 83.CrossRefGoogle Scholar
Henderson, S.G. & Robertson, R.H.S. (1958) A Mineralogical Reconnaissance in Western Iran. Resource Use Ltd., Glasgow, UK.Google Scholar
Ingles, M. & Anadon, P. (1991) Relationship of clay minerals to depositional environment in the nonmarine Eocene Pontils Group, SE Ebro Basin (Spain). Journal of Sedimentary Petrology, 61, 926– 939.Google Scholar
Jackson, M.L. (1975) Soil Chemical Analysis. Advanced Course. University of Wisconsin, College of Agricult ure, Department of Soils, Madison , Wisconsin, USA.Google Scholar
Johns, W.D., Grim, R.E. & Bradley, F. (1954) Quantitative estimation of clay minerals by diffraction methods. Journal of Sedimentary Petrology, 24, 242– 251.Google Scholar
Khademi, H. & Mermut, A.R. (1998) Source of palygorskite in gypsiferous Aridisols and associated sediments from central Iran. Clay Minerals, 33, 561– 575.Google Scholar
Khademi, H. & Mermut, A.R. (1999) Submicroscopy and stable isotope geochemistry of carbonates and associat ed palygorsk ite in Iranian Aridisol s. European Journal of Soil Science, 50, 207–216.Google Scholar
Khormali, F. & Abtahi, A. (2001) Soil genesis and mineralogy of three selected regions of Fars, Bushehr and Khuzestan Provinces of Iran, formed under highly calcareous conditions. Iran Agricultural Research, 20, 67–82.Google Scholar
Kittrick, J.A. & Hope, E.W. (1963) A procedure for the particle size separation of soils for X-ray diffraction analysis. Soil Science, 96, 312–325.CrossRefGoogle Scholar
Lopez-Galindo, A., Ben Aboud, A., Fenoll Hach-Ali, P. & Casas Ruiz, J. (1996) Mineralogical and geochemical characterization of palygorskite from Gabasa (NE Spain). Evidence of a detrital precursor. Clay Minerals, 31, 33–44.CrossRefGoogle Scholar
Mahjoory, R.A. (1975) Clay mineralogy, physical and chemical properties of some soils in arid regions of Iran. Soil Science Society of America Proceedings, 39, 1157–1164.Google Scholar
McFadden, L.D., Wells, S.G. & Dohrenwend, J.C. (1986) Influences of Quaternary climatic changes on the processes of soil development on desert loess deposits of the Cima volcanic field, California. Catena, 13, 361–389.CrossRefGoogle Scholar
Mehra, O.P. & Jackson, M.L. (1960) Iron oxide removal from soils and clays by a dithionite citrate system with sodium bicarbonate. Clays and Clay Minerals, 7, 317–327.Google Scholar
MPB (Ministry of Programming and Budgeting) (1994) Economic and Social Status of Fars Province. Publication Center for Informatic and Development Studies (in Farsi).Google Scholar
Myriam, M. (1998) Structural and textural modifications of palygorskite and sepiolite under acid treatment. Clays and Clay Minerals, 46, 225–231.Google Scholar
Nelson, R.E. (1982) Carbonate and gypsum. Pp. 181–199 in: Methods of Soil Analysis part 2 (Page., A.L. editor). American Society of Agronomy, Madison, Wisconsin, USA.Google Scholar
Nettleton, W.D. & Peterson, F.F. (1983) Aridisols. Pp. 165 –216 in. Pedogenesis and Soil Taxonomy : Part 2. The Soil Orders. (Wilding., L.P. Smeck, N.E. & Hall., G.F. editors). Elsevier Science Publishers, B.V., Amsterdam.Google Scholar
Nettleton, W.D., Nelson, R.E. & Flach, K.W. (1973) Formation of mica in surface horizons of dryland soils. Soil Science Society of America Proceedings, 37, 473–478.CrossRefGoogle Scholar
Niederbudde, E.A. & Kussmaul, H. (1978) Tonmineral eigenschaften und Umwandlungen in Parabraunerde- Profilpaeren unter Acker und Wald in Suddeutschland. Geoderma, 20, 239–255.Google Scholar
Paquet, H. & Millot, G. (1972) Geochemical evolution of clay minerals in the weathered products and soils of Mediter ranean climates. Pp. 199 –202 in. Proceedings of the International Clay Conference, Madrid, Spain.Google Scholar
Pletsch, T., Daoudi, L., Chamley, H., Deconinck, J.F. & Charroud, M. (1996) Palaeogeographic controls on palygorskite occurrence in Mid-Cretaceous sediments of Morocco and adjacent basins. Clay Minerals, 31, 403–416.Google Scholar
Roads, M., Luque, F.J., Mas, R. & Garzon, M.G. (1994) Calcretes, palycretes and silcretes in the Paleogene detrital sediments of the Duero and Tajo Basins, Central Spain. Clay Minerals, 29, 273–285.CrossRefGoogle Scholar
Sadeghi, A.R., Kamgar-Haghighi, A.A., Sepaskhah, A.R., Khalili, D. & Zand-Parsa, Sh. (2002) Regional classification for dryland agriculture in southern Iran. Journal of Arid Environments, 50, 333–341.CrossRefGoogle Scholar
Salinity Laboratory Staff (1954) Diagnosis and Improvement of Saline and Alkali Soils. USDA Handbook No. 60. Washington, D.C.Google Scholar
Sanchez, H.S. & Galán, E. (1995) An approach to the genesis of palygorskite II. A neogene-Quaternary continental basin using principle factor analysis. Clay Minerals, 30, 225–238.Google Scholar
Sanguesa, F.J., Arostegui, J. & Suarez-Ruiz, I. (2000) Distribution and origin of clay minerals in the Lower Cretaceous of the Alava Block (Basque-Cantabrian Basin, Spain). Clay Minerals, 35, 393–410.Google Scholar
Singer, A. (1989) Palygorskite and sepiolite group minerals. Pp. 829– 872.in. Minerals in Soil Environment (Dixon, J.B. & Weed, S.B, editors.) Soil Science Society of America, Madison , Wisconsin, USA.Google Scholar
Singer, A., Kirsten, W. & Buhmaan, C. (1995) Fibrous clay minerals in the soils of Namaqualand, South Africa: Characteristics and formation. Geoderma, 66, 43–70.Google Scholar
Soil Survey Staff (1993) Soil Survey Manual. Handbook No. 18. USDA, Washington, DC.Google Scholar
Soil Survey Staff (1998) Keys to Soil Taxonomy. USDA, NRCS, Washington, D.C.Google Scholar
Suarez, M. (1994) Evidence of a precursor in the neoformation of palygorskite: new data by analytical electron microscopy. Clay Minerals, 29, 255–264.Google Scholar
Wilson, M.J. (1993) Pedologic factors influencing the distribution and properties of soil smectite. Trends in Agricultural Science, 1, 199– 216.Google Scholar
Wilson, M.J. (1999) The origin and formation of clay minerals in soils: past, present and future perspectives. Clay Minerals, 34, 7–24.Google Scholar
Zahedi, M. (1976) Explanatory text of the Esfahan quadrangle map 1:250000. Geological Survey of Iran.Google Scholar