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Characterization of FeOOH polymorphs and ferrihydrite using low-temperature, applied-field, Mössbauer spectroscopy

Published online by Cambridge University Press:  09 July 2018

R. J. Pollard ,
C. M. Cardile ,
D. G. Lewis  and
L. J. Brown
R. J. Pollard
Affiliation:
Department of Physics, Monash University, Clayton, VIC 3168
C. M. Cardile
Affiliation:
CSIRO Division of Mineral Products, Floreat Park, WA 6014
D. G. Lewis
Affiliation:
Waite Agricultural Research Institute, Glen Osmond, SA 5064, Australia
L. J. Brown
Affiliation:
Department of Physics, Monash University, Clayton, VIC 3168
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Abstract

Mössbauer spectroscopy obtained with the sample at low temperatures and subject to large magnetic fields is discussed in terms of its use in analysing the naturally occurring polymorphs of FeOOH and the common growth precursor, ferrihydrite. Experiments on well-characterized synthetic samples provided benchmark results. A relatively simple means of quantitative analysis was used, in which sextets of Voigtian-shaped lines were summed and least-squares fitted. The results are discussed in terms of the magnetic structures of each compound.

Type
Research Article
Information
Clay Minerals , Volume 27 , Issue 1 , March 1992 , pp. 57 - 71
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1992

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References

Bowen, L.H. (1979) Mössbauer spectroscopy of ferric oxides and hydroxides. Pp. 76–94 in . Mössbauer Effect Reference and Data Journal, vol. 2 (Stevens, J.G., Stevens, V.E. & Gettys, W.L., editors). Univ. of North Carolina, Asheville.Google Scholar
Bowen, L.H., De Grave, E., de Barker, P.M.A. & Vandenberghe, R.E. (1990) Hyperfine interactions of aluminium-substituted goethites in external magnetic fields. Hyperfine Interact., 54, 467–472.Google Scholar
Brož, D., Šolcova A., Subrt, J., Sedlak, B., Zounova, F. & Reiman, S.I. (1989) Magnetic properties of goethite with varying particle size. Acta Phys. Slov., 39, 235–238.Google Scholar
Carlson, L. & Schwertmann, U. (1980) Natural occurrence of feroxyhite (^'-FeOOH). Clays Clay Miner., 28, 272–280.Google Scholar
Childs, C.W., Goodman, B.A., Paterson, E. & Woodhams, F.W.D. (1980) The nature of iron in akaganeit. (p-FeOOH). Aust. J. Chem., 33, 15–26.Google Scholar
Coey, J.M.D. & Readman, P.W. (1973a) New spin structure in an amorphous ferric gel. Nature, 246, 476–478.CrossRefGoogle Scholar
Coey, J.M.D. & Readman, P.W. (1973b) Characterisation and magnetic properties of natural ferric gel. Earth Planetary Sci. Lett., 21, 45–51.CrossRefGoogle Scholar
De Barker, P.M.A., De Grave, E., Persoons, R.M., Bowen, L.H. & Vandenberghe, R.E. (1990) An improved, two-parameter distribution method for the description of the Mössbauer spectra of magnetic small particles in an applied field. Meas. Sci. Technol., 1, 954–964.Google Scholar
De Grave, E., Vandenberghe, R.E. & Bowen, L.H. (1990) Magnetic properties of some selected, soil-related iron oxides and oxyhydroxides as probed by 57Fe Mössbauer spectroscopy. Pp. 186-239 in: Proc. XXIV Zakopane School on Physics, vol. 2 (Stanek, J. & Pedziwiatr, A.T., editors). World Scientific, Singapore.Google Scholar
Eggleton, R.A. & Fitzpatrick, R.W. (1988) New data and a revised structural model for ferrihydrite. Clays Clay Miner., 36, 111–124.CrossRefGoogle Scholar
Eibschutz, M. & Lines, M.E. (1982) Observation of second-order quadrupole shift in Mössbauer spectrum of amorphous YIG (yttrium iron garnet). Phys. Rev. B25, 4256–4259.CrossRefGoogle Scholar
Feitknecht, W., Hani, H. & Dvorak, V. (1969) The mechanism of the transformation of δ-FeOOH to α-Fe2O3. Pp. 237–245 in : Reactivity of Solids(Mitchell, J.W., De Vries, R.C., Roberts, R.W. & Cannon, P., editors). Wiley, New York.Google Scholar
Gautschi, W. (1969) Complex error function. Commun. ACM, 12, 635.Google Scholar
Kolbig, K.S. (1972) Certification of algorithm 363 [S15]. Commun. ACM, 15, 465–466.Google Scholar
Klug, H.P. & Alexander, L.E. (1974) X-Ray Diffraction Procedures for Polycrystalline and Amorphous Materials(2nd edn.). Wiley, New York.Google Scholar
Lewis, D.G. & Farmer, V.C. (1986) Infrared absorption of surface hydroxyl groups and lattice vibrations in lepidocrocite (y-FeOOH) and boehmite (y-AlOOH). Clay Miner., 21, 93–100.CrossRefGoogle Scholar
Madsen, M.B., M0rupS., Koch, C.J.W. & Borggaard, O.K. (1985) A study of microcrystals of synthetic feroxyhite (^'-FeOOH). Surface Sci., 156, 328–334.Google Scholar
Madsen, M.B., M0rup, S. & Koch, C.J.W. (1986) Magnetic properties of ferrihydrite. Hyperfine Interact., 27, 329–332.Google Scholar
Meagher, A., Pankhurst, Q.A. & Dickson, D.P.E. (1986) A Mössbauer spectroscopic study of the magnetocrystalline anisotropy in α-FeOOH. Hyperfine Interact., 28, 533–536.Google Scholar
Murad, E. (1988a) Properties and behavior of iron oxides as determined by Mössbauer spectroscopy. Pp. 309-350 in: Iron in Soils and Clay Minerals(Stucki, J.W., Goodman, B.A. & Schwertmann, U., editors). Reidel, Dordrecht.Google Scholar
Murad, E. (1988b) The Mössbauer spectrum of "well"-crystallized ferrihydrite.J. Magn. Magn. Mater., 74, 153–157.CrossRefGoogle Scholar
Murad, E. (1990) Application of 57Fe Mössbauer spectroscopy to problems in day mineralogy and soil science: possibilities and limitations. Pp. 127-157 in: Advances in Soil Science,vol. 12 (Stewart, B.A., editor). Springer- Verlag, New York.Google Scholar
Murad, E., Bowen, L.H., Long, G J.& Quin, T.G. (1988) The influence of crystallinity on magnetic ordering in natural ferrihydrites. Clay Miner., 23, 161–173.CrossRefGoogle Scholar
Murad, E. & Johnston, J.H. (1987) Iron oxides and oxyhydroxides. Pp. 507-582 in: Mössbauer Spectroscopy Applied to Inorganic Chemistry,vol. 2 (Long, G J., editor). Plenum Press, New York.Google Scholar
Pankhurst, Q.A. (1991) Anisotropy field measurement in barium ferrite powders by applied field Mössbauer spectroscopy. J. Phys. Condens. Matter 1323–1335.Google Scholar
Pankhurst, Q.A., Johnson, C.E. & Thomas, M.F. (1986) A Mössbauer study of magnetic phase transitions in α-Fe2O3 crystals. J. Phys. C: Solid State Phys., 19, 7081–7098.CrossRefGoogle Scholar
Pankhurst, Q.A. & Pollard, R J. (1990) Mössbauer spectra of antiferromagnetic powders in applied fields. J. Phys. Condens. Matter, 2, 7329–7337.CrossRefGoogle Scholar
Persoons, R.M., Chambaere, D.G. & De Grave, E. (1986) Mössbauer effect study of the magnetic structure in (5-FeOOH. Hyperfine Interact., 28, 647–650.Google Scholar
Pollard, R.J. (1990) The spin canting anomaly in ferrimagnetic powders. J. Phys. Condens. Matter, 2, 983–991.Google Scholar
Pollard, R.J. (1991) Mössbauer spectra of iron oxides and oxyhydroxides at 4°2 K and in applied magnetic fields. Unpublished Internal Report,Dep. of Physics, Monash Univ. (available upon request).Google Scholar
Posener, D.W. (1959) The shape of spectral lines: tables of the Voigt profile. Aust. J. Phys., 12, 184–196.Google Scholar
Vandenberghe, R.E., De Grave, E., Landuydt, C. & Bowen, L.H. (1990) Some aspects concerning the characterization of iron oxides and hydroxides in soils and clays. Hyperfine Interact., 53, 175–196.Google Scholar