Skip to main content Accessibility help
×
Home
Hostname: page-component-cf9d5c678-w9nzq Total loading time: 0.176 Render date: 2021-07-27T00:29:54.167Z Has data issue: true Feature Flags: { "shouldUseShareProductTool": true, "shouldUseHypothesis": true, "isUnsiloEnabled": true, "metricsAbstractViews": false, "figures": true, "newCiteModal": false, "newCitedByModal": true, "newEcommerce": true, "newUsageEvents": true }

Adsorption of Water by Montmorillonite—Poly(Ethylene Glycol) Adsorption Products

Published online by Cambridge University Press:  09 July 2018

R. L. Parfitt
Affiliation:
Department of Agricultural Biochemistry and Soil Science, Waite Agricultural Research Institute, University of Adelaide
D. J. Greenland
Affiliation:
Department of Agricultural Biochemistry and Soil Science, Waite Agricultural Research Institute, University of Adelaide

Abstract

Water adsorption by interlamellar complexes of poly(ethylene glycols) and montmorillonite has been determined using a silica spiral spring, and supplementary data obtained by X-ray and infrared techniques. The adsorbed water enters the interlamellar region, where it is associated with the exchangeable cation. The lattice swells to accommodate the intercalated water. Only weak hydrogen bonds are formed between the surface of the clay and the adsorbed water or between adsorbed PEG molecules and adsorbed water. The presence of PEG did not prevent extensive swelling of sodium montmorillonite.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1970

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Barshad, I. (1952) Proc. Soil Sci. Soc. Am. 16, 176.CrossRefGoogle Scholar
Bradley, W.F., Grim, R.E. & Clark, G.L. (1937) Z. Kristallogr. Miner. 97, 216.Google Scholar
Dowdy, R.H. & Mortland, M.M. 0967) Clays Clay Miner. 15, 259.CrossRefGoogle Scholar
Farmer, V.C., Russell, J.D. & Ahlrichs, J.L. (1968) Trans 9th Int. Congr. Soil Sci. Adelaide, 3, I01.Google Scholar
Garrett, W.G. & Walker, G.F. (1962) Clays Clay Miner. 9, 557.CrossRefGoogle Scholar
Grandquist, W.T. & Kennedy, J.V. (1967) Clays Clay Miner. 15, 103.CrossRefGoogle Scholar
Greenland, D.J., Laby, R.H. & Quirk, J.P. (1962) Trans. Faraday Soc. 58, 829.CrossRefGoogle Scholar
Greenland, D.J., Laby, R.H. & Quirk, J.P. (1965) Trans. Faraday Soc. 61, 2024.CrossRefGoogle Scholar
Horeman, R.W. & Brindley, G.W. (1960) Geochim. Cosmochim. Acta, 20, 15.Google Scholar
Kodama, H. & Schnitzer, M. (1968) Soil Sci. 106, 73.CrossRefGoogle Scholar
Matsuura, H. & Miyazawa, T. (1967) Spectrochim. Acta, 23A, 2433.CrossRefGoogle Scholar
Mooney, R.W., Keenan, A.G. & Wood, L.A. (1952) J. Am. Chem. Soc. 74, 1367.CrossRefGoogle Scholar
Norrish, K. (1954) Disc. Faraday Soe. 18, 120.CrossRefGoogle Scholar
Parfitt, R.L. & Greenland, D.J. (1970) Clay Miner. 8, 305.CrossRefGoogle Scholar
Parfritt, R.L. & Mortlano, M.M. (1968) Proe. Soil Sci. Soe. Am. 32, 355.CrossRefGoogle Scholar
Russell, J.D. & Farmer, V.C. (1964) Clay Miner. Bull. 5, 443.CrossRefGoogle Scholar
Scltotr, H. (1964) KoIloid Z. 199, 158.Google Scholar
Yariv, SH., Russell, J.D. & Farmer, V.C. (1966) Israel d. Chem. 4, 201.CrossRefGoogle Scholar
28
Cited by

Send article to Kindle

To send this article to your Kindle, first ensure no-reply@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about sending to your Kindle. Find out more about sending to your Kindle.

Note you can select to send to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be sent to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Adsorption of Water by Montmorillonite—Poly(Ethylene Glycol) Adsorption Products
Available formats
×

Send article to Dropbox

To send this article to your Dropbox account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Dropbox.

Adsorption of Water by Montmorillonite—Poly(Ethylene Glycol) Adsorption Products
Available formats
×

Send article to Google Drive

To send this article to your Google Drive account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Google Drive.

Adsorption of Water by Montmorillonite—Poly(Ethylene Glycol) Adsorption Products
Available formats
×
×

Reply to: Submit a response

Please enter your response.

Your details

Please enter a valid email address.

Conflicting interests

Do you have any conflicting interests? *