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Chapter 1 - Solutions and Solution Properties

Published online by Cambridge University Press:  14 June 2019

By
Jennifer Moffitt Schall  and
Allan S. Myerson
Edited by
Allan S. Myerson ,
Deniz Erdemir  and
Alfred Y. Lee
Allan S. Myerson
Affiliation:
Massachusetts Institute of Technology
Deniz Erdemir
Affiliation:
Bristol-Myers Squibb, USA
Alfred Y. Lee
Affiliation:
Merck & Co., Inc
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Summary

Crystallization is a separation and purification technique employed to produce a wide variety of materials. Crystallization may be defined as a phase change in which a crystalline product is obtained from a solution. A solution is a mixture of two or more species that form a homogeneous single phase. Solutions are normally thought of in terms of liquids, but solutions may include solids and even gases. Typically, the term solution has come to mean a liquid solution consisting of a solvent, which is a liquid, and a solute, which is a solid, at the conditions of interest. The term melt is used to describe a material that is solid at normal conditions and is heated until it becomes a molten liquid. Melts may be pure materials, such as molten silicon used for wafers in semiconductors, or they may be mixtures of materials. In that sense, a homogeneous melt with more than one component is also a solution, but it is normally referred to as a melt. A solution can also be gaseous; an example of this is a solution of a solid in a supercritical fluid.

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Chapter
Information
Handbook of Industrial Crystallization , pp. 1 - 31
Publisher: Cambridge University Press
Print publication year: 2019

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References

Bird, R. B., Stewart, W. E., and Lightfoot, E. N. Transport Phenomena (1st edn). Wiley, New York, 1960.Google Scholar
Bromley, L. A. J. Chem. Thermodyn. 1972; 4:669–73.CrossRefGoogle Scholar
Bromley, L. A. AlChE J. 1973; 19(2):313–20.Google Scholar
Bromley, L. A., Singh, D., Ray, P., Sridhar, S., and Read, S. AIChE J. 1974; 20(2):326–35.CrossRefGoogle Scholar
Chang, Y. C. Concentration Dependent Diffusion of Solid-Solute, Liquid-Solvent Systems in the Supersautrated Region, Georgia Institute of Technology, Atlanta, GA, 1985.Google Scholar
Cole, L. S. On-Line Measurement of Crystal Size Distribution in a Mixed Suspension Mixed Product Removal Crystallizer, Master’s thesis, Polytechnic University, 1991.Google Scholar
Felder, R. M., and Rousseau, R. W. Elementary Principles of Chemical Processes (2nd edn). Wiley, New York, NY, 1986.Google Scholar
Frank, T. C., Downey, J. R., and Gupta, S. K. Chem. Eng. Prog. 1999; 95(12):41–61.Google Scholar
Fredenslund, A., Gmehling, J., Michelsen, M. L., Rasmussen, P., and Prausnitz, J. M. Ind. Eng. Chem., Process Des. Dev. 1977; 16(4):450–62.Google Scholar
Gmehling, J. J. Chem. Thermodyn. 2009; 41:731–47.Google Scholar
Gmehling, J., Constantinescu, D., and Schmid, B. Annu. Rev. Chem. Biomol. Eng. 2015; 6:267–92.CrossRefGoogle Scholar
Gordon, L. J., and Scott, R. L. J. Am. Chem. Soc. 1952; 74:4138–40.Google Scholar
Gordon, P. Principles of Phase Diagrams in Materials Systems; McGraw-Hill, New York, NY, 1968.Google Scholar
Green, D. W., and Perry, R. H. Perry’s Chemical Engineers’ Handbook (8th edn). McGraw-Hill, New York, NY, 2007.Google Scholar
Guggenheim, E. A. Thermodynamics: An Advanced Treatment for Chemists and Physicists (8th edn). North Holland, Amsterdam, 1986.Google Scholar
Hansen, C. M. Hansen Solubility Parameters: A User’s Handbook (2nd edn). CRC Press, Boca Raton, FL, 2007.Google Scholar
Hartman, P. Crystal Growth: An Introduction (1st edn). North Holland, Amsterdam, 1973.Google Scholar
Jaworski, Z., Czernuszewicz, M., and Gralla, Ł. Chem. Process Eng. 2011; 32(2):135–54.Google Scholar
Kim, S., and Myerson, A. S. Ind. Eng. Chem. Res. 1996; 35:1078–84.Google Scholar
Kojima, K., and Tochigi, K. Prediction of Vapor-Liquid Equilibria by the ASOG Method. Elsevier Scientific, New York, NY, 1979.Google Scholar
Lin, Y., ten Kate, A., Mooijer, M., et al. AIChE J. 2010; 56(5):1334–51.Google Scholar
Linke, W. F., and Seidell, A. Solubilities, Inorganic and Metal-Organic Compounds: A Compilation of Solubility Data from the Periodical Literature (4th edn). American Chemical Society, Washington, DC, 1965.Google Scholar
Ma, H., Qu, Y., Zhou, Z., Wang, S., and Li, L. J. Chem. Eng. Data 2012; 57:2121–27.Google Scholar
Mullin, J. W. Crystallisation (2nd edn). Butterworths, London, 1972.Google Scholar
Myerson, A. S., Decker, S. E., and Welplng, F. Ind. Eng. Chem. Process Des. Dev. 1986; 25:925–29.CrossRefGoogle Scholar
Myerson, A. S., Lo, P. Y., Kim, Y. C., and Ginde, R. M. In Proceedings of the 11th Symposium on Industrial Crystallization. European Federation of Chemical Engineers, Garmisch, Germany, 1990, p. 847.Google Scholar
Nývlt, J., Söhnel, O., Matachová, M., and Broul, M. The Kinetics of Industrial Crystallization. Elsevier, Amsterdam, 1985.Google Scholar
Peng, Y., Zhu, Z., Braatz, R. D., and Myerson, A. S. Ind. Eng. Chem. Res. 2015; 54:7914–24.Google Scholar
Prausnitz, J. M., Lichenthaler, R. N., and Gomes de Azvedo, E. Molecular Thermodynamics of Fluid-Phase Equilibria (2nd edn). Prentice-Hall, Englewood Cliffs, NJ, 1986.Google Scholar
Reid, R. C., Prausnitz, J. M., and Poling, B. E. The Properties of Gases and Liquids (4th edn). McGraw-Hill, New York, NY, 1987.Google Scholar
Robinson, R. A., and Stokes, R. H. Electrolyte Solutions (2nd edn). Butterworths, London, 1970.Google Scholar
Rosenberger, F. E. Fundamentals of Crystal Growth (Springer Series in Solid-State Sciences vol. 5, 2nd edn). Springer-Verlag, New York, NY, 1981.Google Scholar
Saska, M. Crystallization of Terephthalic Acid. Georgia Institute of Technology, Atlanta, GA, 1994.Google Scholar
Sherman, P. Industrial Rheology: With Particular Reference to Foods, Pharmaceuticals, and Cosmetics. Academic Press, New York, NY, 1970.Google Scholar
Skyner, R. E., McDonagh, J. L., Groom, C. R., van Mourik, T., and Mitchell, J. B. O. Phys. Chem. Chem. Phys. 2015; 17:6174–91.Google Scholar
Smith, J. M., Van Ness, H. C., and Abbott, M. M. Introduction to Chemical Engineering Thermodynamics (7th edn). McGraw-Hill, New York, NY, 2005.Google Scholar
Valavi, M., Svärd, M., and Rasmuson, A. C. Cryst. Growth Des. 2016; 16:6951–6960.CrossRefGoogle Scholar
Walas, S. M. Phase Equilibria in Chemical Engineering; Butterworth-Heinemann, Stoneham, MA, 1985.Google Scholar
Weast, R. C. CRC Handbook of Chemistry and Physics (56th edn). CRC Press, Cleveland, OH, 1975.Google Scholar
Williams, N., and Amidon, G. J. Pharm. Sci. 1984; 73(1):14–18.Google Scholar
Williams, N., and Amidon, G. J. Pharm. Sci. 1984; 73(1):9–13.CrossRefGoogle Scholar
Williams, N., and Amidon, G. Pharm. Res. 1988; 5(3):193–95.CrossRefGoogle Scholar
Williams, N., and Amidon, G. J. Pharm. Sci. 1984; 73(1):18–23.Google Scholar
Yi, Y., Hatziavramidis, D., Myerson, A. S., et al. Ind. Eng. Chem. Res. 2005; 44:5427–33.Google Scholar
Zemaitis, J. F. J., Clark, D. M., Rafal, M., and Scrivner, N. C. Handbook of Aqueous Electrolyte Thermodynamics: Theory & Application. Wiley, New York, NY, 1986.Google Scholar

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