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XII.—On an Electrically Controlled Thermostat and other Apparatus for the Accurate Determination of the Electrolytic Conductivity of Highly Conducting Solutions

Published online by Cambridge University Press:  15 September 2014

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Extract

Kohlrausch and others have recently published investigations which show that the electrolytic conductivity of dilute solutions of inorganic salts may be determined with a maximum error of two or three in ten thousand.

Hitherto such accuracy has not been attained with highly conducting concentrated solutions. With such solutions different difficulties are encountered from those met with in dilute solutions. Temperature variations originating outside the cell, the heating effect of the current within the cell, and polarisation are sources of error which are particularly troublesome in the case of highly conducting solutions.

Type
Proceedings
Copyright
Copyright © Royal Society of Edinburgh 1910

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References

page 254 note * It is interesting to note that so long ago as 1865 Kohlrausch described an apparatus for controlling temperature electrically. At that time the use of the electric current for technical purposes was quite undeveloped, and the appliances now so familiar were unknown. Poggendorf Annalen, Bd. cxxv. p. 126.

page 260 note * Wissenschaftliche Abhandlungen der Physikalisch-Technischen Reichs Anstalt, Band iii. (1900), p. 165.