Molecular line intensity calculations are not a straightforward task. We present a description of the basics for including molecular lines in synthetic spectra and of the input data needed. We aim both at describing ways in which molecular lines are computed in the context of photospheres of F–G–K stars, and to present a new online available version of our code for spectrum synthesis of cool stars. We apply calculations to molecular bands in the ultraviolet, visible, and near-infrared main features, and comparisons with spectra of reference stars are shown. We provide user-friendly tools for the free use of the code Pfant. The code is available at http://trevisanj.github.io/PFANT.

This year 2018 has great historical and current significance for stellar spectral classification. Two hundred years ago in Reggio Emilia, Italy, was born Angelo Secchi, a pioneer of observing and classifying the spectra of stars. At the beginning of the IAU, almost a hundred years ago, one of its original Commissions was entitled the Spectral Classification of Stars, from which was generated Commission 45, Spectral Classification and Multi-band Colour Indices. And seventy-five years ago, was published the system-changing MKK, An Atlas of Stellar Spectra. Through this necessarily brief, historical view we shall recall how spectral classification, supported internationally by the IAU, continually updated its techniques, while remaining anchored to standards. This has ensured that the MK classification process stays very relevant to the initial characterizing of stars in the 21st century era of large spectral surveys.

Getting a better understanding of the evolution and nucleosynthetic yields of the most metal-poor stars (Z ≲ 10−5) is critical because they are part of the big picture of the history of the primitive universe. Yet many of the remaining unknowns of stellar evolution lie in the birth, life, and death of these objects. We review stellar evolution of intermediate-mass Z ≤ 10−5 models existing in the literature, with a particular focus on the problem of their final fates. We emphasise the importance of the mixing episodes between the stellar envelope and the nuclearly processed core, which occur after stars exhaust their central He (second dredge-up and dredge-out episodes). The depth and efficiency of these episodes are critical to determine the mass limits for the formation of electron-capture SNe. Our knowledge of these phenomena is not complete because they are strongly affected by the choice of input physics. These uncertainties affect stars in all mass and metallicity ranges. However, difficulties in calibration pose additional challenges in the case of the most metal-poor stars. We also consider the alternative SN I1/2 channel to form SNe out of the most metal-poor intermediate-mass objects. In this case, it is critical to understand the thermally pulsing Asymptotic Giant Branch evolution until the late stages. Efficient second dredge-up and, later, third dredge-up episodes could be able to pollute stellar envelopes enough for the stars to undergo thermal pulses in a way very similar to that of higher initial Z objects. Inefficient second and/or third dredge-up may leave an almost pristine envelope, unable to sustain strong stellar winds. This may allow the H-exhausted core to grow to the Chandrasekhar mass before the envelope is completely lost, and thus let the star explode as an SN I1/2. After reviewing the information available on these two possible channels for the formation of SNe, we discuss existing nucleosynthetic yields of stars of metallicity Z ≤ 10−5 and present an example of nucleosynthetic calculations for a thermally pulsing Super-Asymptotic Giant Branch star of Z = 10−5. We compare theoretical predictions with observations of the lowest [Fe/H] objects detected. The review closes by discussing current open questions as well as possible fruitful avenues for future research.

We study how the void environment affects the chemical evolution of galaxies by comparing the metallicity of dwarf galaxies in voids with dwarf galaxies in denser regions. Using spectroscopic observations from SDSS DR7, we estimate oxygen and nitrogen abundances of 889 void dwarf galaxies and 672 dwarf galaxies in denser regions. A substitute for the [OII] λ3727 doublet is developed, permitting oxygen abundance estimates of SDSS dwarf galaxies at all redshifts with the direct method. We find that void dwarf galaxies have about the same oxygen abundances and slightly lower N/O ratios than dwarf galaxies in denser environments. The lower N/O ratios seen in void dwarf galaxies may indicate both delayed star formation and a dependence of cosmic downsizing on the large-scale environment. Similar oxygen abundances in the two dwarf galaxy populations might be evidence of larger ratios of dark matter halo mass to stellar mass in voids.

The outer stellar halo is home to a number of substructures that are remnants of former interactions of the Galaxy with its dwarf satellites. Triangulum-Andromeda (TriAnd) is one of these halo substructures, found as a debris cloud by Rocha-Pinto et al., (2004) using 2MASS M giants. Would be these structures related to dwarf galaxies or to the galactic disk? To uncover the nature of these stars we performed a high-resolution spectroscopic study (R = 40,000) along with a kinematic analysis using Gaia data. We determined the atmospheric parameters and chemical abundances of Ca and Mg for the 13 TriAnd candidate stars along with their respective orbits. Our results indicate that the TriAnd stars analyzed have a galactic nature but that these stars are not from the local thin disk.

The lowest metallicity massive stars in the Local Universe with $Z\sim \left( {{Z}_{\odot }}/50-{{Z}_{\odot }}/30 \right)$ are the crucial objects to test the validity of assumptions in the modern models of very low-metallicity massive star evolution. These models, in turn, have major implications for our understanding of galaxy and massive star formation in the early epochs. DDO68-V1 in a void galaxy DDO68 is a unique extremely metal-poor massive star. Discovered by us in 2008 in the HII region Knot3 with $Z={{Z}_{\odot }}/35\,\left[ 12+\log \left( \text{O/H} \right)\sim 7.14 \right]$ , DDO68-V1 was identified as an LBV star. We present here the LBV lightcurve in V band, combining own new data and the last archive and/or literature data on the light of Knot3 over the 30 years. We find that during the years 2008-2011 the LBV have experienced a very rare event of ‘giant eruption’ with V-band amplitude of 4.5 mag ( $V\sim {{24.5}^{m}}-{{20}^{m}}$ ).

Physical conditions and chemical abundances of two H II regions and a planetary nebula in the dIrr galaxy Leo A are presented. These determinations were performed using the direct method (Te measured) and the ONS method. We also constructed photoionization models for the three nebulae to determine the abundances and to analyse the ionizing stars. The O abundance was determined to be 12+log(O/H) = 7.4±0.2 in all cases.

Absorption line spectroscopy of foreground gas in the spectra of background quasars has revealed some clear cases where neutral gas is present and associated with dwarf galaxies. Spectroscopy of Lyα and low-ionization metal lines can be combined to derive neutral gas phase metallicities. The damped Lyα absorbers (DLAs) in quasar spectra are the clearest cases of absorption by predominantly neutral gas regions. Here we present some results on neutral gas phase metallicities for cases where the DLA is clearly associated with a dwarf galaxy. We find that the neutral gas phase metallicities in these systems are similar to those in other DLAs. We argue that there may be many unrecognized cases where a DLA is actually associated with a dwarf galaxy even though there is a luminous galaxy within 100 kpc of the quasar sightline.

Massive stars are the drivers of the chemical evolution of dwarf galaxies. We review here the basics of massive star evolution and the specificities of stellar evolution in low-Z environment. We discuss nucleosynthetic aspects and what observations could constrain our view on the first generations of stars.

Dwarf galaxies make ideal laboratories to test galaxy evolution paradigms and cosmological models. Detailed studies of dwarfs across the spectrum allow us to gauge the efficacy of astrophysical processes at play in the lowest mass halos such as gas accretion, feedback, turbulence and chemical enrichment. Future observational studies will deliver unprecedented insights on the orbits of dwarf companions around the Milky Way, on their star formation histories and on the 3-D internal motions of their stars. Over large volumes, we will assess the impact of local environment on baryon cycling and star formation laws, leading to a full picture of the evolution of dwarfs across cosmic time. In combination, future discoveries promise to trace the history of assembly within the Local Group and beyond, probe how stars form under pristine conditions, and test models of structure formation on small scales.

Red Supergiant Stars (RSGs) are important probes of stellar and chemical evolution in star-forming environments. They represent the brightest near-IR stellar components of external galaxies and probe the most recent stellar population to provide robust, independent abundance estimates. The Local Group dwarf irregular galaxy, NGC6822, is a reasonably isolated galaxy with an interesting structure and turbulent history. Using RSGs as chemical abundance probes, we estimate metallicities in the central region of NGC6822, finding a suggestion of a metallicity gradient (in broad agreement with nebular tracers), however, this requires further study for confirmation. With intermediate resolution Multi-object spectroscopy (from e.g. KMOS, EMIR, MOSFIRE) combined with state-of-the-art stellar model atmospheres, we demonstrate how RSGs can be used to estimate stellar abundances in external galaxies. In this context, we compare stellar and nebular abundance tracers in NGC 6822 and by combining stellar and nebular tracers we estimate an abundance gradient of −0.18 ± 0.05 dex/kpc.

Abundances of heavy elements in dwarf galaxies reflect their early evolutionary histories. Recent astronomical observations have shown that there are star-to-star scatters in the abundances of r-process elements and the decreasing trend of Zn toward higher metallicity in extremely metal-poor stars. However, the enrichment of heavy elements is not well understood. Here we performed a series of high-resolution N-body/smoothed particle hydrodynamics simulations of dwarf galaxies. We find that neutron star mergers can explain ratios of r-process elements to iron in dwarf galaxies due to their suppressed star formation rates. We also find that stars with [Zn/Fe] ≳ 0.5 reflect the ejecta from electron-capture supernovae. Inhomogeneity of the metals in the interstellar medium causes the scatters of heavy elements. We estimate that the timescale of metal mixing is ≲ 40 Myr using heavy element abundances in metal-poor stars.

We analyse the chemical abundances of stars in the local group dwarf galaxies using the SAGA database. The inspection of the relationship between Eu and Ba abundances confirms an anomalously Ba-rich population in Fornax, which indicates a pre-enrichment of interstellar gas with r-process elements.

We have constructed a chemical evolution model in order to reproduce the both metallicity distribution functions (MDFs) of red giant branch stars (RGBs) and RR Lyrae stars (RRLs) of a dwarf galaxy, simultaneously. The detailed chemical abundances of RGBs of the Local Group dwarf galaxies have been measured by spectroscopic observations. Moreover, the metallicity of RRLs of a dwarf galaxy are estimated by using the theoretical period-luminosity relations in the previous study and it is found that the mean metallicity of RRLs are lower than that of RGBs. In order to investigate the MDFs of RGBs and RRLs, we combine our chemical evolution model with the stellar evolutionally isochrones and calculate the metallicity of RGBs and RRLs, respectively. As a result, our chemical evolution model reproduces the peak metallicity of both MDFs of RGBs and RRLs of Sculptor and Fornax dwarf spheroidal galaxies (dSphs), simultaneously. Therefore, it is found that the difference of the mean metallicity between RGBs and RRLs are caused by the effects of stellar evolution. Moreover, by using the theoretical period-luminosity-metallicity relation of the RRLs, our chemical evolution model determines that the distance modulus of Sculptor and Fornax dSphs are 19.68 ± 0.09 and ${20.81^{+0.13}_{-0.11}}$ , respectively. However, our model underestimates the number of metal-rich RRLs ([Fe/H] > −1.5) of Fornax dSph. This result suggests that the mass-loss rate of metal-rich RGBs would be larger than that of metal-poor RGBs.

The Local Group contains a great number of dwarf irregulars and spheroidals, for which the spectroscopy of individual stars can be obtained. Thus, the chemical evolution of these galaxies can be traced, with the only need of finding populations spanning a large age range and such that we can accurately derive the composition. Planetary nebulae (PNe) are old- and intermediate-age star remnants and their chemical abundances can be obtained up to 3-4 Mpc. H ii regions, which are brighter and much easily detected, represent galaxies young content. PNe and H ii regions share similar spectroscopic features and are analysed in the same way. Both are among the best tracers of the chemical evolution allowing to draw the chemical time line of nearby galaxies. The focus in this review are the PN and H ii region populations as constraints to the chemical evolution models and the mass-metallicity relation of the local universe.

We present the NLTE abundances of 10 chemical species in 65 very metal-poor stars in eight dSphs and the Milky Way halo. The classical dSphs Sculptor, Ursa Minor, Sextans, and Fornax reveal a similar plateau at [α/Fe] = 0.3 for each of Mg, Ca, and Ti, similarly to the MW halo. We provide the evidence for a decline in α/Fe in the Boötes I UFD, that is probably due to the ejecta of SNeIa. The dichotomy in the [Sr/Ba] versus [Ba/H] diagram is observed in the classical dSphs, similarly to the MW halo, calling for two different nucleosynthesis channels for Sr. The Boötes I and UMa II UFDs reveal very similar ratios of [Sr/Mg] = −1.3 and [Ba/Mg] = –1. The stars in the Coma Berenices and Leo IV UFDs are even poorer in Sr and Ba. The subsolar Sr/Ba ratios of Boötes I and UMa II indicate a common r-process origin of their n-capture elements.

We present the status of an ongoing project to map the detailed chemical abundances of stars across the main body of the Sagittarius dwarf Spheroidal galaxy (Sgr dSph). The Sgr dSph is the closest known dwarf galaxy, and is being tidally destroyed by its interaction with the Milky Way (MW), leaving behind a massive stellar stream. Sgr dSph is a chemically outstanding object, with peculiar abundance ratios, clear center-outskirts abundance gradients, and spanning more than 3 orders of magnitude in metallicity. We present here detailed abundances from UVES@VLT spectra for more than 50 giants across 8 fields along the major and minor axes of Sgr dSph, and 5 more outside the galaxy main body, but possibly associated to its stellar stream.

Surface abundance observations of halo stars hint at the occurrence of r-process nucleosynthesis at low metallicity ([Fe/H] < -3), possibly within the first 108 yr after the formation of the first stars. Possible loci of early-Universe r-process nucleosynthesis are the ejecta of either black hole–neutron star or neutron star–neutron star binary mergers. Here, we study the effect of the inclination–eccentricity oscillations raised by a tertiary (e.g. a star) on the coalescence time-scale of the inner compact object binaries. Our results are highly sensitive to the assumed initial distribution of the inner binary semi-major axes. Distributions with mostly wide compact object binaries are most affected by the third object, resulting in a strong increase (by more than a factor of 2) in the fraction of fast coalescences. If instead the distribution preferentially populates very close compact binaries, general relativistic precession prevents the third body from increasing the inner binary eccentricity to very high values. In this last case, the fraction of coalescing binaries is increased much less by tertiaries, but the fraction of binaries that would coalesce within 108 yr even without a third object is already high. Our results provide additional support to the compact-binary merger scenario for r-process nucleosynthesis.

Chandra Low Energy Transmission Grating Spectrograph observations of the pre-cataclysmic binary V471 Tau have been used to estimate the C/N abundance ratio of the K dwarf component for the first time. While the white dwarf component dominates the spectrum longward of 50 Å, at shorter wavelengths the observed X-ray emission is entirely due to coronal emission from the K dwarf. The H-like 2p 2Р3/2, 1/2 → 1s 2S1/2 resonance lines of С and N yield an estimate of their logarithmic abundance ratio relative to the Sun of [C/N]= –0.38 ± 0.15—half of the currently accepted solar value. We interpret this result as the first clear observational evidence for the presumed common envelope phase of this system, during which the surface of the K dwarf was contaminated by CN-cycle processed material dredged up into the red giant envelope

The planetary nebula PB 8 around a [WN/WC]-hybrid central star is one of planetary nebulae with moderate abundance discrepancy factors (ADFs ~ 2–3), which could be an indication of a tiny fraction of metal-rich inclusions embedded in the nebula (bi-abundance). In this work, we have constructed photoionisation models to reproduce the optical and infrared observations of the planetary nebula PB 8 using a non-LTE stellar model atmosphere ionising source. A chemically homogeneous model initially used cannot predict the optical recombination lines. However, a bi-abundance model provides a better fit to most of the observed optical recombination lines from N and O ions. The metal-rich inclusions in the bi-abundance model occupy 5.6% of the total volume of the nebula, and are roughly 1.7 times cooler and denser than the mean values of the surrounding nebula. The N/H and O/H abundance ratios in the metal-rich inclusions are ~1.0 and 1.7 dex larger than the diffuse warm nebula, respectively. To reproduce the Spitzer spectral energy distribution of PB 8, dust grains with a dust-to-gas ratio of 0.01 (by mass) were also included. It is found that the presence of metal-rich inclusions can explain the heavy element optical recombination lines, while a dual-dust chemistry with different grain species and discrete grain sizes likely produces the infrared continuum of this planetary nebula. This study demonstrates that the bi-abundance hypothesis, which was examined in a few planetary nebulae with large abundance discrepancies (ADFs > 10), could also be applied to those typical planetary nebulae with moderate abundance discrepancies.