An all-alkoxide sol-gel process utilizing methoxyethoxide complexes in 2-methoxyethanol was used to prepare epitaxial films of SrBi2Nb2O9, SrBi2Ta2O9, BaBi2Nb2O9, BaBi2Ta2O9, and Bi4Ti3O12 on  oriented SrTiO3 single crystals. Films were prepared by spin coating strontium titanate substrates with partially hydrolyzed alkoxide solutions and firing in air at 850 °C for 20 minutes. Out-of-plane orientation was confirmed by θ-2θ scans which showed only [002ℓ] reflections. In-plane orientation was determined by pole figures and phi-scans about the  plane in the case of the (Sr,Ba)Bi2(Nb,Ta)2O9 complexes and the  plane in the case of Bi4Ti3O12. Lattice constants and full-width at half-maximum (fwhm) values for both in-plane and out-of-plane reflections are reported.