As a common mineral phase on Earth and Martian regolith, natural rutile was reported as a potential candidate for use as a Fenton catalyst in this study. The influences of Fe and V in various chemical states on the generation of reactive oxygen species (ROSs) and the catalytic activity of rutile were examined. A series of rutile samples with various surface and bulk states of Fe and V were obtained initially by hydrogen annealing of natural rutile at ~773–1173 K. X-ray diffraction, electron paramagnetic resonance spectra, and X-ray photoelectron spectroscopy demonstrated that the atomic fractions of Fe(III) and V(V) decreased sharply with increasing temperature, along with the accumulation of surface Fe(II) and bulk V(III). All as-prepared materials showed enhanced Fenton degradation efficiency on methylene blue (MB) compared with P25-TiO2, and the treated samples exhibited up to 3.5-fold improvement in efficiency at pH 3 compared to the untreated sample. The improved efficiency was attributed mainly to Fenton catalysis involving Fe(II) and V(III). The dissolved Fe2+ played a crucial role in the homogeneous Fenton reaction, while the bound V(III) favored adsorption primarily and may have facilitated heterogeneous Fenton reaction and the regeneration of Fe2+. The pH regulated the reaction mechanism among homogeneous (pH = 3) and heterogeneous (pH = 3.7) Fenton catalysis and physical adsorption (pH = 5, 6). The aim of the present study was to improve the understanding of the potential role of natural rutile with advanced oxidation functions in Earth systems and even on Mars, which also provide an inspiration for screening natural rutile and any other similar, Earth-abundant, low-cost minerals for environmental application.

In January 2016, static GPS measurements were carried out in a 30 × 30 km2 area centered around Kunlun station at Dome Argus (Dome A), East Antarctica, to acquire high-precision 3-D geodetic coordinates at 49 sites. By comparing the coordinates with previous GPS measurements in 2008 and 2013 at the same sites, we constructed a detailed and long-term record of the ice-surface velocity field, 2008–2016, around Dome A. During this time span, the estimated ice-surface velocity ranges from 0.8 ± 0.3 to 28.7 ± 1.6 cm a−1, with a mean of 10.4 ± 0.3 cm a−1. From 2013 to 2016, the surface elevation of most Dome A areas exhibits a rising trend, and the maximum increase of snow surface elevation is 84.8 cm. The mean snow surface elevation change rate at Dome A is estimated to be 6.6 ± 0.7 cm a−1. The difference of 1.0 cm a−1 between the snow surface change rate derived from GPS and pole-height change rate from surface mass balance is suspected to be a result of a combination of firn densification and basal melt under Dome A.

Using repeat GPS measurements during 2005–16, we calculated and updated two-dimensional high-resolution decadal ice surface velocity estimates along the traverse route from Zhongshan Station to and around Dome Argus, East Antarctica. Along the 71 sites of the transect, the magnitudes of ice velocity increased from near 0 in Dome Argus to 1, 10 and ~100 m a−1 at the sites DT416, DT333 and LT980, respectively. The comparison between GPS and interferometric synthetic aperture radar (InSAR) derived results agree well when the magnitude of the ice surface velocities is faster than 5 m a−1, and disagree for slower flow velocities. A scale value 1.15 and 0.12 can be applied to InSAR derived results over this region with ice surface velocity larger and <5 m a−1, respectively. We attributed the cause of the discrepancy to the insensitivity of InSAR to the magnitude of low ice surface velocities, thus confirming the importance of GPS fieldwork-based ground truth high-resolution ice velocity estimates to constrain ice-sheet dynamics.

Dome A, the highest point on the Antarctic ice sheet at just over 4000 ma.s.l., is located near the centre of East Antarctica. Chinese National Antarctic Research Expeditions have studied ice-sheet dynamics and mass balance along a traverse route from Zhongshan station to Dome A during the austral summers from 1996/97 to 2004/05. Nineteen GPS sites were occupied on at least two occasions at approximately 50 km intervals. The purpose of the surveys was to provide accurate ice-dynamics data. A dual-frequency GPS receiver was used and each site was occupied for 1–12 hours. GPS data were processed using GAMIT/GLOBK software, and horizontal accuracies were within 0.1 m. Repeat GPS measurements provided ice velocities. The horizontal surface ice velocities increase from the summit of the ice sheet to the coast. In the Dome A area, the velocities are <10ma–1; in the plateau area, velocities range from 8 to 24 ma–1 and reach about 98.2 ma–1 at a site (LT980) near the coast. The flow directions are roughly perpendicular to the ice-sheet surface elevation contours, primarily toward the Lambert Glacier basin.

We present a study of seasonal and interannual ice velocity changes at Polar Record Glacier, East Antarctica, using ERS-1/2, Envisat and PALSAR data with D-InSAR and intensity tracking. Ice flow showed seasonal variations at the front of the glacier tongue. Velocities in winter were 19% less than velocities during summer. No significant interannual changes were detected. Ice velocities in the grounding zone and grounded glacier did not show clear seasonal or interannual changes. The distribution of the seasonal variations suggests that the cause for the changes should be localized. Possible causes are seasonal sea-ice changes and iceberg blocking. Satellite images show that the sea ice surrounding Polar Record Glacier undergoes seasonal changes. Frozen sea ice in winter slowed the huge iceberg, and provided increased resistance to the glacier flow. The interaction between the glacier tongue, iceberg and sea ice significantly influences their flow pattern.

Knowledge of the surface topography, velocity field and strain field at an ice-core site is critical to the accurate interpretation of ice-core records. At Dome Argus (Dome A), where a Chinese deep ice-core drilling project is being carried out, we have produced an accurate surface digital elevation model from GPS measurements in January 2013 at 47 sites. We identify two peaks at Dome A, with the northern peak ~7 cm higher than the southern peak. Repeat GPS measurements at 12 sites in 2008 and 2013 provide a surface velocity field around the dome. The surface velocity ranges from 3.1±2.6 to 29.4±1.2 cm a–1, with a mean of 11.1 ~2.4 cm a–1. The surface flow directions are near perpendicular to the surface elevation contours. Velocities from GPS are lower than derived from satellite radar interferometry (InSAR). From GPS velocities, the accuracy of velocity from the existing InSAR velocity field is determined, resulting in a standard deviation of 0.570 m a–1 in speed and 117.5º in direction. This result is consistent with the reported accuracy of InSAR, showing the value of in situ GPS measurements for assessing and correcting remote-sensing results. A surface strain field for the drilling site over Dome A is calculated from 24 strain triangles, showing north–south extension, east– west compression and vertical layer thinning.

This study explores an iterative method for simultaneously estimating the present-day glacial isostatic adjustment (GIA), ice mass change and elastic vertical crustal deformation of the Antarctic ice sheet (AIS) for the period October 2003–October 2009. The estimations are derived by combining mass measurements of the GRACE mission and surface height observations of the ICESat mission under the constraint of GPS vertical crustal deformation rates in the spatial domain. The influence of active subglacial lakes on GIA estimates are mitigated for the first time through additional processing of ICESat data. The inferred GIA shows that the strongest uplift is found in the Amundsen Sea Embayment (ASE) sector and subsidence mostly occurs in Adelie Terre and the East Antarctica inland. The total GIA-related mass change estimates for the entire AIS, West Antarctica Ice Sheet (WAIS), East Antarctica Ice Sheet (EAIS), and Antarctic Peninsula Ice Sheet (APIS) are 43 ± 38, 53 ± 24, −23 ± 29 and 13 ± 6 Gt a−1, respectively. The overall ice mass change of the AIS is −46 ± 43 Gt a−1 (WAIS: −104 ± 25, EAIS: 77 ± 35, APIS: −20 ± 6). The most significant ice mass loss and most significant elastic vertical crustal deformations are concentrated in the ASE and northern Antarctic Peninsula.

The formation of copper-rich precipitates of 17-4 precipitate hardened stainless steel has been investigated, after tempering at 350–570°C for 4 h, by atom probe tomography (APT). The results reveal that the clusters, enriched only with Cu, were observed after tempering at 420°C. Segregation of Ni, Mn to the Cu-rich clusters took place at 450°C, contributing to the increased hardening. After tempering at 510°C, Ni and Mn were rejected from Cu-rich precipitates and accumulated at the precipitate/matrix interfaces. Al and Si were present and uniformly distributed in the precipitates that were <1.5 nm in radius, but Ni, Mn, Al, and Si were enriched at the interfaces of larger precipitates/matrix. The proxigram profiles of the Cu-rich precipitates formed at 570°C indicated that Ni, Mn, Al, and Si segregated to the precipitate/matrix interfaces to form a Ni(Fe, Mn, Si, Al) shell, which significantly reduced the interfacial energy as the precipitates grew into an elongated shape. In addition, the number density of Cu-rich precipitates was increased with the temperature elevated from 350 up to 450°C and subsequently decreased at higher temperatures. Also, the composition of the matrix and the precipitates were measured and found to vary with temperature.