Ultrafast optical responses of the organic films containing squaryliurn dye J-aggregates prepared by simple spincoating method were investigated. Some SQ films exhibited a sharp absorption peak originated from J-aggregates and especially the SQ derivative which has dibutylamino bases at the end of benzene rings forms good J-aggregates in the films without any extra treatment. Time-resolved difference absorption spectra were measured about the SQ44 film. Clear bleached absorption peak and its fast recovery were observed. The decay time was determined to be about 220 fs at 50 MW/cm2 excitation intensity. Sample preparations and all the measurements were performed in air at room temperature.