Small-angle x-ray scattering has been used to investigate the structure of some carbon blacks, some silicas, and an alumina-silica catalyst carrier on length scales from about 5 to 10,000 Å. Equations developed for structural studies of fractal and non-fractal aggregates of primary particles have been employed to analyze the scattering data. From the intensity data, the average diameters of the primary particles could be calculated or estimated. Despite the very different origins of the samples and the fact that the average diameters of the particles varied from about 30 to over 1000 Å, the scattered intensities from the samples had many common features. The data showed that the primary particles had a uniform density and were bounded by smooth or fractal surfaces. On length scales greater than the diameters of the primary particles but not more than a few times larger than the average diameters of the aggregates, some of the aggregates were mass fractals, and others were surface fractals.