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1 results

  • Stereocomplex PMMA Fibers

  • Matija Crne, Jung O Park, Shin-Woong Kang, Satyendra Kumar, Mohan Srinivasarao
  • Journal:
    MRS Online Proceedings Library Archive / Volume 920 / 2006
    Published online by Cambridge University Press:
    01 February 2011, 0920-S03-01
    Print publication:
    2006

  • We have utilized the fact that syndiotactic and isotactic Poly(methyl methacrylate) {PMMA} form a stereocomplex to spin semi-crystalline PMMA fibers. Our goal is to produce oriented semi-crystalline fibers with a high enough melting point to withstand atactic-PMMA processing conditions. We successfully developed stereocomplex PMMA fibers by wet spinning and gel spinning, and characterized their properties by means of differential scanning calorimetry, optical/electron microscopy, mechanical testing and X-ray crystallography. Stereocomplex fibers from gel spinning have highest melting points and polymer chain orientation, hence are the best reinforcing agents. We are currently working on producing self-reinforced composites using these fibers.