1,8-Diazabicyclo[5,4,0]undec-7-ene (DBU) was neutralized by a range of Brønsted acids with a wide variation in the ΔpK
a values of their constituent acids and base. The salts exhibited properties characteristic of an ionic liquid, such as high thermal stability and liquidity near ambient temperature. Analyses of thermal behaviors and temperature dependencies of density, viscosity (η), and ionic conductivity were made to correlate the physicochemical properties with the ΔpK
a value of the obtained protic ionic liquids (PILs). Differential thermal analyses (DTA) revealed that PILs with high ΔpK
a values underwent thermal decomposition resembling their aprotic counterparts; however, PILs with a low ΔpK
a exhibited the evaporation of neutral species progressively generated from the shifting of the equilibrium toward neutral components during the weight loss process. The ionicity of the PILs, determined from Walden plots utilizing density, conductivity, and viscosity data, was found to decrease as temperature increased, and this effect was more pronounced for low ΔpK
a values, possibly because of the shifting of the equilibrium and the imbalance between strong hydrogen bonds and Coulombic interactions. Fragility, estimated from plots of log(η) versus the scaled temperature T
g
/T was found to be lower for PILs than for DBU owing to neutralization. [DBU]-based PILs exhibit intermediate fragility in nature, but this fragility becomes more prominent for PILs with low ΔpK
a values