Impact craters are the dominant landform on Mercury and range from the largest basins to the smallest young craters.  Peak-ring basins are especially prevalent on Mercury, although basins of all forms are far undersaturated, probably the result of the extensive volcanic emplacement of intercrater plains and younger smooth plains between about 4.1 and 3.5 Ga.  This chapter describes the geology of the two largest well-preserved basins, Caloris and Rembrandt, and the three smaller Raditladi, Rachmaninoff, and Mozart basins.  We describe analyses of crater size–frequency distributions and relate them to populations of asteroid impactors (Late Heavy Bombardment in early epochs and the near-Earth asteroid population observable today during most of Mercury’s history), to secondary cratering, and to exogenic and endogenic processes that degrade and erase craters.  Secondary cratering is more important on Mercury than on other solar system bodies and shaped much of the surface on kilometer and smaller scales, compromising our ability to use craters for relative and absolute age-dating of smaller geological units.  Failure to find “vulcanoids” and satellites of Mercury suggests that such bodies played a negligible role in cratering Mercury.  We describe an absolute cratering chronology for Mercury’s geological evolution as well as its uncertainties. 

Mercury is a volcanic world: the planet has experienced a geological history that included partial melting of the interior and the transport of magma to, and eruption onto, the surface. In this chapter, we review Mercury’s volcanic character, first in terms of effusive volcanism (as characterized by lava plains, erosional landforms, and spectral characteristics), next in regard to the planet’s explosive volcanic activity, and then from the perspective of intrusive magmatism. We also visit the planet’s ancient yet spatially expansive intercrater plains and the prospect that they, too, are volcanic. We combine the observations of and inferences for Mercury’s smooth and intercrater plains to propose a model for the planet’s crustal stratigraphy. The extent of our understanding of the petrology of surface materials on Mercury is then discussed, including compositions and lithologies, mineral assemblages, physicochemical properties, and volatile contents. We then describe in broad terms the history of effusive and explosive volcanism on the planet, before addressing the influence that the planet’s lithospheric properties and tectonic evolution have played on volcanism. We finish by listing some major outstanding questions pertaining to the volcanic character of Mercury, and we suggest how those questions might best be addressed.