Calculations based on Poisson-Boltzmann theory are used to investigate the equilibrium properties of an electrolyte containing TcO4− and SO42− ions near the surface of amorphous silica. The calculations show that the concentration of TcO4− is greater than SO42− at distances less than 1 nm from the surface due to the negative charge density caused by deprotonation of the amorphous silica silanol groups. At lower pH, the surface becomes protonated and the magnitude of this effect is reduced. These results have implications for the potential use of oxyanion-SAMMS for the environmental remediation of water contaminated with 99Tc.

The results of sequential large-scale molecular dynamics (MD) simulations of radiation damage cascades in Gd2Ti2O7 and Gd2Zr2O7 are presented. Twelve alpha recoil cascades, each due to a recoil atom with 40 keV of kinetic energy, are performed in both materials and a stark contrast in behaviour observed. Topological connectivity analysis is used to analyse the structural evolution of the two systems. Our results provide important insight into accumulation of disorder in pyrochlore-structured ceramics.

This study investigates whether investors see through materially misstated earnings, and whether they anticipate earnings restatements. For firms that restate at least one annual report, we find that investors are misled by mistakes in reported earnings at the time of initial earnings announcements. Investors react positively to the component of the favorable earnings surprise that will subsequently be restated, and they attach the same valuation to it as to the true earnings surprise. We also find that investors anticipate the subsequent downward restatements and start marking stock prices down several months before a restatement announcement, so that the full impact of a restatement is about three times as large as the restatement announcement effect. Indeed, we show that investors punish restating firms because the stock price gains that shareholders enjoy when firms initially announce overstated earnings are more than reversed by the time of the restatement announcement.