The optoelectronic and thermal properties of conjugated polymers are frequently tuned via direct synthetic modification of the conjugated repeat unit. It is also well known that these properties are inherently tied to the crystal structure, a factor which is difficult to predict upon slight chemical modification. We show that the crystal structure of random copolymers of 3-alkylthiophenes can be controlled, which in turn affects the optoelectronic properties. Furthermore, we show that the melting transitions smoothly vary between that of the two homopolymers. As such, the composition of copolymers is a convenient handle to predictably control the thermal properties, crystalline morphology, and optoelectronic properties simultaneously.

Relative equilibria of two and three satellite vortices in a rotating shallow water layer have been recorded via particle image velocimetry (PIV) and their autorotation speed was estimated. This study shows that these equilibria retain the fundamental characteristics of Kelvin’s equilibria, and could be adequately described by the classical idealized point vortex theory. The same conclusion can also be inferred using the experimental dataset of Bergmann et al. (J. Fluid Mech., vol. 679, 2011, pp. 415–431; J. Fluid Mech., vol. 691, 2012, pp. 605–606) if the assigned field’s contribution to pattern rotation is included.

The problem of direct initiation of detonation, where a powerful ignition source drives a blast wave into a gaseous combustible mixture to generate a Chapman–Jouguet (CJ) detonation, is investigated numerically by using a three-step chain-branching chemical kinetic model. The reaction scheme consists sequentially of a chain-initiation and a chain-branching step, followed by a temperature-independent chain termination. The three regimes of direct initiation i.e. subcritical, critical and supercritical, are numerically simulated for planar, cylindrical and spherical geometries using the present three-step chemical kinetic model. It is shown that the use of a more detailed reaction mechanism allows a well-defined value for the critical initiation energy to be determined. The numerical results demonstrate that detonation instability plays an important role in the initiation process. The effect of curvature for cylindrical and spherical geometries has been found to enhance the instability of the detonation wave and thus influence the initiation process. The results of these simulations are also used to provide further verification of some existing theories of direct initiation of detonation. It appears that these theories are satisfactory only for stable detonation waves and start to break down for highly unstable detonations because they are based on simple blast wave theory and do not include a parameter to model the detonation instability. This study suggests that a stability parameter, such as the ratio between the induction and reaction length, should be considered and a more complex chemistry should be included in future development of a more rigorous theory for direct initiation of detonation.