We review emission processes within the supernova (SN) ejecta. Examples of the application of the theory to observational data are presented. The emission processes and thermal condition within the SN ejecta change as a function of time, and multi-epoch observations are important to obtain comprehensive views. Through the analyses, we can constrain the progenitor radius, compositions as a function of depth, ejecta properties, explosion asymmetry and so on. Multi-frequency follow-up is also important, including radio synchrotron emissions and the inverse Compton effect, γ-ray emissions from radioactive decay of newly synthesized materials. The optical data are essential to make the best use of the multi-frequency data.